Process for the continuous thermal removal of binder from a metallic and/or ceramic shaped body produced by injection molding, extrusion or pressing using a thermoplastic molding composition

Patent metadata

Field	Value
Publication number	US-9556072-B2
Application number	US-201013379894-A
Country	US
Kind code	B2
Filing date	Jun 22, 2010
Priority date	Jun 25, 2009
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

The invention relates to a process for the continuous thermal removal of binder from a metallic and/or ceramic shaped body which has been produced by injection molding, extrusion or pressing using a thermoplastic composition and comprises at least one polyoxymethylene homopolymer or copolymer as binder in a binder removal oven, which comprises the steps (a) removal of binder from the shaped body in a binder removal oven at a temperature which is from 5 to 20° C. below, preferably from 10 to 15° C. below, the temperature of a second temperature stage over a period of from 4 to 12 hours in a first temperature stage in an oxygen-comprising atmosphere, (b) removal of binder from the shaped body at a temperature in the range >160 to 200° C. over a period of from 4 to 12 hours in an oxygen-comprising atmosphere in a second temperature stage and (c) removal of binder from the shaped body at a temperature in the range from 200 to 600° C. over a period of from 2 to 8 hours in a third temperature stage in an oxygen-comprising or neutral or reducing atmosphere, with the shaped bodies being transported through the binder removal oven during process steps (a) and (b).

First claim

The invention claimed is:

1. A process for the continuous thermal removal of binder from a metallic and/or ceramic shaped body which has been produced by injection molding, extrusion or pressing using a thermoplastic composition and comprises at least one polyoxymethylene homopolymer or copolymer as binder, wherein the binder comprises at least 80% by weight of polyoxymethylene, in a binder removal oven, which comprises the steps
(a) Removal of binder from the shaped body in a binder removal oven at a temperature which is from 5 to 20° C. below the temperature of a second temperature stage over a period of from 4 to 12 hours in a first temperature stage in an oxygen-comprising atmosphere,
(b) Removal of binder from the shaped body at a temperature in the range >160 to 200° C. over a period of from 4 to 12 hours in an oxygen-comprising atmosphere in a second temperature stage and
(c) Removal of binder from the shaped body at a temperature in the range from 200 to 600° C. over a period of from 2 to 8 hours in a third temperature stage in an oxygen-comprising or neutral or reducing atmosphere,
with the shaped bodies being transported through the binder removal oven during process steps (a) and (b) wherein if the shaped body is the metal shaped body then the molding composition comprises metal powders wherein the metal powder is selected from the group consisting of Fe, Cu, Nb, Ti, Mn, V, Ni, Cr, Co, Mo, W and Si and the metal powder can be in the form of an alloy.

2. The process according to claim 1 , wherein the shaped body is heated to the temperature of the first temperature stage at a heating rate of from 1 to 4° C./minute before process step (a) is carried out.

3. The process according to claim 1 , wherein process steps (a), (b) and (c) are carried out in the same binder removal oven and the shaped body is transported through the binder removal oven during process steps (a), (b) and (c).

4. The process according to claim 1 , wherein an oven having at least two successive treatment chambers is used as binder removal oven.

5. The process according to claim 1 , wherein an oven having gas guide devices which effect the flow of the oxygen-comprising atmosphere onto the shaped body transverse to the transport direction of the shaped body during process step (a) and/or (b) and/or (c) is used as binder removal oven.

6. The process according to claim 1 for the removal of binder from ceramic shaped bodies.

7. The process according to claim 1 for the removal of binder from metallic shaped bodies.

8. A process for producing metallic and/or ceramic shaped bodies from a thermoplastic composition by
(d) shaping of the thermoplastic composition by injection molding, extrusion or pressing to form a green body,
(e) removal of the binder by a process according to claim 1
(f) subsequent sintering of the green body from which the binder has been removed in step (e).

9. The process according to claim 1 with the proviso the metal shaped body does not contain an aluminum alloy.

Assignees

• Ter Maat Johan
• Wohlfromm Hans
• Bloemacher Martin
• Thom Arnd
• Kern Andreas
• Basf Se

Inventors

• Ter Maat Johan
• Wohlfromm Hans
• Bloemacher Martin
• Thom Arnd
• Kern Andreas

Classifications

• C04B35/58014

  based on titanium nitrides, e.g. TiAlON · CPC title

• C04B35/581

  based on aluminium nitride · CPC title

• B22F2998/00

  Supplementary information concerning processes or compositions relating to powder metallurgy · CPC title

• C04B2235/661

  Multi-step sintering · CPC title

• B22F3/1021

  Removal of binder or filler (removal of binder from ceramics C04B35/638) · CPC title