Method for reducing slag

Patent metadata

Field	Value
Publication number	US-9512497-B2
Application number	US-201414446283-A
Country	US
Kind code	B2
Filing date	Jul 29, 2014
Priority date	Jan 31, 2012
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

Disclosed herein is a method of reducing slag, including the steps of: examining the components of slag to be reduced, and setting a target composition ratio after reduction; determining the mixing ratio and input amount of a complex reducing agent of a plurality of reducing agents in accordance with the set target composition ratio to determine the complex reducing agent; and supplying the complex reducing agent into molten slag to reduce the slag. The method is advantageous in that the reduction efficiency of slag can be maximized, various kinds of reducing agents can be efficiently used, and the recovery amount of valuable metals can be increased, thus reducing cost.

First claim

What is claimed is:

1. A method of reducing slag generated by scrap melting in an electric furnace, comprising:
examining components of slag to be reduced, and setting a target composition ratio after reduction;
determining a mixing ratio and an input amount of a complex reducing agent of a plurality of reducing agents based on the set target composition ratio; and
supplying the complex reducing agent into molten slag to reduce the slag,
wherein the determining a mixing ratio and an input amount includes:
determining the mixing ratio of a plurality of complex reducing agents and the mixing ratio of the reducing agents in a particular complex reducing agent;
calculating the input amount of the particular complex reducing agent and an input amount of a slag forming agent based on an amount of slag to be reduced;
calculating a reaction product obtained by a reaction of the slag with the particular complex reducing agent after supplying the particular complex reducing agent;
calculating a composition of the slag changed by the reaction product;
comparing the composition of the slag with the target composition ratio to determine the mixing ratio of the particular complex reducing agent when the composition of the slag and the target composition ratio are different; and
determining a corresponding complex reducing agent as a final reducing agent when the composition of the slag and the target composition ratio are substantially the same,
wherein, in setting the target composition ratio after reduction, the target composition ratio is set to about 39.5 to 40.5 wt % of calcium oxide (CaO), about 39.5 to 40.5 wt % of silicon dioxide (SiO 2 ) and about 19.5 to 20.5 wt % of aluminum oxide (Al 2 O 3 ), when the total amount of calcium oxide (CaO), silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) in the slag is set to 100 wt %,
wherein, in the determining of the complex reducing agent, the complex reducing agent includes aluminum (Al), calcium (Ca), silicon (Si), carbon (C), and iron (Fe).

2. The method of claim 1 , wherein, in the setting of the target composition ratio, the slag having the target composition ratio includes calcium oxide (CaO), silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) as components.

3. The method of claim 1 , wherein, in the calculating of the reaction product, the weights (g) of calcium oxide (CaO), silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) in the slag are calculated, and in the calculating the of composition of the slag, the contents (wt %) of calcium oxide (CaO), silicon dioxide (SiO 2 ) and aluminum oxide (Al 2 O 3 ) in the reduced slag are calculated.

4. The method of claim 1 , wherein, in the determining of the particular complex reducing agent, in the component ratio of the complex reducing agent, the content ratio of magnesium oxide (MgO) in the reacted slag after the supply of the particular complex reducing agent is set to a predetermined value.

5. The method of claim 4 , wherein the complex reducing agent is determined to have a composition ratio of about 7.5 to 37 wt % of aluminum (Al), about 19.5 to 28.5 wt % of calcium (Ca), about 37 to 55.5 wt % of silicon (Si), about 0.2 to 0.4 wt % of carbon (C) and about 6.3 to 9.8 wt % of iron (Fe), when the total amount of aluminum (Al), calcium (Ca), silicon (Si), carbon (C), and iron (Fe) in the complex reducing agent is set to 100 wt %.

6. The method of claim 5 , wherein, in the determining of the particular complex reducing agent, the input of an slag forming agent based on the total weight of the complex reducing agent is determined, lime (calcium oxide) is used as the slag forming agent, and the lime is supplied in an amount of about 20 ˜ 64 wt % based on the total weight (100 wt %) of the particular complex reducing agent.

Assignees

• Hyundai Steel Co
• Inha-Industry Partnership Inst

Inventors

• Ki Joon-Seong
• Shin Dong-Kyung
• You Byung-Don
• Joo Seong-Woong
• Hong Seong-Hun
• Hwang Jin-Ill

Classifications

• C21B15/00 Primary

  Other processes for the manufacture of iron from iron compounds (by electrolysis C25C1/06) · CPC title

• C21C7/0087 Primary

  Treatment of slags covering the steel bath, e.g. for separating slag from the molten metal · CPC title

• C21C5/54

  Processes yielding slags of special composition · CPC title

• C04B5/06

  Ingredients, other than water, added to the molten slag {or to the granulating medium or before remelting}; Treatment with gases or gas generating compounds, e.g. to obtain porous slag · CPC title

• C21C5/36

  Processes yielding slags of special composition · CPC title