Method for determining adsorption heat and wetting heat of a surface and a measuring cell of a calorimeter

Patent metadata

Field	Value
Publication number	US-9612167-B2
Application number	US-201314109688-A
Country	US
Kind code	B2
Filing date	Dec 17, 2013
Priority date	Dec 24, 2012
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A sample of a material is placed into a measuring cell of a calorimeter consisting of upper and the lower parts connected with each other by a movable detachable tight connection. The cell is equipped with two coaxially arranged tubes capable of independent connection to external devices. An outer tube is connected to the upper part of the cell and an inner tube is connected to the lower part of the cell via the movable detachable tight connection and is movable. At least once a contact of the sample with vapor of a liquid is provided and heat of adsorption is measured, then contact of the sample with the same or another liquid is provided and heat of wetting of the sample by the same or the other liquid is measured.

First claim

The invention claimed is:

1. A measuring cell of a calorimeter comprising:
an upper part and a lower part separated from each other and configured to be connected with each other, the lower part of the cell being used for placing a sample,
two coaxially arranged tubes, an outer tube connected to the upper part of the cell for feeding a liquid into the upper part of the cell and for maintaining pressure in the cell, and an inner tube connected to the lower part of the cell for evacuating the cell and feeding vapor of the liquid into the lower part of the cell, the inner tube is movable and is connected to the lower part of the cell through a movable detachable tight connection which during movement of the inner tube provides connection of the lower and the upper parts of the cell between each other.

2. The calorimeter measuring cell of claim 1 , wherein the inner tube is movable in vertical direction.

3. The calorimeter measuring cell of claim 1 , wherein tightness of the movable detachable tight connection is provided by a junction of two surfaces.

4. The calorimeter measuring cell of claim 1 , wherein tightness of the movable detachable tight connection is provided by a cone-to-cone, a sphere-to-cone or a flat surface-to-flat surface junction.

5. The calorimeter measuring cell of claim 1 , wherein the inner tube is rotatable around axis of symmetry of the inner tube.

6. The calorimeter measuring cell of claim 1 , wherein tightness of the movable detachable tight connection is provided by closing a passageway of the inner tube.

7. The calorimeter measuring cell of claim 6 , wherein the movable detachable tight connection is a ball valve.

Assignees

• Schlumberger Technology Corp

Inventors

• Dyshlyuk Evgeny Nikolaevich
• Baldygin Vitaly Alekseevich

Classifications

• G01K17/02

  Calorimeters using transport of an indicating substances, e.g. evaporation calorimeters · CPC title

• G01N25/4853

  Details · CPC title

• G01N25/4846

  for a motionless, e.g. solid sample · CPC title

• G01K17/00 Primary

  Measuring quantity of heat (measuring temperature by calorimetry G01K3/00 - G01K11/00; specially adapted for measuring thermal properties of materials, e.g. specific heat, heat of combustion G01N) · CPC title