α-alumina particles and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-9604852-B2
Application number	US-201314431891-A
Country	US
Kind code	B2
Filing date	Sep 27, 2013
Priority date	Sep 28, 2012
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

The present invention aims to provide a simple and efficient method for manufacturing α-alumina particles, main component particles of which each have a crystal face other than the face [001] as a main crystal face and a polyhedral shape other than a hexagonal bipyramidal shape. According to the method for manufacturing α-alumina particles of the present invention, when an aluminum compound is calcined in the presence of a specific content of a metal compound, α-alumina particles each having a particle diameter of 50 μm or less, a degree of α crystallization of 90% or more, and a polyhedral shape can be obtained.

First claim

The invention claimed is:

1. α-alumina particles each having a particle diameter of 50 μm or less, a degree of α crystallization of 90% or more, a crystal face other than the face [001] as a main crystal face, and a polyhedral shape other than a hexagonal bipyramidal shape, wherein the α-alumina particles contain molybdenum oxide and/or vanadium oxide.

2. The α-alumina particles according to claim 1 , wherein the α-alumina particles each have at least eight crystal faces.

3. The α-alumina particles according to claim 2 , wherein the α-alumina particles contain 10 percent by mass or less of molybdenum oxide and/or vanadium oxide.

4. The α-alumina particles according to claim 2 , wherein the area of the face [001] is 20% or less of the total area of each particle.

5. The α-alumina particles according to claim 3 , wherein the area of the face [001] is 20% or less of the total area of each particle.

6. The α-alumina particles according to claim 1 , wherein the α-alumina particles contain 10 percent by mass or less of molybdenum oxide and/or vanadium oxide.

7. The α-alumina particles according to claim 6 , wherein the area of the face [001] is 20% or less of the total area of each particle.

8. The α-alumina particles according to claim 1 , wherein the area of the face [001] is 20% or less of the total area of each particle.

9. A method for manufacturing polyhedral α-alumina particles, the method comprising: calcining an aluminum compound in the presence of a metal compound,
wherein aluminum in the aluminum compound and a metal in the metal compound are set so that a molar ratio of metal/aluminum is in a range of 0.03 to 3.0
wherein the calcination is performed in an air or an oxygen atmosphere or in an inert atmosphere of nitrogen or argon.

10. The method for manufacturing polyhedral α-alumina particles according to claim 9 ,
wherein the calcination is performed at a maximum temperature of 900° C. to 1,300° C., an increase in temperature to the maximum temperature is performed in a range of 1 to 10 hours, and holding at the maximum temperature is performed for a holding time in a range of 5 minutes to 5 hours.

11. The method for manufacturing α-alumina particles according to claim 10 ,
wherein the types of metals in the metal compound include molybdenum and/or vanadium.

12. The method for manufacturing α-alumina particles according to claim 9 ,
wherein the types of metals in the metal compound include molybdenum and/or vanadium.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Yuan Jianjun
• Kinoshita Hiroshi

Classifications

• C30B29/20

  Aluminium oxides · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01F7/30 Primary

  Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title

• C01P2006/12

  Surface area · CPC title