Rubber composition suitable for use as a cap ply in a tire

Patent metadata

Field	Value
Publication number	US-9556351-B2
Application number	US-201514886915-A
Country	US
Kind code	B2
Filing date	Oct 19, 2015
Priority date	Jan 19, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

Disclosed is a rubber composition suitable for use as a cap ply rubber composition. The rubber composition comprises: (a) at least one natural or synthetic rubbery polymer; (b) from 0.1 to 20 phr of at least one hydrazide compound; (c) from 0.1 to 10 phr of at least one methylene donor; (d) from 0.1 to 10 phr of at least one methylene acceptor resin; and (e) from 0.1 to 10 phr of zinc oxide is disclosed. A method of making the same is also disclosed.

First claim

We claim:

1. A tire cap ply comprising at least one textile cord layer coated with a skim rubber composition, the skim rubber composition comprising:
(a) at least one natural or synthetic rubbery polymer;
(b) from 0.1 to 20 phr of at least one hydrazide compound;
(c) from 0.1 to 10 phr of at least one methylene donor;
(d) from 0.1 to 10 phr of at least one methylene acceptor resin; and
(e) from 0.1 to 10 phr of zinc oxide;
wherein the at least one hydrazide compound is selected from a compound represented by Formula I or Formula II shown below:

where:
R 1 is selected from the group consisting of an acyclic aliphatic group having 2-18 carbons, a cyclic aliphatic group having 5-20 carbons, an aromatic group having 6-18 carbons, and an alkylaromatic group having 7-24 carbons,
R 2 is selected from the group consisting of a hydroxy group, an amino group, and a mercapto group,
each of R 3 and R 4 is the same or different and is selected from the group consisting of a hydrogen atom, an alkyl group having 1-18 carbons, a cyclohexyl group, and an aromatic group, and
n is an integer selected from 2 or 3.

2. The tire cap ply of claim 1 , wherein the skim rubber composition has a tan δ value, measured at 60° C., a 1% strain amplitude and a frequency of 52 Hz of at least 0.01 lower than a comparative composition lacking any hydrazide compound.

3. The tire cap ply of claim 1 , wherein the rubbery polymer is selected from the group consisting of polyisoprene, polybutadiene, styrene-butadiene rubber, and combinations thereof.

4. The tire cap ply of claim 1 , wherein the methylene donor is selected from the group consisting of hexamethoxymethylmelamine, hexamethylenetetramine, methoxymethyl melamine, N,N′,N″-trimethyl N,N′,N″-trimethylolmelamine, hexamethylolmelamine, N-methylolmelamine, N,N′-dimethylolmelamine, N,N′,N″-tris(methoxymethyl)melamine, N,N′,N″-tributyl-N,N′,N″-trimethylol-melamine, hexaethoxymethylmelamine, and mixtures thereof.

5. The tire cap ply of claim 1 , wherein the methylene acceptor resin is selected from the group consisting of resorcinol, resorcinolic derivatives, monohydric phenols and derivatives thereof, dihydric phenols and derivatives thereof, polyhydric phenols and derivatives thereof, unmodified phenol novolak resins, modified phenol novolak resin, novolak resins, and mixtures thereof.

6. The tire cap ply of claim 1 , wherein the zinc oxide is present in a total amount ranging from 1 to 5 phr.

7. The tire cap ply of claim 1 , wherein said skim rubber composition is void of a polymaleimide.

8. The tire cap ply of claim 1 , wherein the at least one hydrazide compound is present in an amount of from 0.1 to 5 phr.

9. A method for reducing hysteresis in a tire by utilizing a cap tire ply comprising at least one textile cord layer coated with a skim rubber composition, where the skim rubber composition is made by a process comprising:
mixing at least one natural or synthetic rubbery polymer with:
(a) from 0.1 to 20 phr of at least one hydrazide compound;
(b) from 0.1 to 10 phr of at least one methylene donor;
(c) from 0.1 to 10 phr of at least one methylene acceptor resin; and
(d) from 0.1 to 10 phr of zinc oxide;
wherein a portion of the zinc oxide is mixed in a non-productive mixing stage and the remaining portion of zinc oxide is mixed in a productive mixing stage,
wherein the at least one hydrazide compound is selected from a compound represented by Formula I or Formula II shown below:

where:
R 1 is selected from the group consisting of an acyclic aliphatic group having 2-18 carbons, a cyclic aliphatic group having 5-20 carbons, an aromatic group having 6-18 carbons, and an alkylaromatic group having 7-24 carbons,
R 2 is selected from the group consisting of a hydroxy group, an amino group, and a mercapto group,
each of R 3 and R 4 is the same or different and is selected from the group consisting of a hydrogen atom, an alkyl group having 1-18 carbons, a cyclohexyl group, and an aromatic group, and
n is an integer selected from 2 or 3.

