Braze materials and method for joining of ceramic matrix composites

Patent metadata

Field	Value
Publication number	US-9624786-B2
Application number	US-201314103927-A
Country	US
Kind code	B2
Filing date	Dec 12, 2013
Priority date	Mar 15, 2013
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A method of coupling two ceramic matrix composite components comprises procuring a first ceramic matrix composite component, procuring a second ceramic matrix composite component, and applying a melt alloy between the first and second ceramic matrix components. The melt alloy comprises a homogeneous mixture of two or more materials in powder form, where the two or more materials include a braze alloy comprising silicon and a high melting point material or alloy. The first and second ceramic matrix composite components and the melt alloy are heat treated to a temperature, and the temperature is maintained for a length of time, followed by cooling, thereby coupling the first and second ceramic matrix composite components.

First claim

What is claimed is:

1. A melt alloy for use as a braze material for joining ceramic matrix composites, the melt alloy comprising:
a homogeneous mixture of two or more materials in powder form, one of the two or more materials being a braze alloy comprising silicon and another of the two or more materials being a high melting point material or alloy,
wherein the homogeneous mixture of the two or more materials in powder form is selected from the group consisting of (in wt. %): Ti-9Si (5%)+71Si—Cr (95%), 75Si—Ti (97%)+C (3%), 75Si—Ti (97%)+B (3%), 75Si—Ti (50%)+71Si—Cr (50%), 75Si—Ti (50%)+Ti-43Cr (50%), 75Si—Ti (50%)+12.5Si—Co (50%), and Ti-25Cr-23Si (97%)+C (3%).

2. The melt alloy of claim 1 , wherein the braze alloy comprising silicon further comprises titanium.

3. The melt alloy of claim 1 , wherein the braze alloy comprising silicon further comprises chromium.

4. The melt alloy of claim 1 , wherein the braze alloy includes up to about 75 wt. % Si.

5. The melt alloy of claim 4 , wherein the braze alloy is selected from the group consisting of (in wt. %): Ti-9Si, Ti-25Cr-23Si, 71Si—Cr, and 75Si—Ti.

6. The melt alloy of claim 1 , wherein the high melting point material is selected from the group consisting of C, B and TiH.

7. The melt alloy of claim 1 , wherein the high melting point material is an alloy including at least one of silicon, titanium, chromium and cobalt.

8. The melt alloy of claim 1 , wherein the mixture includes from 50 wt. % to 97 wt. % of the braze alloy, and from 3 wt. % to 50 wt. % of the high melting point material.

9. A method of coupling two ceramic matrix composite components, the method comprising the operations of:
procuring a first ceramic matrix composite component;
procuring a second ceramic matrix composite component;
applying a melt alloy between the first and second ceramic matrix components, the melt alloy comprising a homogeneous mixture of two or more materials in powder form, where the two or more materials in powder form include a braze alloy comprising silicon and a high melting point material or alloy, the braze alloy including up to about 75 wt. % Si and being selected from the group consisting of (in wt. %): Ti-9Si, Ti-25Cr-23Si, 71Si—Cr, and 75Si—Ti;
heat treating the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy to a temperature;
maintaining the temperature for a length of time; and
cooling the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy,
thereby coupling the first and second ceramic matrix composite components.

10. The method of claim 9 , wherein the braze alloy further comprises titanium.

11. The method of claim 9 , wherein the braze alloy further comprises chromium.

12. The method of claim 9 , wherein the high melting point material is selected from the group consisting of C, B and TiH.

13. The method of claim 9 , wherein the high melting point material is an alloy including at least one of silicon, titanium, chromium and cobalt.

14. The method of claim 9 , wherein the mixture includes from 50 wt. % to 97 wt. % of the braze alloy, and from 3 wt. % to 50 wt. % of the high melting point material.

15. The method of claim 9 , wherein the homogeneous mixture of the two or more materials in powder form is selected from the group consisting of (in wt. %): Ti-9Si (5%)+71Si—Cr (95%), 75Si—Ti (97%)+C (3%), 75Si—Ti (97%)+B (3%), 75Si—Ti (50%)+71Si—Cr (50%), 75Si—Ti (50%)+Ti-43Cr (50%), 75Si—Ti (50%)+12.5Si—Co (50%), and Ti-25Cr-23Si (97%)+C (3%).

16. A method of coupling two ceramic matrix composite components, the method comprising the operations of:
procuring a first ceramic matrix composite component;
procuring a second ceramic matrix composite component;
applying a melt alloy between the first and second ceramic matrix components, the melt alloy comprising a homogeneous mixture of two or more materials in powder form, where the two or more materials in powder form include a braze alloy comprising silicon and a high melting point material or alloy;
heat treating the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy to a temperature;
maintaining the temperature for a length of time; and
cooling the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy,
thereby coupling the first and second ceramic matrix composite components,
wherein the homogeneous mixture of the two or more materials in powder form is selected from the group consisting of (in wt. %): Ti-9Si (5%)+71Si—Cr (95%), 75Si—Ti (97%)+C (3%), 75Si—Ti (97%)+B (3%), 75Si—Ti (50%)+71Si—Cr (50%), 75Si—Ti (50%)+Ti-43Cr (50%), 75Si—Ti (50%)+12.5Si—Co (50%), and Ti-25Cr-23Si (97%)+C (3%).

17. A method of coupling two ceramic matrix composite components, the method comprising the operations of:
procuring a first ceramic matrix composite component;
procuring a second ceramic matrix composite component;
applying a melt alloy between the first and second ceramic matrix components, the melt alloy comprising a homogeneous mixture of two or more materials in powder form, where the two or more materials in powder form include a braze alloy comprising silicon and a high melting point material selected from the group consisting of C, B and TiH;
heat treating the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy to a temperature;
maintaining the temperature for a length of time; and
cooling the first ceramic matrix composite component, the second ceramic matrix composite component, and the melt alloy,
thereby coupling the first and second ceramic matrix composite components.

Assignees

• Rolls Royce Nam Tech Inc
• Rolls Royce Corp

Inventors

• Xu Raymond R
• Freeman Ted J

Classifications

• B23K1/0018 Primary

  Brazing of turbine parts · CPC title

• B23K35/32

  with the principal constituent melting at more than 1550°C · CPC title

• C22C1/0458

  Alloys based on titanium, zirconium or hafnium · CPC title

• C04B2237/122

  based on refractory metals · CPC title

• C04B37/006

  consisting of metals or metal salts · CPC title