Preparation of nanoparticle materials

Patent metadata

Field	Value
Publication number	US-9567520-B2
Application number	US-201514923199-A
Country	US
Kind code	B2
Filing date	Oct 26, 2015
Priority date	Apr 30, 2004
Publication date	Feb 14, 2017
Grant date	Feb 14, 2017

Abstract

A method of producing nanoparticles comprises effecting conversion of a nanoparticle precursor composition to the material of the nanoparticles. The precursor composition comprises a first precursor species containing a first ion to be incorporated into the growing nanoparticles and a separate second precursor species containing a second ion to be incorporated into the growing nanoparticles. The conversion is effected in the presence of a molecular cluster compound under conditions permitting seeding and growth of the nanoparticles.

First claim

What is claimed is:

1. A method of producing nanoparticles comprising:
effecting conversion of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a first ion to be incorporated into the nanoparticles and a separate second precursor species containing a second ion to be incorporated into the nanoparticles,
wherein said conversion is effected in the presence of a molecular cluster compound comprising both the first ion to be incorporated into the nanoparticles and the second ion to be incorporated into the nanoparticles, under conditions permitting seeding and growth of the nanoparticles.

2. The method recited in claim 1 wherein the first ion is a Group 12 element and the second ion is Group 16 element.

3. The method recited in claim 2 wherein the Group 12 element is cadmium.

4. The method recited in claim 2 wherein the Group 16 element is selenium.

5. The method recited in claim 2 the Group 12 element is cadmium and the Group 16 element is selenium.

6. The method recited in claim 1 wherein the molecular cluster compound is [HNEt 3 ] 4 [Cd 10 Se 4 (SPh) 16 ].

7. The method recited in claim 1 wherein the total amount of precursor composition required to form the final desired yield of nanoparticles is added before nanoparticle growth has begun.

8. The method recited in claim 1 wherein the total amount of precursor composition required to form the final desired yield of nanoparticles is added at stages throughout the conversion reaction.

9. The method recited in claim 8 wherein an initial amount of the nanoparticle precursor composition is added before growth of the nanoparticles has begun and one or more further amounts of the nanoparticle precursor composition are added during growth of the nanoparticles.

10. The method recited in claim 1 wherein the first precursor species comprises tri-n-octyl phosphine selenide (TOPSe) and the second precursor species comprises Cd(CH 3 CO 2 ) 2 .

11. The method recited in claim 1 wherein the first precursor species comprises elemental selenium and the second precursor species comprises CdO.

12. The method recited in claim 1 wherein the first precursor species comprises tri-n-octyl phosphine selenide (TOPSe) and the second precursor species comprises Cd(OH) 2 .

13. The method recited in claim 1 wherein the first precursor species comprises tri-n-octyl phosphine selenide (TOPSe) and the second precursor species comprises Me 2 Cd.

14. The method recited in claim 1 wherein the first precursor species comprises tri-n-octyl phosphine selenide (TOPSe) and the second precursor species comprises (C 17 H 35 COO) 2 Cd.

15. The method recited in claim 1 wherein the first precursor species comprises tri-n-octyl phosphine selenide (TOPSe) and the second precursor species comprises CdCO 3 .

16. A method of producing nanoparticles comprising
effecting conversion of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a first ion to be incorporated into the nanoparticles and a separate second precursor species containing a second ion to be incorporated into the nanoparticles,
said conversion being effected in the presence of a molecular cluster compound comprising both the first ion to be incorporated into the nanoparticles and the second ion to be incorporated into the nanoparticles, under conditions permitting seeding and growth of the nanoparticles,
wherein the molecular cluster compound and nanoparticle precursor composition are dissolved in a solvent at a first temperature to form a solution and the temperature of the solution is then increased to a second temperature which is sufficient to initiate seeding and growth of the nanoparticles on the molecular clusters of said compound.

17. A method of producing nanoparticles, the method comprising:
effecting conversion of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a first ion to be incorporated into the nanoparticles and a separate second precursor species containing a second ion to be incorporated into the nanoparticles,
the first precursor species not containing the second ion and the second precursor species not containing the first ion,
said conversion being effected in the presence of a molecular cluster compound comprising both the first ion to be incorporated into the nanoparticles and the second ion to be incorporated into the nanoparticles, under conditions permitting seeding and growth of the nanoparticles,
wherein the nanoparticles comprise outermost layers comprising a capping agent selected from the Group consisting of a mercapto-functionalized amine, a mercaptocarboxylic acid, and a ligand comprising a polymerisable Group.

18. A method of producing nanoparticles, the method comprising:
effecting conversion of a nanoparticle precursor composition to a material of the nanoparticles,
said precursor composition comprising a first precursor species containing a first ion to be incorporated into the nanoparticles and a separate second precursor species containing a second ion to be incorporated into the nanoparticles,
said conversion being effected in the presence of a molecular cluster compound comprising both the first ion to be incorporated into the nanoparticles and the second ion to be incorporated into the nanoparticles, under conditions permitting seeding and growth of the nanoparticles,
wherein the nanoparticles comprise outermost layers comprising a capping agent which is a Lewis base selected from the Group consisting of a mono-dentate ligand, a multi-dentate ligand, a phosphine, a phosphine oxide, an alkyl-amine, an aryl-amine, a pyridine, a thiophene and derivatives thereof.

19. The method recited in claim 18 wherein the capping agent is hexadecylamine.

Assignees

• Nanoco Technologies Ltd

Inventors

• O'Brien Paul
• Pickett Nigel

Classifications

• C09K11/02

  Use of particular materials as binders, particle coatings or suspension media therefor · CPC title

• Y10S977/774

  Exhibiting three-dimensional carrier confinement, e.g. quantum dots · CPC title

• C30B7/005

  Epitaxial layer growth · CPC title

• C09K11/892

  Chalcogenides · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title