Cylinder lubricant for a two-stroke marine engine

Patent metadata

Field	Value
Publication number	US-9605568-B2
Application number	US-201214111684-A
Country	US
Kind code	B2
Filing date	Apr 13, 2012
Priority date	Apr 14, 2011
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

A cylinder lubricant having a BN determined according to the standard ASTM D-2896 greater than or equal to 15 milligrams of potash per gram of lubricant, including: one or more lubricant base oils for marine engines, at least one detergent based on alkali or alkaline-earth metals, overbased with metallic carbonate salts, at least one neutral detergent, one or more oil-soluble alkoxylated fatty amines, having a BN determined according to the standard ASTM D-2896 comprised between 100 and 600 milligrams of potash per gram, where the percentage by mass of alkoxylated fatty amines with respect to the total weight of lubricant is chosen such that the BN provided by these compounds represents a contribution comprised between 2 and 8 milligrams of potash per gram of lubricant, and where the BN provided by the metallic carbonate salts represents a contribution of at the most 65%.

First claim

The invention claimed is:

1. A cylinder lubricant for a two-stroke marine engine having a BN determined according to the standard ASTM D-2896 greater than or equal to 15 milligrams of potash per gram of lubricant, comprising:
(a) one or more lubricant base oils for marine engines;
(b) at least one detergent based on alkali or alkaline-earth metals, overbased with metallic carbonate salts;
(c) at least one neutral detergent; and
(d) one or more oil-soluble alkoxylated fatty amines, and having a BN determined according to the standard ASTM D-2896 comprised between 100 and 600 milligrams of potash per gram;

where the percentage by mass of alkoxylated fatty amines with respect to the total weight of lubricant is chosen such that the BN provided by these compounds represents a contribution comprised between 2 and 7 milligrams of potash per gram of lubricant; and where the BN provided by the metallic carbonate salts represents a contribution of at the most 65% of the total BN, measured according to the standard ASTM D2896, of the cylinder lubricant.

2. The cylinder lubricant according to claim 1 wherein the BN of the alkoxylated fatty amines determined according to the standard ASTM D-2896 is comprised between 120 and 500 milligrams of potash per gram.

3. The cylinder lubricant according to claim 1 wherein the percentage by mass of alkoxylated fatty amines with respect to the total weight of lubricant is chosen such that the BN provided by these compounds represents a contribution comprised between 3 and 7 milligrams of potash per gram of lubricant with the total BN of said cylinder lubricant, determined according to the standard ASTM D-2896.

4. The cylinder lubricant according to claim 1 having a BN, determined according to the standard ASTM D-2896, greater than or equal to 20 milligrams of potash per gram of lubricant.

5. The cylinder lubricant according to claim 1 having a BN, determined according to the standard ASTM D-2896, less than 55 milligrams of potash per gram of lubricant.

6. The cylinder lubricant according to claim 1 having a BN, determined according to the standard ASTM D-2896, comprised between 40 and 50 milligrams of potash per gram of lubricant.

7. The cylinder lubricant according to claim 1 having a BN, determined according to the standard ASTM D-2896, comprised between 50 and 55 milligrams of potash per gram of lubricant.

8. The cylinder lubricant according to claim 1 wherein the BN provided by the metallic carbonate salts represents a contribution comprised between 10% and 60% of the total BN of the cylinder lubricant.

9. The cylinder lubricant according to claim 1 in which the oil-soluble alkoxylated fatty amine(s) are obtained from palm, olive, peanut, standard or oleic rapeseed, standard or oleic sunflower, soya or cotton oil, from beef tallow, or from palmitic, stearic, oleic or linoleic acid.

10. The cylinder lubricant according to claim 1 in which the oil-soluble alkoxylated fatty amine(s) are obtained from fatty acids comprising between 16 and 18 carbon atoms.

