Diazepane Derivatives, Processes for their Preparation, and Uses thereof for the Amelioration, Prevention and/or Treatment of Mental and Neurological Diseases
US-2024246957-A1 · Jul 25, 2024 · US
US9302971B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9302971-B2 |
| Application number | US-201414515823-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 16, 2014 |
| Priority date | Nov 1, 2013 |
| Publication date | Apr 5, 2016 |
| Grant date | Apr 5, 2016 |
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This invention relates to the production of terephthalic acid by 1) cycloaddition of 2,5 substituted furan (such as 2,5-bis hydroxymethylfuran or 5-hydroxymethylfurfural) and ethylene, and 2) the subsequent oxidation of the dehydrated cycloaddition product to terephthalic acid. The invention relates more particularly to overall biobased pathways for making terephthalic acid from carbohydrates such as hexoses (e.g., glucose or fructose).
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We claim: 1. A terephthalic acid production process comprising reacting substituted furan with ethylene under cycloaddition reaction conditions and in the presence of a catalyst to produce a bicyclic ether, dehydrating the bicyclic ether to produce a substituted phenyl and thereafter oxidizing the substituted phenyl to terephthalic acid, wherein the substituted furan is represented by the formula:…
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
Chemistry & Metallurgy · mapped topic
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