Process to separate phosgene and hydrogen chloride from a fluid stream comprising phosgene and hydrogen chloride

Patent metadata

Field	Value
Publication number	US-9533885-B2
Application number	US-201214117892-A
Country	US
Kind code	B2
Filing date	Jun 15, 2012
Priority date	Aug 19, 2011
Publication date	Jan 3, 2017
Grant date	Jan 3, 2017

Abstract

A process according to the invention is a process to separate an initial fluid stream comprising phosgene and hydrogen chloride in at least a first and a second fluid stream, said first fluid stream being a hydrogen chloride enriched and phosgene depleted gaseous stream, said second fluid stream being a hydrogen chloride depleted and phosgene enriched stream. The separation is performed by feeding said initial fluid stream to a membrane separation unit, said membrane separation unit separating said initial fluid stream in a first and a second fluid stream.

First claim

The invention claimed is:

1. A process for the conversion of an amine to a corresponding isocyanate component by phosgenation of said amine, the process comprising the steps of
providing a reaction mixture comprising an amine and phosgene to a phosgenation reactor;
at least partially converting the amine and the phosgene in said reaction mixture into the corresponding isocyanate component and hydrogen chloride, thereby providing a liquid isocyanate stream comprising said isocyanate component, phosgene and hydrogen chloride;
removing at least part of said phosgene and at least part of said hydrogen chloride from said liquid isocyanate stream thereby providing an initial gaseous stream comprising phosgene and hydrogen chloride;
evacuating at least part of the hydrogen chloride from said initial gaseous stream, said evacuation comprises a process comprising feeding said initial gaseous stream to a membrane separation unit having a retentate side and a permeate side, said membrane separation unit separating said initial gaseous stream into a first and a second gaseous stream.

2. The process according to claim 1 , wherein removing at least part of said phosgene and at least part of said hydrogen chloride from said liquid isocyanate stream comprises
removing at least part of said phosgene and at least part of said hydrogen chloride from said liquid isocyanate stream as a gaseous mixture; and
at least partially condensing the gaseous mixture providing a liquid intermediate mixture and said initial gaseous stream.

3. The process according to claim 2 , wherein the second gaseous stream of the membrane separation unit is condensed and blended with the liquid intermediate mixture.

4. The process according to claim 2 , wherein said condensing includes cooling the gaseous mixture to a temperature in the range of 20 to 60° C.

5. The process according to claim 2 , wherein said condensing includes cooling the gaseous mixture to a temperature in the range of −40 to 20° C.

6. The process according to claim 2 , wherein the first gaseous stream of the membrane separation unit is distilled and/or stripped and/or washed with a solvent further reducing the content of phosgene in the first gaseous stream.

7. The process according to claim 1 , wherein said reaction mixture of an amine and phosgene further comprises a solvent.

8. The process according to claim 7 , wherein said initial gaseous stream further comprises at least part of said solvent.

9. The process according to claim 1 , wherein removing at least part of said phosgene and at least part of said hydrogen chloride from said liquid isocyanate stream comprises:
removing at least part of said phosgene and at least part of said hydrogen chloride from said liquid isocyanate stream as a gaseous mixture;
at least partially condensing the gaseous mixture providing a liquid intermediate mixture and a gaseous intermediate mixture;
distilling and/or stripping and/or washing with a solvent of the gaseous intermediate mixture and/or the liquid intermediate mixture to provide a gaseous vent mixture comprising hydrogen chloride and phosgene.

10. The process according to claim 1 , wherein said first gaseous stream comprises a hydrogen chloride enriched and phosgene depleted gaseous stream, and said second gaseous stream comprises a hydrogen chloride depleted and phosgene enriched stream.

11. The process according to claim 1 , wherein the pressure at the retentate side is in the range of 1.2 to 4 bara and the pressure at the permeate side is in the range of 0.1 to 0.9 bara.

Assignees

• Mouazer Rabah
• Scheffer Ramon
• Huntsman Int Llc

Inventors

• Mouazer Rabah
• Scheffer Ramon

Classifications

• B01D2257/2045

  Hydrochloric acid · CPC title

• C01B31/28

  Chemistry & Metallurgy · mapped topic

• Y02P20/154

  Cross-Sectional Technologies · mapped topic

• C07C263/20

  Separation; Purification · CPC title

• C01B7/0706 Primary

  of hydrogen chloride · CPC title