11. The cylinder lubricant according to claim 1 in which the alkoxylated fatty amine(s) correspond to general formula (I):

where
R 1 is an ethylene, propylene, butylene radical,
R 2 is a fatty chain of saturated or unsaturated fatty acids, comprising between 12 and 22 carbon atoms, preferably between 16 and 18 carbon atoms,
R 3 is an alkylene radical comprising between 2 and 3 carbon atoms,
q is equal to 0 or to 1, and when q is equal to zero, p is equal to zero,
n, m and p are integers comprised between 0 and 12,
and n+m+p is strictly greater than zero.

12. The cylinder lubricant according to claim 11 wherein:
q=p=0,
m+n is comprised between 2 and 5, and
m and n are non-zero.

13. The cylinder lubricant according to claim 1 in which the overbased detergents (b) and the neutral detergents (c) are chosen from the carboxylates, sulphonates, salicylates, naphthenates, phenates, and mixed detergents combining at least two of these types of detergents.

14. The cylinder lubricant according to claim 1 wherein at least one overbased detergent (b) is a sulphonate.

15. The cylinder lubricant according to claim 1 wherein at least one neutral detergent (c) is a phenate or a sulphonate.

16. The cylinder lubricant according to claim 1 also comprising from 0.1 to 10% by mass, of one or more compounds chosen from:
the primary, secondary or tertiary fatty monoalcohols, the alkyl chain of which is saturated or unsaturated, linear or branched, and comprise at least 12 carbon atoms; and
the esters of saturated fatty monoacids comprising at least 14 carbon atoms and alcohols comprising at the most 6 carbon atoms.

17. The cylinder lubricant according to claim 1 , the kinematic viscosity of which measured according to the standard ASTM D445 at 100° C. is comprised between 12.5 and 26.1 cSt.

18. A method for lubricating a two-stroke marine engine powered with a fuel oil comprising operating the engine with a cylinder lubricant according to claim 1 , wherein the lubricant can be used both with fuel oils with a sulphur content less than 1.5% m/m and with fuel oils with a sulphur content greater than 3.5% m/m.

19. A method for lubricating a two-stroke marine engine powered with a fuel oil comprising operating the engine with a cylinder lubricant according to claim 1 , wherein the lubricant can be used with all the fuel oils with a sulphur content comprised between 0.1% m/m and 3.5% m/m.

20. A method for preventing corrosion and/or reducing the formation of insoluble metallic salt deposits in the cylinders of a two-stroke marine engine powered with a fuel oil the sulphur content of which is less than 4.5% m/m, comprising operating the engine with a cylinder lubricant according to claim 1 .

21. A concentrate of additives, for the preparation of cylinder lubricants having a BN determined according to the standard ASTM D-2896 greater than or equal to 15 milligrams of potash per gram of lubricant, the concentrate having a BN comprised between 180 and 250, and comprising one or more alkoxylated fatty amines with a BN comprised between 100 and 600 mg of potash/g of amine according to the standard ASTM D-2896, the percentage by mass of the alkoxylated fatty amines in the concentrate being chosen so as to provide the concentrate with a contribution of BN determined according to the standard ASTM D-2896 comprised between 10 and 40 milligrams of potash per gram of concentrate.

22. A cylinder lubricant for a two-stroke marine engine having a BN determined according to the standard ASTM D-2896 greater than or equal to 15 milligrams of potash per gram of lubricant, comprising:
(a) from 78% (weight) to 81% (weight) group I base oils for marine engines;
(b) from 9% (weight) to 14% (weight) phenate and sulphonate detergents overbased with metallic carbonate salts;
(c) from 1% (weight) to 8% (weight) neutral phenate detergent;
(d) 3% (weight) ethoxylated oleic monoamine;
(e) 1.2% (weight) dispersant; and
(f) 0.04% (weight) anti-foaming agent,
where the percentage by mass of ethoxylated oleic monoamine with respect to the total weight of lubricant is such that the BN provided by these compounds represents a contribution comprised between 3.5 and 5 milligrams of potash per gram of lubricant.

Assignees

• Lancon Denis
• Doyen Valérie
• Total Marketing Services

Inventors

• Lancon Denis
• Doyen Valérie

Classifications

• C10N2040/252

  Diesel engines · CPC title

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2030/12

  Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title