Process for the purification of a residue

Patent metadata

Field	Value
Publication number	US-9555343-B2
Application number	US-201213984114-A
Country	US
Kind code	B2
Filing date	Feb 9, 2012
Priority date	Feb 9, 2011
Publication date	Jan 31, 2017
Grant date	Jan 31, 2017

Abstract

Process for the purification of a residue containing solids and mother liquor and having a chloride ion content greater than 5000 ppm by weight relative to the weight of the residue which comprises (a) piston washing said residue with a washing fluid and (b) recovering a purified residue.

First claim

The invention claimed is:

1. A process for the purification of a residue obtained from cement kiln dust, said residue containing solids and a mother liquor and having a chloride ion content greater than 5000 ppm by weight relative to the weight of the residue, said process comprising: (a) a piston washing operation, wherein a washing fluid is transported through a layer of said residue by applying a force to said residue layer; (b) recovering a purified residue; and (c) recovering and treating the washing fluid removed from the washing operation (a) to recover KCl dissolved in said washing fluid;
wherein the piston washing operation (a) is carried out by conveying the washing fluid to the residue placed on a vacuum belt filter and wherein the piston washing operation (a) comprises at least 2 washing steps and is carried out in a counter-current mode and wherein the washing fluid removed from a first washing step is recovered and used as washing fluid for a further washing step.

2. The process according to claim 1 , wherein said washing fluid is water.

3. The process according to claim 1 , wherein the piston washing operation (a) is carried out under conditions minimizing formation of cracks in the residue.

4. The process according to claim 1 , wherein the thickness of the residue layer is from 0.8 to 3 cm.

5. The process according to claim 1 , wherein the ratio of the total volume of said washing fluid supplied to the residue to the volume of said mother liquor in the residue supplied to the washing operation (a) is from 0.5 to 5.

6. The process according to claim 1 , wherein the washing fluid is applied to the residue by spraying.

7. The process according to claim 1 , wherein the chloride content of the residue is from 3 to 95% wt.

8. The process according to claim 1 , further comprising expelling said washing fluid from said residue with a gas stream.

9. The process according to claim 8 , wherein the expelling step of the washing fluid from the residue is carried under conditions allowing to obtain a washing fluid content in the residue of at most 40% weight relative to the weight of the residue.

10. The process according to claim 8 , wherein the chloride content of the purified residue obtained after expelling said washing fluid is less than 5000 ppm wt.

11. The process according to claim 1 , wherein the residue is obtained by dissolving a water-soluble fraction of cement kiln dust from cement production with water.

12. A process for the manufacture of cement or a metal which comprises
a. Carrying out a process for the purification of a residue obtained from cement kiln dust, said residue containing solids and a mother liquor and having a chloride ion content greater than 5000 ppm by weight relative to the weight of the residue, said process comprising: (a) a piston washing operation, wherein a washing fluid is transported through a layer of said residue by applying a force to said residue layer; (b) recovering a purified residue; and (c) recovering and treating the washing fluid removed from the washing operation (a) to recover KCl dissolved in said washing fluid;
wherein the piston washing operation (a) is carried out by conveying the washing fluid to the residue placed on a vacuum belt filter and wherein the piston washing operation (a) comprises at least 2 washing steps and is carried out in a counter-current mode and wherein the washing fluid removed from a first washing step is recovered and used as washing fluid for a further washing step; and

b. Using said purified residue as a raw material for said manufacture.

13. The process according to claim 8 , wherein the expelling of the washing fluid from the residue is carried under conditions allowing to obtain a washing fluid content in the residue of from 30 to 35% weight relative to the weight of the residue; and wherein the residue is non-thixotropic.

14. The process according to claim 1 , wherein the cement kiln dust is cement by-pass dust.

Assignees

• Blondel Jean-Marie
• Humblot Cedric
• Solvay

Inventors

• Blondel Jean-Marie
• Humblot Cedric

Classifications

• C04B7/60

  Methods for eliminating alkali metals or compounds thereof {, e.g. from the raw materials or during the burning process; methods for eliminating other harmful components (avoiding environmental pollution C04B7/364)} · CPC title

• Y02W30/95

  Cross-Sectional Technologies · mapped topic

• B01D11/0288

  Applications, solvents · CPC title

• B01D11/02 Primary

  of solids · CPC title

• C04B18/162

  Cement kiln dust; Lime kiln dust · CPC title