Porous carbon materials for CO2 separation in natural gas

Patent metadata

Field	Value
Publication number	US-9597656-B2
Application number	US-201514833248-A
Country	US
Kind code	B2
Filing date	Aug 24, 2015
Priority date	Jan 11, 2012
Publication date	Mar 21, 2017
Grant date	Mar 21, 2017

Abstract

In some embodiments, the present disclosure pertains to materials for use in CO 2 capture in high pressure environments. In some embodiments, the materials include a porous carbon material containing a plurality of pores for use in a high pressure environment. Additional embodiments pertain to methods of utilizing the materials of the present disclosure to capture CO 2 from various environments. In some embodiments, the materials of the present disclosure selectively capture CO 2 over hydrocarbon species in the environment.

First claim

What is claimed:

1. A method of capturing CO 2 , the method comprising:
associating a CO 2 containing environment with a high surface area, porous carbon material that includes a plurality of moieties embedded within the pores of the porous carbon materials,
wherein the plurality of moieties are selected from the group consisting of nitrogen-containing moieties, sulfur-containing moieties, and combinations thereof;
wherein the environment is selected from the group consisting of industrial gas streams, natural gas streams, natural gas wells, industrial gas wells, oil and gas fields, and combinations thereof, wherein the environment is pressurized to a total pressure between about 2.5 bar to about 100 bar;
wherein the majority of the pores in the porous carbon material have a diameter of about 3 nm or less,
wherein the density of the porous carbon material is between about 0.3 g/cm 3 to about 4 g/cm 3 , and
wherein the CO 2 sorption absolute capacity of the porous carbon material is between about 50 wt % and about 200 wt %; and

selectively capturing CO 2 over hydrocarbon species in the environment within the pores of the porous carbon material.

2. The method of claim 1 , wherein the selectively capturing comprises:
sorption of CO 2 to the porous carbon material between about 2.5 bar and about 100 bar total pressure;
wherein the sorption of the CO 2 occurs without heating the porous carbon material or the environment; and
wherein the plurality of moieties facilitate selectively capturing CO 2 by facilitating formation of a matrix of CO 2 within the pores of the porous carbon material.

3. The method of claim 1 , further comprising releasing the CO 2 from the porous carbon material after it has been captured;
wherein the release of the CO 2 occurs at total pressures ranging from about 0.01 bar to about atmospheric pressure; and
wherein the release of the CO 2 occurs without heating the porous carbon material or the environment.

4. The method of claim 1 , wherein the release of the CO 2 is enhanced by the addition of heat to the porous carbon material or to the environment.

5. The method of claim 1 , wherein the porous carbon material is produced from a high fixed carbon content precursor selected from a group consisting of biochar, hydrochar, coal, lignite, biomass, organic substances containing heteroatoms such as nitrogen or sulfur, and combinations thereof;
optionally wherein the precursor is heated at temperatures greater than 600° C., and wherein CO 2 selectivity and CO 2 capacity of the porous carbon material is enhanced by functionalization of the porous carbon material surface during such heating; or
optionally wherein the precursor is activated at a temperature between about 650° C. and about 1000° C. and in the presence of an amount of activating agent, to create and maintain micropores within the porous carbon material.

6. The method of claim 1 , wherein the porous carbon material comprises an asphalt-derived porous carbon.

7. The method of claim 1 , wherein the plurality of moieties within the pores are covalently linked to the pores.

8. A method of capturing CO 2 , the method comprising:
associating a CO 2 containing environment with a high surface area, porous carbon material that comprises a plurality of moieties embedded within the pores of the porous carbon materials,
wherein the plurality of moieties are selected from the group consisting of nitrogen-containing moieties, sulfur-containing moieties, and combinations thereof;
selectively capturing CO 2 over hydrocarbon species within the pores of the porous carbon material;
releasing the CO 2 from the porous carbon material after it has been captured; and
reusing the porous carbon material for CO 2 capture subsequent to the releasing step,
wherein the environment has a total pressure between about 2.5 to about 100 bar, and wherein the majority of the pores in the porous carbon material have a diameter of about 3 nm or less.

9. The method of claim 8 , wherein the environment is selected from the group consisting of industrial gas streams, natural gas streams, natural gas wells, industrial gas wells, oil and gas fields, and combinations thereof.

10. The method of claim 8 , wherein the plurality of moieties facilitate selectively capturing CO 2 by facilitating formation of a matrix of CO 2 within the pores of the porous carbon material.

11. The method of claim 8 , wherein the porous carbon material has a CO 2 uptake of between about 0.92 g/g to about 1.50 g/g, at a CO 2 partial pressure of about 30 bar.

12. The method of claim 8 , wherein the porous carbon material selectively captures CO 2 over CH 4 , such that the molecular ratio between CO 2 and CH 4 is between about 2 and about 10.

13. The method of claim 8 , wherein the porous carbon material is produced from a high fixed carbon content precursor selected from a group consisting of biochar, hydrochar, coal, lignite, biomass, organic substances containing heteroatoms such as nitrogen or sulfur, and combinations thereof;
optionally wherein the precursor is heated at temperatures greater than 600° C., and wherein CO 2 selectivity and CO 2 capacity of the porous carbon material is enhanced by functionalization of the porous carbon material surface during such heating; or
optionally wherein the precursor is activated at a temperature between about 650° C. and about 1000° C. and in the presence of an amount of activating agent, to create and maintain micropores within the porous carbon material.

14. The method of claim 8 , wherein the porous carbon material comprises an asphalt-derived porous carbon.

15. The method of claim 8 , wherein the plurality of moieties within the pores are covalently linked to the pores.

Assignees

• Univ Rice William M

Inventors

• Tour James M
• Schipper Desmond E
• Hwang Chih-Chau
• Tour Josiah
• Jalilov Almaz S
• Ruan Gedeng
• Li Yilun

Classifications

• B01J2220/4825

  Polysaccharides or cellulose materials, e.g. starch, chitin, sawdust, wood, straw, cotton · CPC title

• B01J20/28066

  being more than 1000 m2/g · CPC title

• B01J20/3416

  of sorbents or filter aids comprising free carbon, e.g. activated carbon · CPC title

• Y02C20/20

  of methane · CPC title

• B01D2257/504

  Carbon dioxide · CPC title