Method for producing isocyanates in the gas phase

Patent metadata

Field	Value
Publication number	US-9328064-B2
Application number	US-201514790478-A
Country	US
Kind code	B2
Filing date	Jul 2, 2015
Priority date	May 5, 2010
Publication date	May 3, 2016
Grant date	May 3, 2016

Abstract

The invention relates to a process for the preparation of isocyanates by reaction of the corresponding amines with phosgene in the gas phase, wherein a diluent containing between 90.0000% by weight and 99.9999% by weight of substances which are inert in the phosgenation process and between 0.0001% by weight and 10.0000% by weight of oxygen is present during the conversion of the amine into the gas phase and the molar ratio of amine to oxygen (O2) is ≧1,000:1.

First claim

The invention claimed is:

1. A process for preparing an isocyanate by reaction of the corresponding amine with phosgene in the gas phase, wherein
(i) the amine is converted into the gas phase in a vaporization space in the presence of from >0.10% by weight to 25% by weight of a diluent, based on the total weight of diluent and amine;
(ii) the gaseous stream obtained from (i) containing amine and diluent is reacted with a gaseous phosgene stream in a reaction space to give the corresponding isocyanate;
characterized in that
the diluent employed in step (i) contains between 90.0000% by weight and 99.9950% by weight of substances which are inert in the phosgenation process and between 0.0050% by weight and 10.0000% by weight of oxygen, in each case based on the weight of the diluent, and
the molar ratio of amine to oxygen (O 2 ) in step (i) in the vaporization space is ≧1,000:1; wherein the amine is toluylenediamine (TDA).

2. Process according to claim 1 , in which in step (i) the amine is converted into the gas phase in the presence of >0.10% by weight to 10% by weight of a diluent which contains between 99.0000% by weight and 99.9950% by weight of substances which are inert in the phosgenation process and between 0.0050% by weight and 1.0000% by weight of oxygen, in each case based on the weight of the diluent, and wherein the molar ratio of amine to oxygen in the vaporization space is in the range between 1,000:1 and 1,000,000:1.

3. Process according to claim 1 , in which in step (i) the amine is converted into the gas phase in the presence of >0.20% by weight to 5.0% by weight of a diluent which contains between 99.5000% by weight and 99.9900% by weight of substances which are inert in the phosgenation process and between 0.0100% by weight and 0.5000% by weight of oxygen, in each case based on the weight of the diluent, and wherein the molar ratio of amine to oxygen in the vaporization space is in the range between 10,000:1 and 50,000:1.

4. Process according to claim 1 , in which the molar ratio of amine to oxygen (O2) in step (i) in the vaporization space of ≧1,000:1 is maintained by reducing the absolute volume flow of the diluent fed to the vaporization space.

5. Process according to claim 1 , in which the diluent employed in step (i) at least partially contains the inert substance recycled after the reaction to give the isocyanate has taken place in step (ii).

6. Process according to claim 1 , in which the substance which is inert in the phosgenation process is nitrogen.

Assignees

• Bayer Ip Gmbh
• Bayer Materialscience Ag

Inventors

• Bruns Rainer
• Lorenz Wolfgang
• Rausch Andreas Karl
• Wershofen Stefan
• Loddenkemper Tim

Classifications

• C07C263/10 Primary

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• C07C265/14

  containing at least two isocyanate groups bound to the same carbon skeleton · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title