Lithium secondary battery cathode

Patent metadata

Field	Value
Publication number	US-9515347-B2
Application number	US-201113286514-A
Country	US
Kind code	B2
Filing date	Nov 1, 2011
Priority date	Nov 17, 2010
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

An object of the present invention is to provide a lithium secondary battery cathode which can more improve characteristics of the battery. The cathode of the present invention includes an electroconductive cathode current collector, a plurality of plate-like particle formed of a cathode active material, and a binder containing microparticles formed of the cathode active material and being smaller than the plate-like particles. The plate-like particles are formed so as to have an aspect ratio of 4 to 50. The plate-like particles are arranged such that the particles cover the surface of the cathode current collector surface at a percent area of 85 to 98%. The binder is disposed so as to intervene between two adjacent plate-like particles.

First claim

The invention claimed is:

1. A lithium secondary battery cathode comprising:
an electroconductive current collector;
a plurality of plate-like particles formed of a cathode active material:
wherein said particles are formed so as to have an aspect ratio of 4 to 50, the aspect ratio being a value obtained by dividing a particle size d by a thickness t, wherein the particle size d is a size of the particle as measured in a direction orthogonal to the thickness direction which defines the thickness t,
wherein said particles are arranged in a single layer so as to cover a cathode-layer-contact surface of said electroconductive current collector at a percent area of 85 to 98% such that spaces are formed between adjacent particles, and
wherein an inner plate surface, which is one of the two plate surfaces of each of the particles orthogonal to the thickness direction, is directly joined to and in contact with the cathode-layer-contact surface; and

a binder containing microparticles formed of the cathode active material, said microparticles being smaller than the plate-like particles, said binder intervening between two adjacent plate-like particles such that the binder fills the space therebetween along the juxtaposition direction of the plate-like particles.

2. A lithium secondary battery cathode according to claim 1 , wherein the binder is disposed so as to cover an outer plate surface, which is the other one of the two plate surfaces of each of the plate-like particles.

3. A lithium secondary battery cathode according to claim 2 , which satisfies the relationship: 0.02≦r≦0.2, wherein r is t2/t, and t2 represents the thickness of the portion of the binder covering the plate-like particles contained in the binder.

4. A lithium secondary battery cathode according to claim 1 , wherein the plate-like particles have a layered rock salt structure, the ratio of intensity of diffraction by the 003) plane to intensity of diffraction by the (104) plane, (003)/(104), as obtained through X-ray diffraction of surfaces of the plate-like particles, is 1.6 or less.

5. A lithium secondary battery cathode according to claim 2 , wherein the plate-like particles have a layered rock salt structure, the ratio of intensity of diffraction by the 003) plane to intensity of diffraction by the (104) plane, (003)/104), as obtained through X-ray diffraction of surfaces of the plate-like particles, is 1.6 or less.

6. A lithium secondary battery cathode according to claim 3 , wherein the plate-like particles have a layered rock salt structure, the ratio of intensity of diffraction by the (003) plane to intensity of diffraction by the (104) plane, (003)/(104), as obtained through X-ray diffraction of surfaces of the plate-like particles, is 1.6 or less.

7. A lithium secondary battery cathode comprising:
an electroconductive current collector;
a plurality of plate-like particles formed of a cathode active material;
wherein said particles are formed so as to have an aspect ratio of 4 to 50, the aspect ratio being a value obtained by dividing a particle size d by a thickness t, wherein the particle size d is a size of the particle as measured in a direction orthogonal to the thickness direction which defines the thickness t,
wherein said particles are arranged so as to cover a cathode-layer-contact surface of said electroconductive current collector at a percent area of 85 to 98% such that spaces are formed between adjacent particles, and
wherein an inner plate surface, which is one of the two plate surfaces of each of the particles orthogonal to the thickness direction, is directly joined to and in contact with the cathode-layer-contact surface; and

a binder containing microparticles formed of the cathode active material, said microparticles being smaller than the plate-like particles, said binder intervening between two adjacent plate-like particles such that the binder fills the space therebetween along the juxtaposition direction of the plate-like particles,
wherein the binder is disposed so as to cover an outer plate surface, which is the other one of the two plate surfaces of each of the plate-like particles.

Assignees

• Okada Shigeki
• Nanataki Tsutomu
• Kobayashi Nobuyuki
• Yoshikawa Jun
• Urakawa Akira
• Ngk Insulators Ltd

Inventors

• Okada Shigeki
• Nanataki Tsutomu
• Kobayashi Nobuyuki
• Yoshikawa Jun
• Urakawa Akira

Classifications

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M10/0585

  of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators · CPC title

• H01M4/623

  fluorinated polymers · CPC title

• H01M4/621

  Binders · CPC title