Hydrometallurgical process for nickel oxide ore

Patent metadata

Field	Value
Publication number	US-9617619-B2
Application number	US-201414777678-A
Country	US
Kind code	B2
Filing date	Jan 23, 2014
Priority date	Mar 19, 2013
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

Provided is a hydrometallurgical process for nickel oxide ore by high pressure acid leach that achieves a high iron oxidation ratio. The carbon grade in ore slurry and the flow rate are measured to determine the amount of carbon to be fed, and then, sulfuric acid is added. The blowing ratio of high pressure air and high pressure oxygen is adjusted so as to attain an oxygen purity of 21% to 60%. While the oxygen purity is maintained, an oxygen blowing amount per weight of carbon contained in the ore slurry and fed in the second step is adjusted to 200 to 600 Nm 3 , whereby ORP (Ag/AgCl basis) in the leaching treatment is controlled to 400 to 650 mV.

First claim

The invention claimed is:

1. A hydrometallurgical process for nickel oxide ore, the process comprising: a first step of slurrying a nickel oxide ore to prepare ore slurry; and a second step of adding sulfuric acid to the ore slurry and applying a leaching treatment using high pressure air and high pressure vapor to obtain a leachate containing nickel and cobalt;
wherein, in the second step, a ratio of a blown gas made up of high pressure air and high pressure oxygen so as to attain an oxygen is adjusted purity of 21% to 60%, and, while the oxygen purity is maintained, an oxygen blowing amount is adjusted to 200 to 600[Nm 3 -O 2 /t-C] per ton of carbon amount which is contained in the ore slurry and fed in the second step, whereby an oxidation-reduction potential (Ag/AgCl basis) in a leaching treatment is controlled to 400 to 650 mV.

2. The hydrometallurgical process for nickel oxide ore according to claim 1 , wherein, in the first step, a carbon grade of solids in the ore slurry is adjusted to 0.1% to 0.5% by weight by a blending ratio of nickel oxide ore which have different carbon grades and constitute the ore slurry.

3. The hydrometallurgical process for nickel oxide ore according to claim 1 , wherein, in the second step, a partial pressure of oxygen in a leaching vessel to perform a leaching treatment is adjusted to 100 to 400 kPaG.

4. The hydrometallurgical process for nickel oxide ore according to claim 1 , wherein, in the second step, the high pressure air and the high pressure oxygen are mixed in advance so as to attain the ratio of the blown gas, and then, blown into a leaching vessel.

5. The hydrometallurgical process for nickel oxide ore according to claim 1 , wherein an iron oxidation ratio in the leachate obtained in the second step is not less than 90%.

6. The hydrometallurgical process for nickel oxide ore according to claim 1 , wherein an amount of sulfuric acid used in the second step is 200 to 250[kg-H 2 SO 4 /t-dry Solid] per ton of dry ore for the nickel oxide ore fed to be subjected to a leaching treatment.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Sato Yoshiteru
• Nishikawa Isao
• Higuchi Hirotaka
• Sugita Izumi
• Nakano Osamu

Classifications

• Y02P10/212

  Cross-Sectional Technologies · mapped topic

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C22B23/043 Primary

  Sulfurated acids or salts thereof · CPC title

• C22B23/005

  Preliminary treatment of ores, e.g. by roasting or by the Krupp-Renn process · CPC title

• Y02P10/20

  Recycling · CPC title