Removal of sulfur compounds in an acid gas stream generated from solvent-based gas treating process

Patent metadata

Field	Value
Publication number	US-9528062-B2
Application number	US-201414326742-A
Country	US
Kind code	B2
Filing date	Jul 9, 2014
Priority date	Jul 31, 2013
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

The invention involves a process for treating a natural gas stream comprising sending the natural gas stream first to an adsorbent unit for removal of mercury. Then the gas stream is sent to an absorbent unit containing a chemical solvent and a physical solvent for removal of carbon dioxide, hydrogen sulfide, carbonyl sulfide and organic sulfur compounds to produce a partially purified natural gas stream. This stream is dehydrated and becomes the product stream. The partially purified natural gas stream to a dehydration unit to remove water to produce a natural gas product stream. The impurities absorbed by the absorption unit are removed and a liquid stream is separated that contains the sulfur impurities. This liquid stream may be purified and stabilized before being shipped for further treatment.

First claim

The invention claimed is:

1. A process for treating a natural gas stream comprising:
a) sending said natural gas stream to an absorbent unit containing a chemical solvent and a physical solvent for removal of carbon dioxide, hydrogen sulfide, carbonyl sulfide and organic sulfur compounds to produce a partially purified natural gas stream;
b) then sending said partially purified natural gas stream to a dehydration unit to remove water to produce a natural gas product stream; and
c) removing said sulfur compounds from said absorbent unit to produce a liquid comprising said sulfur compounds and
d) regenerating said absorbent unit by removing a regeneration gas containing sulfur compounds and water, cooling said regeneration gas to knock out water, then compressing said regeneration gas followed by cooling to condense a majority of said regeneration gas.

2. The process of claim 1 further comprising first sending said natural gas stream to an adsorbent guard bed for removal of mercury and then sending said natural gas stream to said absorbent unit.

3. The process of claim 1 wherein said chemical solvent is selected from the group consisting of amines, ammonia, potassium carbonate and sodium carbonate.

4. The process of claim 1 wherein said physical solvent is selected from the group consisting of dimethyl ethers of polyethylene glycol, propylene carbonate, methanol, N-methyl-2-pyrrolidone, and sulfolane.

5. The process of claim 1 wherein a liquid comprising sulfur compounds and a residual gas are separated from a regeneration gas.

6. The process of claim 1 wherein a regeneration gas is compressed, dried and cooled prior to said separation of said liquid comprising said sulfur compounds.

7. The process of claim 5 wherein said residual gas is recycled to said absorbent unit.

8. The process of claim 1 wherein said natural gas product stream is further processed to remove natural gas liquids.

9. The process of claim 1 wherein said natural gas product is sent to a gas pipeline or to a liquefaction unit.

10. The process of claim 1 wherein said natural gas product is dry and sulfur-free.

11. The process of claim 1 wherein a portion of heavy hydrocarbons in said natural gas stream are removed by said absorption unit.

Assignees

• Uop Llc

Inventors

• Doong Shain-Jer
• Zhou Lubo

Classifications

• C10L3/104

  Carbon dioxide · CPC title

• Y02C10/06

  Cross-Sectional Technologies · mapped topic

• C10L3/101

  Removal of contaminants · CPC title

• C10L3/106 Primary

  of water · CPC title

• C10L3/103

  Sulfur containing contaminants · CPC title