Selectively coated CRP components and process for the production thereof

Patent metadata

Field	Value
Publication number	US-9562301-B2
Application number	US-201214001046-A
Country	US
Kind code	B2
Filing date	Feb 24, 2012
Priority date	Feb 25, 2011
Publication date	Feb 7, 2017
Grant date	Feb 7, 2017

Abstract

A component made of carbon fiber reinforced plastic is described, consisting of or comprising a matrix material (M) and carbon fibers embedded into the matrix material (M), wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers, characterized in that the exposed regions(s) of the carbon fibers is or are selectively coated with a layer (S). A process for producing such a component and also an assembly comprising such a component and one or a plurality of further components comprising or consisting of a material such as steel, iron, copper, magnesium or aluminum or alloys thereof are also described.

First claim

The invention claimed is:

1. A component in carbon fiber reinforced plastic, consisting of or comprising:
a matrix material (M) and carbon fibers embedded into the matrix material (M),
wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers,
wherein the exposed region(s) of the carbon fibers of the at least one surface portion A is or are selectively coated with a layer (S), and
wherein the layer (S) is
a layer of dipping paint applied by electrophoretic dip-painting

or
a layer created by electropolymerization.

2. The component as claimed in claim 1 , that can be produced by a process comprising the following steps:
(i) providing a component in carbon fiber reinforced plastic, consisting of or comprising a matrix material (M) and carbon fibers embedded into the matrix material (M),
wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers, and
(ii) coating the exposed regions of the carbon fibers with a layer (S) by
(a) electrophoretic dip-painting, preferably by cataphoretic dip-painting, or
(b) electropolymerization, preferably potentiostatic, galvanostatic or potentiodynamic electropolymerization, preferably potentiostatic electropolymerization,

wherein the exposed regions of the carbon fibers of the at least one surface portion (A) are selectively coated with a layer (S).

3. The component as claimed in claim 2 , wherein the coating of the exposed regions of the carbon fibers with a layer (S) takes place by (a) electrophoretic dip-painting.

4. The component as claimed in claim 1 , wherein the layer (S) is a layer produced by electropolymerization and consists of or comprises a polymer, which is formed from a monomeric unit selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazole and derivatives thereof or comprises one such.

5. The component as claimed in claim 1 , wherein the layer (S) has an average thickness in the range 0.1 through 200 μm.

6. The component as claimed in claim 5 , wherein the layer (S) is
a layer of dipping paint and has an average thickness in the range 1 through 200 μm, preferably in the range 10 through 60 μm, or
a layer created by electropolymerization and has an average thickness in the range 0.1 through 100 μm, preferably in the range 1 through 50 μm.

7. The component as claimed in claim 1 , wherein the matrix material (M) is selected from the group consisting of duroplastics, in particular epoxides, polyurethanes, polyimides, phenol formaldehyde condensation resins, unsaturated polyesters, vinyl ester resins and thermoplastics, in particular polyaryletherketones, polyarylethersulfones, polypropylene, polyamides and polyesters.

8. An assembly consisting of or comprising
(A) a component as claimed in claim 1 and
(B) a component comprising or consisting of a material selected from the group consisting of steel, iron, copper, aluminum, magnesium and alloys thereof,
wherein the component according to (A) and the component according to (B), are connected to one another preferably by means of one or a plurality of contact surfaces.

9. A process for producing a component in carbon fiber reinforced plastic, comprising the steps:
(i) providing a component in carbon fiber reinforced plastic, consisting of or comprising a matrix material (M) and carbon fibers embedded into the matrix material (M), wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers, and
(ii) selectively coating the exposed regions of the carbon fibers of the at least one surface portion (A) with a layer (S) by
(a) electrophoretic dip-painting, or
(b) potentiostatic, galvanostatic or potentiodynamic electropolymerization, and wherein the exposed regions of the carbon fibers of the at least one surface portion (A) are selectively coated with a layer (S).

10. The process as claimed in claim 9 , wherein the coating of the exposed regions of the carbon fibers with a layer (S) takes place by (a) electrophoretic dip-painting including cataphoretic dip-painting.

11. The process as claimed in claim 9 ,
wherein the coating of the exposed regions of the carbon fibers with a layer (S) takes place by (b) potentiostatic electropolymerization using one or a plurality of monomers selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazole and derivatives thereof, and
wherein a layer (S) is obtained, consisting of or comprising a polymer, which is formed from a monomeric unit selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazol and derivatives thereof or comprises one such.

12. The process as claimed in claim 9 , wherein the matrix material (M) is selected from the group consisting of duroplastics, in particular epoxides, polyurethanes, polyimides, phenol formaldehyde condensation resins, unsaturated polyesters, vinyl ester resins and thermoplastics, in particular polyaryletherketones, polyarylethersulfones, polypropylene, polyamides and polyester.

13. A component in carbon fiber reinforced plastic, consisting of or comprising:
a matrix material (M) and carbon fibers embedded into the matrix material (M), wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers,
wherein the exposed region(s) of the carbon fibers is or are selectively coated with a layer (S),
wherein the layer (S) is
a layer of dipping paint applied by electrophoretic dip-painting
or
a layer created by electropolymerization, and

wherein the layer (S) is a layer produced by electropolymerization and consists of or comprises a polymer, which is formed from a monomeric unit selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazole and derivatives thereof or comprises one such.

14. A process for producing a component in carbon fiber reinforced plastic, comprising the steps:
(i) providing a component in carbon fiber reinforced plastic, consisting of or comprising a matrix material (M) and carbon fibers embedded into the matrix material (M), wherein the component has at least one surface portion (A), having one or a plurality of exposed regions of the carbon fibers, and
(ii) coating the exposed regions of the carbon fibers with a layer (S) by
(a) electrophoretic dip-painting, or
(b) potentiostatic, galvanostatic or potentiodynamic electropolymerization,

wherein the exposed regions of the carbon fibers of the at least one surface portion (A) are selectively coated with a layer (S),
wherein the coating of the exposed regions of the carbon fibers with a layer (S) takes place by (b) potentiostatic electropolymerization using one or a plurality of monomers selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazole and derivatives thereof, and
wherein a layer (S) is obtained, consisting of or comprising a polymer, which is formed from a monomeric unit selected from the group consisting of pyrrole, thiophene, aniline, furan, phenol, azulene, carbazole and derivatives thereof or comprises one such.

Assignees

• Plagemann Peter
• Brinkmann Andreas
• Zockoll Anja
• Fangmeier Armin
• Kott Rouven
• Schroder Simone
• Lemckau Thomas
• Airbus Operations Gmbh

Inventors

• Plagemann Peter
• Brinkmann Andreas
• Zockoll Anja
• Fangmeier Armin
• Kott Rouven
• Schroder Simone
• Lemckau Thomas

Classifications

• C25D5/02

  Electroplating of selected surface areas · CPC title

• C25D5/56 Primary

  of plastics · CPC title

• B29C41/14

  Dipping a core {(B29C41/10 takes precedence)} · CPC title

• B29K2307/04

  Carbon · CPC title

• C08J5/042

  with carbon fibres · CPC title