Carbon materials comprising carbon nanotubes and methods of making carbon nanotubes

Patent metadata

Field	Value
Publication number	US-9969619-B2
Application number	US-201113882721-A
Country	US
Kind code	B2
Filing date	Nov 2, 2011
Priority date	Nov 2, 2010
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

The present invention relates to carbon materials comprising carbon nanotubes, powders comprising carbon nanotubes and methods of making carbon nanotubes. In the methods of the present invention, the size and/or formation of floating catalyst particles is closely controlled. The resulting carbon nanotubes typically exhibit armchair chirality and typically have metallic properties. The carbon nanotubes produced by this method readily form bulk materials, which typically have a conductivity of at least 0.7×106 Sm″1 in at least one direction. The invention has particular application to the manufacture of components such as electrical conductors. Suitable electrical conductors include wires (e.g. for electrical motors) and cables (e.g. for transmitting electrical power).

First claim

What is claimed is:

1. A method of producing carbon nanotubes, the method comprising:
providing a plurality of floating catalyst particles, wherein at least 70% by number of the catalyst particles have a diameter less than or equal to 4.5 nm; and
contacting the floating catalyst particles with a gas phase carbon source at a carbon nanotube formation temperature of at least 900° C. to produce carbon nanotubes, wherein the floating catalyst particles are provided by:
initiating growth of the catalyst particles by thermal degradation of a catalyst source substance, the thermal degradation of the catalyst source substance beginning at a first onset temperature being 700° C. or less, and subsequently
arresting the growth of the catalyst particles using an arresting agent the arresting agent being sulfur, the arresting agent being provided to the catalyst particles by thermal degradation of an arresting agent source substance comprising carbon disulphide (CDS), the thermal degradation of the arresting agent source substance beginning at a second onset temperature being 800° C. or less, wherein the second onset temperature is in the range of temperatures from 10° C. more than the first onset temperature to 350° C. more than the first onset temperature; and
wherein the arresting agent source substance, the catalyst source substance and the carbon source pass through the reaction chamber in a gas phase and in a flow direction, wherein the temperature in the reaction chamber varies along the flow direction from the first onset temperature to the second onset temperature to the carbon nanotube formation temperature.

2. The method according to claim 1 wherein the first onset temperature is in the range from 300° C. to 700° C., and wherein the second onset temperature is in the range from 350° C. to 750° C.

3. The method according to claim 1 , further comprising performing the contacting step substantially continuously for at least 10 minutes.

Assignees

• Sundaram Rajyashree
• Koziol Krzysztof Kazimierz
• Lekawa Raus Agnieszka Ewa
• Windle Alan
• Cambridge Entpr Ltd

Inventors

• Sundaram Rajyashree
• Koziol Krzysztof Kazimierz
• Lekawa-Raus Agnieszka Ewa
• Windle Alan

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• C01B2202/36

  Diameter · CPC title

• C01B2202/30

  Purity · CPC title

• C01B32/158 Primary

  Carbon nanotubes · CPC title

• C01B32/164

  involving continuous processes · CPC title