Lubricating composition containing a salt of a carboxylic acid

Patent metadata

Field	Value
Publication number	US-9243202-B2
Application number	US-201214117377-A
Country	US
Kind code	B2
Filing date	Jun 14, 2012
Priority date	Jun 15, 2011
Publication date	Jan 26, 2016
Grant date	Jan 26, 2016

Abstract

The invention provides a lubricating composition containing an oil of lubricating viscosity and an amine or ammonia salt of a carboxylic acid compound where said carboxylic acid is characterized in that it is functionalized with a hydroxy-substituted aromatic moiety. The invention further relates to methods of lubricating an internal combustion engine by supplying the described lubricating composition to the internal combustion engine. The invention further relates to the use of the salt of the carboxylic acid compound as an antiwear agent or an antioxidant.

First claim

We claim:

1. A lubricating composition comprising an oil of lubricating viscosity and an amine or ammonia salt of a carboxylic acid wherein the carboxylic acid has the formula (4a):

wherein each R 2 is independently hydrogen, linear or branched hydrocarbyl groups containing 1 to 10 carbon atoms, or mixtures thereof; and R 3 is hydrogen or a hydrocarbyl group containing 1 to 30 carbon atoms.

2. The lubricating composition of claim 1 wherein R 2 is hydrogen.

3. The lubricating composition of claim 1 wherein said salt comprises an amine or ammonia salt of caffeic acid.

4. The lubricating composition of claim 1 wherein the amine or ammonia salt of a carboxylic acid comprises an amine salt of a carboxylic acid and said amine comprises a primary amine, a secondary amine, a tertiary amine, a quaternary ammonium ion or mixtures thereof.

5. The lubricating composition of claim 1 wherein said salt is present in a range of 0.01 wt % to 10 wt % of the lubricating composition.

6. The lubricating composition of claim 1 wherein the lubricating composition is characterized as having (i) a sulfur content of 0.5 wt % or less, (ii) a phosphorus content of 0.1 wt % or less, (iii) a sulfated ash content of 1.5 wt % or less, or any combination thereof.

7. The lubricating composition of claim 1 further comprising an antiwear agent, a dispersant viscosity modifier, a friction modifier, a viscosity modifier, an antioxidant, an overbased detergent, or mixtures thereof.

8. The lubricating composition of claim 1 further comprising a metal dihydrocarbyl dithiophosphate that contributes at least 100 ppm of phosphorus to the overall composition.

9. The lubricating composition of claim 7 , wherein the friction modifier is selected from the group consisting of long chain fatty acid derivatives of amines, long chain fatty esters, long chain fatty epoxides, fatty imidazolines, amine salts of alkylphosphoric acids, fatty alkyl tartrates, fatty alkyl tartrimides, fatty alkyl tartramides, and combinations thereof.

10. A method of lubricating an internal combustion engine comprising the step of: (I) supplying to the internal combustion engine the lubricating composition of claim 1 .

Assignees

• Mosier Patrick E
• Capitosti Scott
• Delbridge Ewan E
• Lubrizol Corp

Inventors

• Mosier Patrick E
• Capitosti Scott
• Delbridge Ewan E

Classifications

• C10N2030/42

  Phosphor free or low phosphor content compositions · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2030/45

  Ash-less or low ash content · CPC title