NMR sample tube and NMR spectrometer

Patent metadata

Field	Value
Publication number	US-9581663-B2
Application number	US-201313889569-A
Country	US
Kind code	B2
Filing date	May 8, 2013
Priority date	May 15, 2012
Publication date	Feb 28, 2017
Grant date	Feb 28, 2017

Abstract

An NMR sample tube is offered which can be spun at high speed stably. The NMR sample tube is adapted for use in solid-state NMR spectroscopy and includes a tubular member, spacers, and cover bodies. The spacers are disposed inside the tubular member. Each spacer has first and second surfaces located on opposite sides. The first surfaces of the spacers define a space filled up with a sample. The tubular member has openings which are closed off by the cover bodies.

First claim

The invention claimed is:

1. An NMR sample tube for use in solid-state NMR spectroscopy, said NMR sample tube comprising:
a tubular member having an axial bore with openings at each axial end;
solid disc-like spacers disposed inside the bore of the tubular member and each spacer having a first surface cooperating with the axial bore to define a space filled up with a sample without biasing or deformation of the sample and a second surface located on an opposite side of the spacer from the first surface; and
cover bodies mounted in the openings at each axial end of the bore disposed opposite to and abutting the second surfaces of the spacers and sealing off the openings in the tubular member.

2. An NMR sample tube as set forth in claim 1 , wherein a recess is formed in the first surface of each of the spacers.

3. An NMR sample tube as set forth in claim 2 , wherein said recess is conical in shape.

4. An NMR sample tube as set forth in claim 2 , wherein said recess is a paraboloid of revolution in shape, and wherein said spacers are disposed such that an axis of spinning of the recess is coincident with a central axis of said tubular member.

5. An NMR sample tube as set forth in claim 1 , wherein said first surface of each of the spacers is smooth.

6. An NMR sample tube as set forth in claim 4 , wherein said spacers are cylindrical in shape.

7. An NMR sample tube as set forth in claim 1 , wherein said spacers are two in number and disposed inside said tubular member, and wherein said space is formed between said first surfaces of the two spacers.

8. An NMR sample tube as set forth in claim 1 , wherein said spacers are made of an engineering plastic material.

9. An NMR sample tube as set forth in claim 1 , wherein said spacers are made of the same material as said cover bodies.

10. An NMR sample tube as set forth in claim 1 , wherein said spacers are placed in contact with the inner surface of said tubular member.

11. An NMR sample tube as set forth in claim 1 , wherein said spacers are fitted inside said tubular member.

12. An NMR spectrometer including an NMR sample tube as set forth in claim 1 .

Assignees

• Jeol Resonance Inc
• Jeol Ltd

Inventors

• Endo Yuki

Classifications

• G01R33/307 Primary

  specially adapted for moving the sample relative to the MR system, e.g. spinning mechanisms, flow cells or means for positioning the sample inside a spectrometer · CPC title