Process for producing dry synthetic natural gas (SNG)

Patent metadata

Field	Value
Publication number	US-9611440-B2
Application number	US-201314424462-A
Country	US
Kind code	B2
Filing date	Oct 25, 2013
Priority date	Nov 2, 2012
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A process for producing dry synthetic natural gas (SNG, Synthetic Natural Gas) from solid or liquid, carbonaceous fuel, substantially consisting of the following process steps:
a) gasification of a solid or liquid, carbonaceous fuel to a raw synthesis gas b) cooling of the gas, separation of solids and the gas condensate c) raw gas conversion d) washing of the gas with methanol for separating hydrogen sulfide, carbon dioxide and moisture, wherein the methanol is circulated via a regeneration plant, e) methanation, f) condensation of moisture by means of cooling and/or cold water, g) further drying of the gas by condensation at low temperature by adding methanol to avoid the formation of ice.

First claim

The invention claimed is:

1. A process for producing dry synthetic natural gas from solid or liquid, carbonaceous fuel, said process comprising the following process steps carried out in the following order:
a) preparing a first gas by gasifying the fuel, wherein said first gas consists substantially of carbon monoxide, carbon dioxide, methane and hydrogen;
b) preparing a second gas by cooling said first gas and separating from the first gas solids and a gas condensate;
c) preparing a third gas by converting carbon monoxide in said second gas into carbon dioxide and hydrogen;
d) preparing a fourth gas by separating hydrogen sulfide, carbon dioxide and steam from said third gas by washing the third gas with methanol as solvent, wherein the methanol is circulated via a regenerating means for separating hydrogen sulfide, carbon dioxide and water from the methanol, wherein the regenerating means also comprises a methanol-water separation column;
e) preparing a fifth gas by catalytically-supported-conversion of the carbon monoxide, residual carbon dioxide and hydrogen in the fourth gas, wherein the fifth gas consists substantially of methane and steam;
f) preparing a sixth gas by predrying the fifth gas by condensing moisture by means of cooling and/or cold water;
g) preparing a seventh gas by adding methanol to the sixth gas;
h) preparing an eighth gas by separating steam from the seventh gas and condensing out the steam by forming a water-methanol mixture;
i) preparing a ninth gas by separating the water-methanol mixture from the eighth gas; and
j) obtaining said dry synthetic natural gas by heating the ninth gas to a desired discharge temperature.

2. The process according to claim 1 , wherein the water-methanol mixture separated in step i) is introduced into the regenerating means of step d) and treated in the methanol-water separation column.

Assignees

• L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude

Inventors

• Meyer Manfred
• Walter Stefan
• Herrlett Ute

Classifications

• C10L3/106 Primary

  of water · CPC title

• C10K3/04

  reducing the carbon monoxide content {, e.g. water-gas shift [WGS]} · CPC title

• C10K1/004

  Sulfur containing contaminants, e.g. hydrogen sulfide · CPC title

• C10J2300/1662

  to methane · CPC title

• C10J3/00 Primary

  Production of combustible gases containing carbon monoxide from solid carbonaceous fuels (destructive distillation processes C10B) · CPC title