Composition and method for preventing or reducing engine knock and pre-ignition in high compression spark ignition engines

Patent metadata

Field	Value
Publication number	US-10119093-B2
Application number	US-201615161718-A
Country	US
Kind code	B2
Filing date	May 23, 2016
Priority date	May 28, 2015
Publication date	Nov 6, 2018
Grant date	Nov 6, 2018

Abstract

A lubricant composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine lubricated with a formulated oil. The formulated oil has a composition including at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A fuel composition for high compression spark ignition engines that contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). A method for preventing or reducing engine knock and pre-ignition in an engine by using a fuel additive composition in a gasoline fuel composition. The fuel additive composition contains at least one bismuth-containing compound (e.g., a bismuth salt of a carboxylic acid). The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.

First claim

What is claimed is:

1. A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil, said formulated oil having a composition comprising from 98 to 99 mass % of at least one branched hydrocarbon having greater than 20 carbon atoms and having at least 50% of the carbons in the form of methyl groups and from 1 to 2 mass % of bismuth naphthenate, based on the total weight of the lubricating oil, and
wherein the lubricating oil, when 5% of which is added to isooctane, maintains at least 101.55% of the isooctane combustion delay, using the equipment and test conditions as determined by ASTM D7668.

2. The method of claim 1 wherein the bismuth naphthenate is present in an amount sufficient to provide from 1730 to 3460 parts per million (ppm) of bismuth in the lubricating oil.

3. The method of claim 1 wherein the at least one branched hydrocarbon comprises hydrogenated polyisobutene.

4. The method of claim 1 wherein the lubricating oil further comprises a Group I, Group II, Group III, Group IV, Group V base oil, or mixtures thereof.

5. The method of claim 1 wherein the lubricating oil further comprises one or more of a detergent, dispersant, antiwear agent, viscosity index improver, antioxidant, pour point depressant, corrosion inhibitor, metal deactivator, seal compatibility additive, anti-foam agent, inhibitor, anti-rust additive, and friction modifier.

6. The method of claim 1 wherein the high compression spark ignition engine has a compression ratio of at least 13.

7. The method of claim 1 wherein the high compression spark ignition engine has a compression ratio of at least 15.

8. The method of claim 1 wherein the high compression spark ignition engine is a super-charged engine or a turbo-charged engine.

9. The method of claim 1 wherein the lubricating oil is used with a gasoline fuel with Research Octane Number (RON) or Motor Octane Number (MON) higher than 95.

10. The method of claim 1 wherein the lubricating oil is used with a gasoline fuel comprising essentially isooctane.

11. The method of claim 1 wherein the pre-ignition is low speed pre-ignition (LSPI).

12. A lubricating engine oil for high compression spark ignition engine having a composition comprising, based on the total weight of the lubricating oil, from 1 to 2 mass % of bismuth naphthenate, and from 98 to 99 mass % of at least one branched hydrocarbon having greater than 20 carbon atoms and having at least 50% of the carbons in the form of methyl groups, and
wherein the lubricating oil, when 5% of which is added to isooctane, maintains at least 101.55% of the isooctane combustion delay, using the equipment and test conditions as determined by ASTM D7668.

13. The lubricating engine oil of claim 12 wherein the bismuth naphthenate is present in an amount sufficient to provide from 1730 to 3460 parts per million (ppm) of bismuth in the lubricating oil.

14. The lubricating engine oil of claim 12 wherein the lubricating oil is used with a gasoline fuel with Research Octane Number (RON) or Motor Octane Number (MON) higher than 95.

15. The lubricating engine oil of claim 12 wherein the lubricating oil is used with a gasoline fuel comprising essentially isooctane.

Assignees

• Exxonmobil Res & Eng Co

Inventors

• Gao Jason Z
• Choi Eugine
• Boland Matthew W
• Salvi Luca

Classifications

• C10N2040/255

  Gasoline engines · CPC title

• C10M2207/141

  monocarboxylic · CPC title

• C10M133/18

  of carbonic or haloformic acids · CPC title

• C10M135/18

  thiocarbamic type, e.g. containing the groups [IMAGE cpc-sch-C10M-1027.gif] · CPC title

• C10M2207/12

  having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms · CPC title