Method for producing an anticorrosion coating

Patent metadata

Field	Value
Publication number	US-9556339-B2
Application number	US-201214351475-A
Country	US
Kind code	B2
Filing date	Oct 19, 2012
Priority date	Oct 19, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

The present invention relates to a method for producing an anticorrosion coating, wherein
(1) an anticorrosion primer comprising
(A) at least one organic resin as binder and (B) at least one synthetic layered double hydroxide comprising organic anions is applied directly to a metallic substrate and
(2) a polymer film is formed from the anticorrosion primer applied in stage (1),

the method being characterized in that the at least one synthetic layered double hydroxide (B) comprises at least one organic anion of the following formula (I):

where R 1 ═COO − , SO 3 − , R 2 /R 3 ═NH 2 , OH, H.

The present invention relates, furthermore, to coated metallic substrates coated by the method of the invention. The present invention relates not least to the use of the anticorrosion primer for use in the method of the invention for improving the corrosion resistance of metallic substrates.

First claim

The invention claimed is:

1. A method for producing an anticorrosion coating, comprising:
(1) applying directly to a metallic substrate: an anticorrosion primer comprising:
(A) at least one organic polymer that is free from carboxylate groups and carboxylic acid groups as a binder and
(B) at least one synthetic layered double hydroxide comprising organic anions and

(2) forming a polymer film from the anticorrosion primer applied in stage (1),
the method being characterized in that
the at least one synthetic layered double hydroxide (B) comprises at least one organic anion of the following formula (I):

where
R 1 ═COO − , SO 3 − ,
R 2 /R 3 ═NH 2 , OH, H.

2. The method according to claim 1 , wherein the anticorrosion primer comprises at least one polyvinylbutyral resin and/or epoxy resin as organic polymer (A).

3. The method according to claim 2 , wherein the anticorrosion primer comprises at least one epoxy resin as organic polymer (A) and at least one polyamine as crosslinking agent.

4. The method according to claim 1 , wherein the anticorrosion primer is a two-component system.

5. The method according to claim 1 , wherein the formula (I) R 2 ═R 3 ═H is excluded.

6. The method according to claim 1 , wherein the at least one synthetic layered double hydroxide (B) comprising organic anions has the general formula (II)
[M 2+ (1-x) M 3+ x (OH) 2 ][A y− (x/y) ].n H 2 O  (II)

where M 2+ stands for divalent metallic cations, M 3+ stands for trivalent metallic cations and A y− stands for anions of average valence y, the anions at least proportionally comprising at least one organic anion which is obtainable from a compound of the formula (I), x adopts a value of 0.05 to 0.5 and n adopts a value between 0 and 10.

7. The method according to claim 6 , wherein
the divalent metallic cations M 2+ are selected from the group consisting of Zn 2+ , Mg 2+ , Ca 2+ , Cu 2+ , Ni 2+ , Co 2+ , Fe 2+ , Mn 2+ , Cd 2+ , Pb 2+ , Sr 2+ , and mixtures thereof,
the trivalent metallic cations M 3+ are selected from the group consisting of Al 3+ , Bi 3+ , Fe 3+ , Cr 3+ , Ga 3+ , Ni 3+ , Co 3+ , Mn 3+ , V 3+ , Ce 3+ , La 3+ , and mixtures thereof,
x is a value of 0.05 to 0.5, and
n is a value of 0 to 10.

8. The method according to claim 1 , wherein the at least one compound of the formula (I) is selected from the group consisting of 3,4-dihydroxybenzoic acid and also anilinesulfonic acids encompassed by the formula (I).

9. The method according to claim 8 , wherein m-anilinesulfonic acid is selected as compound of the formula (I).

10. The method according to claim 1 , wherein the at least one synthetic layered double hydroxide (B) comprising organic anions is prepared by direct coprecipitation or anionic exchange reaction.

11. The method according to claim 1 , wherein the fraction of the at least one synthetic layered double hydroxide (B) comprising organic anions is 5% to 15% by weight, based on the total amount of the anticorrosion primer.

12. The method of claim 1 , further comprising, after the formation of the polymer film (2),
(3) applying at least one further coating material to produce a multicoat coating.

13. The method according to claim 1 , wherein the metallic substrate is selected from the group consisting of aluminum, aluminum alloys.

14. The method of claim 1 , wherein the anticorrosion primer is effective for improving the corrosion resistance of the metallic substrate.

15. A coated metallic substrate coated by the method according to claim 1 .

Assignees

• Basf Coatings Gmbh
• Université´Blaise Pascal - Clermont II
• Univ Blaise Pascal—Clermont Ii

Inventors

• Hintze-Brüning Horst
• Kues Jan-Bernd
• Sinnwell Sebastian
• Wapner Kristof
• Leroux Fabrice
• Stimpfling Thomas

Classifications

• C09D15/00 Primary

  Woodstains · CPC title

• C09D4/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title

• C09D5/086

  Organic or non-macromolecular compounds · CPC title

• C08K5/18

  with aromatically bound amino groups · CPC title

• C08K5/42

  Sulfonic acids; Derivatives thereof · CPC title