Method for oligomerising alkenes using the ITQ-39 zeolite

Patent metadata

Field	Value
Publication number	US-9550706-B2
Application number	US-201514599544-A
Country	US
Kind code	B2
Filing date	Jan 19, 2015
Priority date	Jul 19, 2012
Publication date	Jan 24, 2017
Grant date	Jan 24, 2017

Abstract

The invention relates to a heterogeneous method for oligomerising alkenes in order to produce hydricarbons within a diesel fraction in the present of a catalyst based on the ITQ-39 zeolite. The oligomerisation method described in the present invention includes at least: a. feeding a catalyst containing at least the ITQ-39 zeolitic material into the reactor; b. supplying the reactor with a stream that includes at least one olefinic compound; and c. enabling the catalyst containing at least the ITQ-39 material and the organic compound to remain in contact during the time required for the reaction to take place.

First claim

The invention claimed is:

1. A process of oligomerization of olefinic compound for producing hydrocarbons, comprising at least:
a. introducing a catalyst containing at least a zeolitic material ITQ-39 in a reactor;
b. feeding the reactor with a stream comprising at least one olefinic compound;
c. allowing the catalyst containing at least the zeolitic material ITQ-39 and the at least one olefinic compound to remain in contact the time necessary for the oligomerization to take place.

2. The process according to claim 1 , wherein the olefinic compound is selected from the group consisting of ethylene, propene, butenes, pentenes, hexenes or mixtures of same.

3. The process according to claim 1 , wherein the olefinic compound is present in the stream at a concentration between 10 and 100% by weight.

4. The process according to claim 1 , wherein the zeolitic material ITQ-39 is in its acid form.

5. The process according to claim 1 , wherein the zeolitic material ITQ-39 has been modified to generate additional mesoporosity.

6. The process according to claim 1 , wherein the zeolitic material ITQ-39 has a external surface that has been deactivated through selectivation processes.

7. The process according to claim 1 , wherein the zeolitic material ITQ-39 has been selectivated through treatments with oxalic acid.

8. The process according to claim 1 , wherein the zeolitic material ITQ-39 has been selectivated through treatments with ethylenediaminetetraacetic acid (EDTA).

9. The process according to claim 1 , wherein the catalyst comprises a matrix formed by, at least, one oxide selected from the group consisting of amorphous oxide, low crystallinity oxide and combinations thereof.

10. The process according to claim 1 , wherein the catalyst comprises a matrix formed by, at least, one oxide selected from the group consisting of alumina, silica-alumina, silica, clays, magnesium oxide, titanium oxide, boron oxide, zirconium oxide, and combinations thereof.

11. The process according to claim 1 , wherein the catalyst comprises a matrix formed by gamma-alumina.

12. The process according to claim 1 , wherein the catalyst comprises a matrix that comprises at least aluminum phosphates, zirconium phosphates, coal, aluminates and combinations thereof.

13. The process according to claim 1 wherein the catalyst comprises at least one hydrogenating Group VIII metal and combinations thereof.

14. The process according to claim 1 , wherein the catalyst comprises at least one metal selected from the group consisting of iridium, ruthenium, rhodium, rhenium, palladium, platinum, iron, cobalt, nickel and combinations thereof.

15. The process according to claim 1 wherein the catalyst comprises at least, a promoter agent selected from phosphorus, boron and combinations thereof.

16. The process according to claim 1 wherein the catalyst comprises at least, a promoter that is phophorus.

17. The process according to claim 1 , wherein the catalyst comprises at least, an element of Group VIIB.

18. The process according to claim 1 that it is carried out at a temperature between 100 and 500° C., at a pressure between 0, 1 and 200 bar and at a spatial rate (WHSV) between 0.1-100 h −1 .

19. The process according to claim 1 , that it is carried out in the presence of hydrogen.

Assignees

• Corma Canós Avelino
• Martínez Sánchez Cristina
• Exxonmobil Chemical Patents Inc

Inventors

• Corma Canós Avelino
• Martínez Sánchez Cristina

Classifications

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J29/72

  containing iron group metals, noble metals or copper · CPC title

• C07C2/12 Primary

  with crystalline alumino-silicates {or with catalysts comprising} molecular sieves · CPC title

• B01J2229/37

  Acid treatment · CPC title