10. The method of claim 9 , wherein the textile cord layer comprises fiber cords selected from nylon, polyester, aramid, polyamine, or rayon.

11. The method of claim 9 , wherein the skim rubber composition has a tan δ value, measured at 60° C., a 1% strain amplitude and a frequency of 52 Hz of at least 0.01 lower than a comparative composition lacking any hydrazide compound.

12. The method of claim 9 , wherein the rubbery polymer is selected from the group consisting of polyisoprene, polybutadiene, styrene-butadiene rubber, and combinations thereof.

13. The method of claim 9 , wherein the methylene donor is selected from the group consisting of hexamethoxymethylmelamine, hexamethylenetetramine, methoxymethyl melamine, N,N′,N″-trimethyl N,N′,N″-trimethylolmelamine, hexamethylolmelamine, N-methylolmelamine, N,N′-dimethylolmelamine, N,N′,N″-tris(methoxymethyl)melamine, N,N′,N″-tributyl-N,N′,N″-trimethylol-melamine, hexaethoxymethylmelamine, and mixtures thereof.

14. The method of claim 9 , wherein the methylene acceptor resin is selected from the group consisting of resorcinol and derivatives thereof, monohydric phenols and derivatives thereof, dihydric phenols and derivatives thereof, polyhydric phenols and derivatives thereof, unmodified phenol novolak resins, modified phenol novolak resin, novolak resins, and mixtures thereof.

15. A method for preparing a skim rubber composition for a textile-cord containing cap ply for a tire, where the skim rubber composition is made by a process comprising mixing:
(a) at least one natural or synthetic rubbery polymer;
(b) from 0.1 to 20 phr of at least one hydrazide compound;
(c) from 0.1 to 10 phr of at least one methylene donor;
(d) from 0.1 to 10 phr of at least one methylene acceptor resin; and
(e) from 0.1 to 10 phr of zinc oxide;
wherein a portion of the zinc oxide is mixed in a non-productive mixing stage and the remaining portion of zinc oxide is mixed in a productive mixing stage,
wherein the at least one hydrazide compound is selected from a compound represented by Formula I or Formula II shown below:

where:
R 1 is selected from the group consisting of an acyclic aliphatic group having 2-18 carbons, a cyclic aliphatic group having 5-20 carbons, an aromatic group having 6-18 carbons, and an alkylaromatic group having 7-24 carbons,
R 2 is selected from the group consisting of a hydroxy group, an amino group, and a mercapto group,
each of R 3 and R 4 is the same or different and is selected from the group consisting of a hydrogen atom, an alkyl group having 1-18 carbons, a cyclohexyl group, and an aromatic group, and
n is an integer selected from 2 or 3.

16. The method of claim 15 , wherein the at least one hydrazide compound is present in an amount of from 0.1 to 5 phr.

17. The method of claim 15 , wherein the at least one hydrazide compound is present in an amount of from 0.1 to 5 phr, the at least one methylene donor is present in an amount of from 0.1 to 5 phr, and the at least one methylene acceptor resin is present in an amount of from 0.1 to 5 phr.

18. The method of claim 15 , wherein the ratio of the amount o

Assignees

• Bridgestone Americas Tire Operations Llc
• Bridgestone Americas Tire Operations Inc

Inventors

• Weingart Natalie
• Stewart David R
• Mcnutt Jamie J
• Kusano Tomohiro

Classifications

• B60C2001/0083

  Compositions of the cap ply layers · CPC title

• C09D107/00 Primary

  Coating compositions based on natural rubber · CPC title

• C08K2003/2296

  of zinc · CPC title

• C08K5/25

  Carboxylic acid hydrazides · CPC title

• B60C1/00 Primary

  Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition · CPC title