Operating method in hydrometallurgy of nickel oxide ore

Patent metadata

Field	Value
Publication number	US-9328399-B2
Application number	US-201214365842-A
Country	US
Kind code	B2
Filing date	Dec 14, 2012
Priority date	Dec 20, 2011
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

It is an object to provide a method for producing magnesium oxide by which magnesium oxide being high in purity and low in impurity content can be produced simply and efficiently from a sulfuric acid solution containing magnesium and calcium such as waste water. In the present invention, calcium is precipitated as calcium sulfate and separated by concentrating a sulfuric acid solution containing magnesium and calcium, and magnesium is precipitated as magnesium sulfate and separated by further concentrating the solution resulting from the separation of calcium. The separated magnesium sulfate is roasted together with a reductant, so that magnesium oxide and sulfur dioxide are obtained. The resulting magnesium oxide is washed to produce magnesium oxide with high purity.

First claim

The invention claimed is:

1. An operating method in hydrometallurgy of nickel oxide ore, the method comprising:
adding sulfuric acid to a slurry of nickel oxide ore to leach the ore under heat and pressure;
separating a leach residue to obtain a leachate;
adding a purified magnesium oxide to the leachate and separating a neutralized precipitate containing an impurity to obtain a neutralization final liquid comprising nickel, cobalt, magnesium and calcium;
subjecting the neutralization final liquid to sulfurization treatment to obtain sulfide and a barren liquor solution comprising the magnesium and calcium;
precipitating calcium sulfate by concentrating the barren liquor solution and separating the calcium;
precipitating magnesium sulfate by further concentrating the concentrated barren liquor solution and separating the magnesium sulfate;
roasting the magnesium sulfate together with a reductant to obtain magnesium oxide and sulfur dioxide; and
washing the magnesium oxide to obtain the purified magnesium oxide,
wherein separating the calcium is ended at a time at which the specific gravity of the concentrated solution is 1.2 g/cm 3 .

2. The operating method in hydrometallurgy of nickel oxide ore according to claim 1 , wherein concentrating the barren liquor solution and further concentrating the barren liquor solution are performed by natural drying.

3. The operating method in hydrometallurgy of nickel oxide ore according to claim 1 , wherein the purified magnesium oxide is added to the leachate to adjust the neutralization final liquid to a pH in the range of 7.0 to 8.5.

4. The operating method in hydrometallurgy of nickel oxide ore according to claim 1 , wherein the reductant is at least one of coke, coal, charcoal, bamboo coal and spent activated carbon.

5. The operating method in hydrometallurgy of nickel oxide ore according to claim 1 , wherein the sulfur dioxide is converted into sulfuric acid and the resulting sulfuric acid is iteratively used as the sulfuric acid for the leaching of the nickel oxide ore.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ozaki Yoshitomo
• Takahashi Jun-Ichi
• Yamashita Yu
• Ohara Hideki

Classifications

• C01F11/46

  Sulfates (dehydration of gypsum {for the production of calcium sulfate cements} C04B11/02) · CPC title

• C01B17/501

  by reduction of sulfur compounds · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01F5/40

  Magnesium sulfates (double sulfates of magnesium with sodium or potassium C01D5/12, with other alkali metals {C01D15/00}, C01D17/00) · CPC title

• C22B23/043 Primary

  Sulfurated acids or salts thereof · CPC title