Solvent-based low temperature heat seal coating

Patent metadata

Field	Value
Publication number	US-9624400-B2
Application number	US-201514668586-A
Country	US
Kind code	B2
Filing date	Mar 25, 2015
Priority date	Mar 26, 2014
Publication date	Apr 18, 2017
Grant date	Apr 18, 2017

Abstract

A low temperature heat seal coating solution which contains an amorphous or semi-crystalline polyester or co-polyester resin, tackifier, anti-blocking agent, and solvent. The coating solution can be applied to a packaging web such as a foil or film by converters using conventional methods such as gravure, rod, slot die, or printing process. The heal seal coating can be sealed to itself or another substrate to manufacture food packaging bags or pharmaceutical blister packaging. The heat seal temperature can be as low as 70° C. under conventional equipment and conditions in the industry.

First claim

We claim:

1. A solvated, heat seal coating mixture to be applied onto a surface of a packaging film or foil, said mixture comprising:
a solvent in an amount of about 69.7% by weight;
a heat seal resin, in an amount of about 24% by weight, comprising an amorphous or semi-crystalline polyester or co-polyester with a glass transition temperature (Tg) between −35° C. and 0° C. and a Ring and Ball Softening Point between 60° C. and 120° C., the heat seal resin being soluble in said solvent;
a tackifying resin in an amount of about 3% by weight; and
an anti-block additive comprising wax in an amount of about 1.9% by weight, silica in an amount of about 0.6% by weight, stearyl erucamide in an amount of about 0.2% by weight, and talc in an amount of about 0.6% by weight;
wherein said mixture when coated on a packaging film or foil and dried to form a heat sealable coating enables heat sealing of coated surfaces face-to-face on a form, fill and seal machine at a sealing temperature as low as 70° C.

2. A mixture as recited in claim 1 wherein the solvent comprises one or more of the following: ethyl acetate, methyl ethyl ketone, acetone, toluene, dioxolane, tetrahydrofuran, cyclohexane, xylene, butyl acetate or a chlorinated solvent.

3. A mixture as recited in claim 1 wherein the heat seal resin is an amorphous or semi-erystalline polyester comprising one or more of the following glycols:
ethylene glycol, diethylene glycol, butane diol (1,4-; 1,2-; and 1,3-), neopentyl glycol, 2-methyl-1,3-propane diol, hexane diol, trimethylolpropane, and cyclohexanedimethanol; and one or more of the following acids: dimethyl terephthalate, terephthalic acid, isophthalic acid, adipic acid, azelaic acid, sebacic acid, cyclohexanedicarboxylic acid, and hydroxycarboxylic acid.

4. A mixture as recited in claim 1 wherein the tackifying resin comprises natural or modified rosin, rosin esters, natural terpenes, styrenated terpenes, aromatic hydrocarbon resins, aromatic/aliphatic hydrocarbons and their partially or fully hydrogenated derivatives.

5. A mixture as recited in claim 1 wherein the heat seal resin comprises ethylene glycol, terephthalic acid, and sebacic acid.

6. A mixture as recited in claim 1 wherein the heat seal coating anchors to packaging films or foils made of polyester, polypropylene, polyvinyl chloride, treated biaxially oriented polypropylene, biaxially oriented polyethylene, polylactic acid, cellulose, metal foils without requiring that a primer be applied to the surface of the film or foil before applying the solvent based mixture to the surface of the film or foil and drying the mixture to form the heat sealable coating on the surface of the film or foil.

7. A mixture as recited in claim 1 wherein said wax includes paraffin, microcrystal line, polyethylene, polypropylene, or naturally derived wax.

8. A mixture as recited in claim 1 wherein said heat seal resin is an amorphous polyester or co-polyester having a heat of fusion value of 10 Joules/gram or less.

9. A mixture as recited in claim 1 wherein said heat seal resin is a semi-crystalline polyester or co-polyester having a heat of fusion value greater than 10 Joules/gram and up to 50 Joules/grain.

Assignees

• Bostik Inc

Inventors

• Deak Darius K
• Ruppert Thomas Lee
• Lo Elaine

Classifications

• C08J7/0427 Primary

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title

• C08J2467/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• C09J2467/00

  Presence of polyester · CPC title

• C09J7/35

  Heat-activated · CPC title

• Y10T428/31667

  Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product · CPC title