Method for removing high-boiling hydrocarbons from solvent flows

Patent metadata

Field	Value
Publication number	US-9249069-B2
Application number	US-201113885935-A
Country	US
Kind code	B2
Filing date	Nov 11, 2011
Priority date	Nov 16, 2010
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

A method for removing high-boiling hydrocarbons from water-soluble solvent flows, wherein said solvent flows are produced in industrial processes which circulate a solvent as a part of the process, and the solvent must be periodically or permanently freed of high-boiling hydrocarbons which influence the quality or the desired properties of the solvent in an unwanted way, and water is added for carrying out the method in a phase separator, so that the high-boiling hydrocarbons are separated off because of their immiscibility with water, and then the water-miscible phase containing water and solvent is returned to the process. According to the invention, the proportion of high-boiling hydrocarbons in circulating solvents in an industrial process can be kept permanently low.

First claim

The invention claimed is:

1. A process for the removal of high boiling hydrocarbons from water-soluble solvent streams in an industrial process which comprises a gas scrubbing process utilizing an absorbtion column and a scrubbing medium comprising a water-soluble solvent, the process comprising:
withdrawing a partial stream of the water-soluble solvent containing accumulated high boiling hydrocarbons from the absorbtion column;
feeding said partial stream of water-soluble solvent and water to a tank, wherein an aqueous phase, and a non-aqueous hydrocarbonaceous phase containing high boiling hydrocarbon are formed;
withdrawing the non-aqueous hydrocarbonaceous phase from the tank;
recirculating the aqueous phase from the tank to the water-soluble solvent used in the gas scrubbing process, at a recirculation ratio such that an allowable water concentration in the water-soluble solvent is not exceeded, the aqueous phase not having been subjected to distillation prior to recirculation,
combining the recirculating aqueous phase from the tank with a further partial stream of solvent containing high boiling hydrocarbons such that the combined streams have a water concentration below 0.5 wt. %; and
removing water after said step of recirculating by contact with a dry feed gas stream input into the absorbtion column.

2. The process for the removal of high-boiling hydrocarbons from solvent streams according to claim 1 , wherein water in an amount of 5 to 90 wt.-% is added to the partial stream of water-soluble solvent in the tank.

3. The process for the removal of high-boiling hydrocarbons from solvent streams according to claim 1 , further comprising cooling the tank with a cooler.

4. The process for the removal of high-boiling hydrocarbons from solvent streams according to claim 1 , wherein the tank for phase separation is equipped with a heating device.

5. The process of claim 1 , wherein the water content of the water-soluble solvent is monitored, and the amount of aqueous phase which is recirculated is adjusted to keep the water content below 0.5 wt. %.

Assignees

• Menzel Johannes
• Thielert Holger
• Thyssenkrupp Uhde Gmbh

Inventors

• Menzel Johannes
• Thielert Holger

Classifications

• C07C7/005 Primary

  Processes comprising at least two steps in series · CPC title

• C10G21/06

  characterised by the solvent used · CPC title

• C10G21/28

  Recovery of used solvent · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G2300/44

  Solvents · CPC title