Electrolyte solution and electrochemical device

Patent metadata

Field	Value
Publication number	US-9601279-B2
Application number	US-201314420443-A
Country	US
Kind code	B2
Filing date	Aug 8, 2013
Priority date	Sep 4, 2012
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

The present invention aims to provide an electrolyte solution that is less likely to lead to an increase in resistance and realizes high capacity retention factor even after continuous application of a high voltage, and to provide an electrochemical device. The present invention provides an electrolyte solution including: a nitrile compound; and a quaternary ammonium salt, the electrolyte solution having a potassium ion content of less than 10 ppm, a moisture content of 20 ppm or less, a tertiary amine content of 30 ppm or less, a heterocyclic compound content of 30 ppm or less, and an ammonia content of 20 ppm or less.

First claim

The invention claimed is:

1. An electrolyte solution comprising:
a nitrile compound; and
a quaternary ammonium salt,
the electrolyte solution having a potassium ion content of less than 10 ppm,
a moisture content of 20 ppm or less,
a tertiary amine content of 30 ppm or less,
a heterocyclic compound content of 30 ppm or less, and
an ammonia content of 20 ppm or less.

2. The electrolyte solution according to claim 1 ,
wherein the quaternary ammonium salt is triethylmethylammonium tetrafluoroborate, or tetraethylammonium tetrafluoroborate.

3. The electrolyte solution according to claim 1 ,
wherein the nitrile compound is acetonitrile.

4. The electrolyte solution according to claim 1 , further comprising a sulfolane compound.

5. The electrolyte solution according to claim 1 , further comprising a fluorine-containing ether.

6. The electrolyte solution according to claim 1 ,
wherein the quaternary ammonium salt has a concentration of 0.1 to 2.5 mol/1.

7. The electrolyte solution according to claim 1 for an electrochemical device.

8. The electrolyte solution according to claim 1 for an electrical double layer capacitor.

9. An electrochemical device comprising:
the electrolyte solution according to claim 1 ;
a positive electrode; and
an negative electrode.

10. The electrochemical device according to claim 9 , which is an electrical double layer capacitor.

11. The electrolyte solution according to claim 1 ,
wherein the quaternary ammonium salt is at least one of the group consisting of a tetraalkyl quaternary ammonium salt represented by the formula (IIA):

wherein R 1a , R 2a , R 3a , and R 4a may be the same as or different from one another, and each are a C1-C6 alkyl group that may have an ether bond; and X − is BF 4 − , PF 6 − , AsF 6 − or SbF 6 − ,
a spirobipyridinium salt represented by the formula (IIB):

wherein R 8a and R 9a may be the same as or different from each other, and each are a C1-C4 alkyl group; X − is BF 4 − , PF 6 − , AsF 6 − or SbF 6 − ; n1 is an integer of 0 to 5; and n2 is an integer of 0 to 5,
an imidazolium salt represented by the formula (IIC):

wherein R 10a and R 11a may be the same as or different from each other, and each are a C1-C6 alkyl group; and X − is BF 4 − , PF 6 − , AsF 6 − or SbF 6 − , or
an N-alkylpyridinium salt represented by the formula (IID):

wherein R 12a is a C1-C6 alkyl group; and X − is BF 4 − , PF 6 − , AsF 6 − or SbF 6 − .

12. The electrolyte solution according to claim 1 ,
wherein the quaternary ammonium salt is at least one of the group consisting of compounds represented by the following formulas:

wherein Me represents a methyl group; Et represents an ethyl group; and X − is BF 4 − , PF 6 − , AsF 6 − or SbF 6 − ; and x and y may be the same as or different from each other and each are an integer of 0 to 4, provided that x+y=4.

Assignees

• Daikin Ind Ltd

Inventors

• Takahashi Kenzou
• Koh Meiten

Classifications

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/0568

  characterised by the solutes · CPC title

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title

• H01G11/58

  Liquid electrolytes · CPC title