Reforming catalyst compositions

Patent metadata

Field	Value
Publication number	US-9604203-B2
Application number	US-201113235858-A
Country	US
Kind code	B2
Filing date	Sep 19, 2011
Priority date	Sep 19, 2011
Publication date	Mar 28, 2017
Grant date	Mar 28, 2017

Abstract

Process for the preparation of a catalyst suitable for use in a naphtha reforming process, the process including providing a Y zeolite with an initial SiO 2 :Al 2 O 3 molar ratio of at least 150, introducing the Y zeolite to a binder to form an intermediate composition, extruding the intermediate composition, reducing the alpha acidity of the extruded composition to provide a low acid composition, and introducing a noble metal to the low acid composition. Processes and systems of converting naphtha to a higher-octane hydrocarbon supply using catalysts, as prepared herein, are also disclosed.

First claim

The invention claimed is:

1. A process for the preparation of a catalyst suitable for use in a naphtha reforming process comprising:
(a) providing a Y zeolite with an initial SiO 2 :Al 2 O 3 molar ratio of at least 150;
(b) introducing the Y zeolite to a binder to form an intermediate composition;
(c) extruding the intermediate composition;
(d) reducing the acidity of the extruded composition to provide a low acid composition such that the alpha acidity of the low acid composition is less than about 1.25; and
(e) introducing a noble metal to the low acid composition; wherein the noble metal is selected from the group consisting essentially of platinum, rhenium, iridium, or combinations thereof, wherein the noble metal is introduced to the low acid composition via impregnation in a rotating impregnation cone; and
wherein the catalyst suitable for use in a flaptha naphtha reforming process is chlorine free.

2. The process of claim 1 , wherein the initial SiO 2 :Al 2 O 3 molar ratio of the Y zeolite is at least 200.

3. The process of claim 1 , wherein the Y zeolite is initially in an H-form.

4. The process of claim 1 , further comprising introducing a polyvinyl alcohol to the Y zeolite prior to extruding the intermediate composition.

5. The process of claim 1 , wherein the binder includes SiO 2 .

6. The process of claim 5 , wherein the intermediate composition has a solid weight ratio of Y zeolite:binder of from about 7:3 to about 9:1 prior to being extruded, based on the total solid weight of the intermediate composition at 1000° F.

7. The process of claim 1 , wherein reducing the acidity of the extruded composition includes calcining the extruded composition.

8. The process of claim 7 , wherein the calcining occurs at a heat up rate of between about 3° F. to about 7° F. per minute, and the extruded composition is maintained at at least about 1000° F. for at least 2 hours.

9. The process of claim 7 , wherein reducing the acidity of the extruded composition further includes an ammonium exchange operation.

10. The process of claim 9 , wherein the extruded composition at beginning of the ammonium exchange operation has a pH of between about 5.7 to about 5.0 and the extruded composition at the end of the ammonium exchange operation has a pH of between about 4.5 to about 3.8.

11. The process of claim 9 , wherein the ammonium exchange operation includes introducing a NH 4 + source to a vessel containing the extruded composition, and mixing the NH 4 + source with the extruded composition.

12. The process of claim 9 , wherein reducing the acidity of the extruded composition further includes a steaming operation.

13. The process of claim 12 , wherein the steaming operation includes heating the extruded composition to at least 1400° F. at a rate of between about 3° F. to about 7° F. per minute and subsequently introducing steam to the heated composition.

14. The process of claim 1 , wherein the low acid composition has an alpha acidity of less than 1.0.

15. The process of claim 14 , wherein the low acid composition has an alpha acidity of less than 0.5.

16. The process of claim 1 , further including
(f) drying the composition from (e) to prepare a dried catalyst; and
(g) calcining the dried catalyst.

Assignees

• Beeckman Jean W
• Mccarthy Stephen J
• Cheng Jane C
• Exxonmobil Res & Eng Co

Inventors

• Beeckman Jean W
• Mccarthy Stephen J
• Cheng Jane C

Classifications

• B01J37/10

  in the presence of water, e.g. steam · CPC title

• B01J2229/36

  Steaming · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• B01J2229/16

  to increase the Si/Al ratio; Dealumination · CPC title

• C10G35/065

  containing crystalline zeolitic molecular sieves, other than aluminosilicates · CPC title