Flexible butadiene extraction process

Patent metadata

Field	Value
Publication number	US-9611195-B2
Application number	US-201314034806-A
Country	US
Kind code	B2
Filing date	Sep 24, 2013
Priority date	Oct 9, 2012
Publication date	Apr 4, 2017
Grant date	Apr 4, 2017

Abstract

A butadiene extraction processes designed for flexible operations, with or without a compressor, is disclosed. The ability to run at both high and low pressures provides added process flexibility.

First claim

What is claimed:

1. A system tier recovering 1,3-butadiene from a C 4 fraction in both a high pressure mode or a low pressure mode, comprising:
a feed vaporization system for at least partially vaporizing a hydrocarbon feed containing butanes, butenes, 1,2-butadiene, 1,3-butadiene, C 4 acetylenes, C 3 acetylenes, and C 5+ hydrocarbons;
an extractive distillation system for contacting the vaporized hydrocarbon fraction with a solvent to selectively dissolve a portion of the hydrocarbon fraction forming (a) an enriched solvent fraction comprising the 1,3-butadiene, the 1,2 butadiene, C 4 acetylenes, C 3 acetylenes, C 5+ hydrocarbons, and a first portion of the butanes and the butenes and (b) a vapor fraction comprising a second portion of the butanes and the butenes;
a rectifier and afterwasher for at least partially degassing the enriched solvent and recovering a first vapor fraction comprising the first portion of the butanes and butenes, a second vapor fraction comprising the C 3 and C 4 acetylenes, 1,3-butadiene, 1,2-butadiene, and C 5+ hydrocarbons, and a bottoms fraction comprising partially degassed solvent;
a degasser and cooling column for further degassing the solvent and recovering a liquid fraction comprising degassed solvent, a third vapor fraction comprising at least one of C4 acetylenes and 1,2-butadiene, and a fraction comprising C4 acetylenes;
wherein the system for recovering 1,3-butadiene is operable for recovering 1,3-butadiene from a C 4 fraction (a) with the degasser in a high pressure mode, and (b) with the degasser in a low pressure mode.

2. The system of claim 1 , further comprising:
a compressor for compressing the third vapor fraction when operating in the low pressure mode; and
a heat exchanger for indirectly heating the partially degassed solvent with the liquid fraction comprising degassed solvent when operating in the high pressure mode.

3. The system of claim 2 , wherein valves and flow conduits associated with the heat exchanger and compressor are operable, respectively, such that (a) in low pressure mode, the liquid fraction comprising degassed solvent bypasses the heat exchanger and the third vapor fraction passes through the compressor, and (b) in high pressure mode, the liquid fraction comprising degassed solvent flows through the heat exchanger and the third vapor fraction bypasses the compressor.

4. The system of claim 1 , further comprising:
a control system configured to operate the system for recovering 1,3-butadiene with or without the compressor.

5. The system of claim 4 , wherein the control system is further configured to disable or enable operations of portions of the system for recovering 1,3-butadiene based on the selected mode of operation.

6. The system of claim 4 , wherein the control system is further configured to transition between the modes of operation.

7. The system of claim 1 , wherein the system for recovering 1,3-butadiene is configured such that the cooling column is in operation during both the high pressure mode and the low pressure mode.

8. The system of claim 1 , wherein the cooling column, degasser and a degasser reboiler are designed for temperature and pressure conditions required for both modes of operation.

9. A system for recovering 1,3-butadiene from a C 4 fraction in both a high pressure mode or a low pressure mode, comprising:
a feed vaporization system for at least partially vaporizing a hydrocarbon feed containing butanes, butenes, 1,2-butadiene, 1,3-butadiene, C 4 acetylenes, C 3 acetylenes, and C 5+ hydrocarbons;
an extractive distillation system for contacting the vaporized hydrocarbon fraction with a solvent to selectively dissolve a portion of the hydrocarbon fraction forming (a) an enriched solvent fraction comprising the 1,3-butadiene, the 1,2-butadiene, C 4 acetylenes, C 3 acetylenes, C 5+ hydrocarbons, and a first portion of the butanes and the butenes and (b) a vapor fraction comprising a second portion of the butanes and the butenes;
a rectifier and afterwasher for at least partially degassing the enriched solvent and recovering a first vapor fraction comprising the first portion of the butanes and butenes, a second vapor fraction comprising the C 3 and C 4 acetylenes, 1,3-butadiene, 1,2 butadiene, and C 5+ hydrocarbons, and a bottoms fraction comprising partially degassed solvent;
a degasser and cooling column for further degassing the solvent and recovering a liquid fraction comprising degassed solvent, a third vapor fraction comprising at least one of C4 acetylenes and 1,2-butadiene, and a fraction comprising C4 acetylenes;
a compressor for compressing the third vapor fraction when operating in the low pressure mode; and
a heat exchanger for indirectly heating the partially degassed solvent with the liquid fraction comprising degassed solvent when operating in the high pressure mode.

10. A system for recovering 1,3-butadiene from a C 4 fraction alternatively in a high pressure mode and a low pressure mode, comprising:
a feed vaporization system for at least partially vaporizing a hydrocarbon feed containing butanes, butenes, 1,2-butadiene, 1,3-butadiene, C 4 acetylenes, C 3 acetylenes, and C 5+ hydrocarbons;
an extractive distillation system for contacting the vaporized hydrocarbon fraction with a solvent to selectively dissolve a portion of the hydrocarbon fraction forming (a) an enriched solvent fraction comprising the 1,3-butadiene, the 1,2-butadiene, C 4 acetylenes, C 3 acetylenes, C 5+ hydrocarbons, and a first portion of the butanes and the butenes and (h) a vapor fraction comprising a second portion of the butanes and the butenes;
a rectifier and afterwasher for at least partially degassing the enriched solvent and recovering a first vapor fraction comprising the first portion of the butanes and butenes a second vapor fraction comprising the C 3 and C 4 acetylenes, 1,3-butadiene, 1,2-butadiene, and C 5+ hydrocarbons, and a bottoms fraction comprising partially degassed solvent;
a degasser and cooling column for further degassing the solvent and recovering a liquid fraction comprising degassed solvent, a third vapor fraction comprising at least one of C4 acetylenes and 1,2-butadiene, and a fraction comprising C4 acetylenes;
wherein the system for recovering 1,3-butadiene is configured such that the cooling column is operable during both the high pressure mode and the low pressure mode.

Assignees

• Lummus Technology Inc

Inventors

• Brummer Robert J
• Dwyer Thomas Alexander

Classifications

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01D3/40

  Extractive distillation · CPC title

• C07C7/08 Primary

  by extractive distillation · CPC title

• C07C7/04 Primary

  by distillation · CPC title

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title