Metal nanowire thin-films

Patent metadata

Field	Value
Publication number	US-9574272-B2
Application number	US-200913061745-A
Country	US
Kind code	B2
Filing date	Sep 1, 2009
Priority date	Sep 2, 2008
Publication date	Feb 21, 2017
Grant date	Feb 21, 2017

Abstract

A conductive nanowire film based on a high aspect-ratio metal is disclosed. The nanowire film is produced by inducing metal reduction in a concentrated surfactant solution containing metal precursor ions, a surfactant and a reducing agent. The metal nanostructures demonstrate utility in a great variety of applications.

First claim

The invention claimed is:

1. A process for the preparation of a conductive nanowire film on a surface of a substrate, wherein the aspect ratio of the nanowires is greater than 1000 and the cross-sectional diameter of the nanowires is less than 10 nm, said process comprising:
(a) obtaining an aqueous precursor solution comprising at least one metal precursor, at least one surfactant and at least one metal reducing agent wherein the concentration of the at least one surfactant in said solution is at least 5% (w/w), wherein the metal precursor is selected from metal precursor in a form of metal ions or in a form which under the reaction conditions dissociate into metal ions;
(b) after obtaining the precursor solution, placing the precursor solution on the surface of a substrate, forming a film of the precursor solution on at least a portion of the surface of the substrate; and
(c) allowing said nanowires to form in said film;

thereby obtaining a conductive nanowire film on at least a portion of said surface.

2. The process according to claim 1 , further comprising irradiating the film of the precursor solution on at least a portion of a surface of a substrate with ultraviolet radiation.

3. The process according to claim 1 , wherein said aqueous precursor solution is prepared by first forming a solution of at least one first metal precursor and at least one surfactant at a temperature allowing dissolution followed by the addition of at least one metal reducing agent and/or at least one second metal precursor.

4. The process according to claim 3 , wherein said aqueous precursor solution is prepared by first forming a solution of at least one first metal precursor, at least one surfactant and at least one metal reducing agent at a temperature allowing dissolution followed by the addition of at least one second metal precursor.

5. The process according to claim 3 , wherein said aqueous precursor solution is prepared by first forming a solution of at least one first metal precursor, at least one surfactant and at least one second metal precursor and at least one reducing agent at a temperature allowing dissolution, followed by the addition of at least one second reducing agent.

6. The process according to claim 5 , wherein said at least one second metal precursor is a silver metal precursor.

7. The process according to claim 1 , wherein said at least one metal precursor is selected from the group consisting of gold metal precursors, silver gold precursors, palladium metal precursors, copper metal precursors, nickel metal precursors and platinum metal precursors.

8. The process according to claim 7 , wherein said at least one metal precursor is selected from the group consisting of HAuCl 4 ; AgNO 3 ; (NH 4 ) 2 PdCl 6 ; Cu(NO 3 ) 2 ; NiCl 2 ; and H 2 PtCl 6 .

9. The process according to claim 7 , wherein said at least one metal precursor is at least one gold metal precursor.

10. The process according to claim 1 , wherein said at least one surfactant is at least one cationic surfactant.

11. The process according to claim 10 , wherein said at least one cationic surfactant comprises at least one quaternary ammonium group.

12. The process according to claim 11 , wherein said at least one surfactant is selected from the group consisting of cetyltrimethylammonium bromide (CTAB), didodecyldimethylammonium bromide, tetradecyltrimethylammonium bromide, didecyldimethylammonium bromide, wherein the bromide counterion, alternatively, may be a chloride or an iodide.

13. The process according to claim 1 , wherein said at least one metal reducing agent is selected from the group consisting of inorganic and organic reducing agents.

14. The process according to claim 13 , wherein said at least one reducing agent is selected from the group consisting of metal borohydride, metal ascorbate, hydroquinone and hydroquinone derivatives, hydrazine and hydrazine derivatives and any combination thereof.

15. The process according to claim 14 , wherein said metal borohydride and metal ascorbate are sodium borohydride and sodium ascorbate, respectively.

16. The process according to claim 1 , wherein the thickness of the thin-film is between 10 and 100 μm.

17. The process according to claim 1 , wherein the aqueous precursor solution in step (a) being prepared by combining the at least one surfactant, the at least one metal precursor being at least one first metal precursor, the at least one metal reducing agent, and at least one second metal precursor in an aqueous medium.

18. The process according to claim 17 , wherein the reduction of the at least one first metal precursor is induced by the addition of the at least one second metal precursor.

19. The process according to claim 18 , wherein said at least one second metal precursor is a silver metal precursor.

20. The process according to claim 17 , wherein said at least one first metal precursor is a gold metal precursor and the aqueous precursor solution is obtained by:
(i) forming a solution of at least one surfactant, at least one gold metal precursor and at least one metal reducing agent in an aqueous medium; and
(ii) adding into the aqueous solution the at least one second metal precursor, wherein the at least one second metal precursor is at least one silver metal precursor to thereby induce reduction of said at least one gold metal precursor.

21. The process according to claim 17 , wherein said at least one metal reducing agent is sodium ascorbate and said at least one surfactant is CTAB.

22. The process according to claim 1 , wherein
in the obtaining the aqueous precursor solution, said solution being prepared by:
(i) combining the at least one surfactant, the at least one first metal precursor, at least one second metal precursor and the at least one metal reducing agent in an aqueous medium, wherein the at least one metal precursor and the at least one second metal precursor are each, independently selected from metal precursors in a form of metal ions or in a form which under the reaction conditions dissociate into metal ions; and
(ii) introducing at least one second reducing agent.

23. The process according to claim 22 , wherein the reduction of the at least one first metal precursor is induced by the at least one second reducing agent after a solution has been formed of the first and second metal precursors, first reducing agent and the at least one surfactant.

24. The process according to claim 22 , wherein the at least one reducing agent and the at least one second reducing agent employed are a hydride or a metal borohydride and sodium ascorbate.

25. The process according to claim 22 , wherein the at least one first metal precursor is a gold metal precursor and the at least one second metal precursor is silver.

Assignees

• Markovich Gil
• Azulai Daniel
• Krichevski Olga
• Ramot At Tel-Aviv Univ Ltd

Inventors

• Markovich Gil
• Azulai Daniel
• Krichevski Olga

Classifications

• C23C18/143

  Radiation by light, e.g. photolysis or pyrolysis · CPC title

• H05K3/182

  characterised by the patterning method · CPC title

• H05K2201/026

  Nanotubes or nanowires · CPC title

• Y10T428/24917

  including metal layer · CPC title

• C23C18/44

  using reducing agents · CPC title