Lubricating composition containing a salt of a carboxylic acid

Patent metadata

Field	Value
Publication number	US-9631159-B2
Application number	US-201514969335-A
Country	US
Kind code	B2
Filing date	Dec 15, 2015
Priority date	Jun 15, 2011
Publication date	Apr 25, 2017
Grant date	Apr 25, 2017

Abstract

The invention provides a lubricating composition containing an oil of lubricating viscosity and an amine or ammonia salt of a carboxylic acid compound where said carboxylic acid is characterized in that it is functionalized with a hydroxy-substituted aromatic moiety. The invention further relates to methods of lubricating an internal combustion engine by supplying the described lubricating composition to the internal combustion engine. The invention further relates to the use of the salt of the carboxylic acid compound as an antiwear agent or an antioxidant.

First claim

What is claimed is:

1. A lubricating composition comprising an oil of lubricating viscosity and an amine or ammonia salt of a carboxylic acid wherein the carboxylic acid has the formula (2a):

wherein each R 2 is independently hydrogen, linear or branched hydrocarbyl groups containing 1 to 10 carbon atoms, or mixtures thereof; and
R 3 is hydrogen or a hydrocarbyl group containing 1 to 30 carbon atoms; and
at least one of:
(i) a metal dihydrocarbyl dithiophosphate that contributes at least 100 ppm of phosphorus to the overall composition;
(ii) a dispersant viscosity modifier comprising at least one of ethylene-propylene copolymers that have been functionalized with an acylating agent such as maleic anhydride and an amine, polymethacrylates functionalized with an amine, or esterified styrene-maleic anhydride copolymers reacted with an amine; or
(iii) an overbased detergent comprising at least one of phenates, sulfur containing phenates, sulfonates, salixarates, salicylates, or mixtures thereof.

2. The lubricating composition of claim 1 wherein R 2 is hydrogen.

3. The lubricating composition of claim 1 , wherein the amine or ammonia salt of a carboxylic acid comprises an amine salt of a carboxylic acid and said amine comprises a primary amine, a secondary amine, a tertiary amine, a quaternary ammonium ion or mixtures thereof.

4. The lubricating composition of claim 1 , wherein said salt is present in a range of 0.01 wt % to 10 wt % of the lubricating composition.

5. The lubricating composition of claim 1 , wherein the lubricating composition is characterized as having (i) a sulfur content of 0.5 wt % or less, (ii) a phosphorus content of 0.1 wt % or less, (iii) a sulfated ash content of 1.5 wt % or less, or any combination thereof.

6. The lubricating composition of claim 1 further comprising at least one of an antiwear agent, a friction modifier, a viscosity modifier, an antioxidant, or mixtures thereof.

7. The lubricating composition of claim 6 , wherein the friction modifier comprises at least one long chain fatty acid derivative of an amine, long chain fatty ester, long chain fatty epoxide, fatty imidazoline, amine salt of alkylphosphoric acid, fatty alkyl tartrate, fatty alkyl tartrimide, fatty alkyl tartramide, or mixtures thereof.

8. A method of lubricating an internal combustion engine comprising the step of: (I) supplying to the internal combustion engine the lubricating composition of claim 1 .

Assignees

• Lubrizol Corp

Inventors

• Mosier Patrick E
• Capitosti Scott
• Delbridge Ewan E

Classifications

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/45

  Ash-less or low ash content · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/43

  Sulfur free or low sulfur content compositions · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title