Method for concentrating aqueous lye and apparatus suitable therefor
US-9849400-B2 · Dec 26, 2017 · US
US9512057B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9512057-B2 |
| Application number | US-201414213616-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 14, 2014 |
| Priority date | Mar 15, 2013 |
| Publication date | Dec 6, 2016 |
| Grant date | Dec 6, 2016 |
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Methods and systems for producing high purity 3-hydroxypropionic acid (3-HP) from an aqueous medium, such as a fermentation broth, are described. Aqueous 3-HP solution can be purified by flash evaporation wherein the 3-HP is vaporized at an elevated temperature without conversion to acrylic acid. This process can be integrated with downstream processes for producing other chemical and consumer products.
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What is claimed is: 1. A composition comprising nonaqueous components that are at least about 90% by weight of a biologically produced 3-HP, wherein said 3-HP has a 14 C concentration of at least 1 part per trillion carbon and wherein said composition consists essentially of about 1 to about 60% water by weight and about 40% to about 99% nonaqueous components. 2. The composition of claim 1 , wherein said 3-HP has a 14 C concentration of about 1.2 parts per trillion carbon. 3. The composition of claim 1 , wherein said nonaqueous components comprise at least about 95% by weight of said biologically produced 3-HP. 4. The composition of claim 1 , wherein said nonaqueous components comprise at least about 98% by weight of said biologically produced 3-HP. 5. The composition of claim 1 , wherein said composition comprises less than about 30% water by weight. 6. The composition of claim 1 , wherein said composition comprises less than about 10% by weight of acrylic acid. 7. The composition of claim 1 , wherein said composition comprises less than about 5% by weight of acrylic acid. 8. The composition of claim 1 , wherein said composition comprises less than about 1% by weight of acrylic acid. 9. A downstream chemical product produced from the composition of claim 1 , wherein said downstream chemical product is selected from the group consisting of acrylic acid (AA), 1,3-propanediol, methyl acrylate, acrylamide, propiolactone, ethyl-3-3-HP, malonic acid, acrylonitrile, butyl acrylate, 3-HP amide, and ethyl acrylate. 10. A consumer product produced using the downstream chemical product of claim 9 . 11. The consumer product of claim 10 , wherein said consumer product comprises a downstream chemical product with a 14 C concentration of at least 1 part per trillion carbon.
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