Collector compositions and methods for making and using same

Patent metadata

Field	Value
Publication number	US-9511378-B2
Application number	US-201414509086-A
Country	US
Kind code	B2
Filing date	Oct 8, 2014
Priority date	Oct 9, 2013
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

Collector compositions and methods for making and using same to purify one or more crude materials are provided. The collector composition can include one or more amidoamines having the chemical Formula I and one or more amines having the chemical Formula IV, where a weight ratio of the amidoamine to the amine can be about 99:1 to about 1:99.

First claim

What is claimed is:

1. A collector composition, comprising an amidoamine and an amine, wherein:
a weight ratio of the amidoamine to the amine is about 99:1 to about 1:99,
the amidoamine is produced by reacting tall oil fatty acids and a polyamine comprising 1,3-diaminopentane, and
the amine has a formula:
R 6 —NH 2 ,

wherein R 6 is a (C 1 -C 24 )alkyl, a phenyl, a benzyl, a (C 1 -C 24 )alkenyl, a heterocyclyl, an unsubstituted aryl, or an aryl substituted by one or more (C 1 -C 8 )alkyl substituents.

2. The composition of claim 1 , wherein the weight ratio of the amidoamine to the amine is about 1:3 to about 3:1.

3. The composition of claim 1 , wherein the polyamine further comprises diethylenetriamine; N-(hydroxyethyl)ethylenediamine; 3-(dimethylamino)-1-propylamine; aminoguanidine bicarbonate; 1,5-diamino-2-methylpentane; 1,2-diaminopropane; 2,4-diaminotoluene; 2,4-diaminobenzene sulfonic acid; N,N-dimethylaminopropyl-N-proplyenediamine; 3-(N,N-diethylamino)propylamine, 2-amino-4-methylpyridine; 2-(N,N-diethylamino)ethylamine; 2-amino-6-methylpyridine; 2-aminothiazole; aminoguanidine carbonate; aminoethylpiperazine; 1-methylpiperazine; 2-aminopyrimidine; aminoethylaminopropyltrimethoxysilane; 2-aminopyridine; 5-aminotetrazole; 2-amino-3-methylpyridine; 2-aminobenzothiazole; 3-aminomethylpyridine; 3-picolylamine; 3-morpholinopropylamine; 1-ethylpiperazine; N-methylpropylenediamine, histidine; aminoethylaminoethylaminopropyltrimethoxysilane; 3-aminopyridine; N-ethylethylenediamine; aminopropylimidazole; 2-methylpiperazine; 2-amino-5-diethylaminopentane; 3-amino-1,2,4-triazole; 2-(N,N-dimethylamino)ethylamine; L-ornithine-monohydrochloride; N-(aminoethyl)morpholine; 6-aminopurine; histamine; 1-[2-[[2-[(2-aminoethyl)amino]ethyl]amino]ethyl]-piperazine); N-[(2-aminoethyl)2-aminoethyl]piperazine)]; 5,6-diamino-2-thiouracil; adenosine; adenosine 3′,5′-cyclic monophosphate; S-adenosylmethionine, S-adenosyl homocysteine; 5-hydroxylysine; carnosine; serotonin; 5-hydroxytryptophan; N-methyltryptamine; norbaeocystin; 5, 6-dibromotryptamine; 6-bromotryptamine; anserine; beta-methylamino-L-alanine, diphthamide; ibotenic acid; saccharopine; 4-aminopiperidine; 3-aminopiperidine; 2,4-diaminobenzoic acid; 1,2-diaminoanthraquinone; 2,3-diaminophenol; 2,4-diaminophenol; 2,3-diaminopropionic acid; 1-amino-4-methylpiperidine; 4-(aminomethyl)piperidine; 4-amino-2,2,6,6-tetramethylpiperidine; 3-aminopyrrolidine; 4-aminobenzylamine; 2-aminobenzylamine; or any mixture thereof.

4. The composition of claim 1 , wherein the polyamine further comprises diethylenetriamine.

5. The composition of claim 1 , wherein the collector composition further comprises:
one or more etheramines having a formula:
R 7 —O—R 8 —NH 2 ,

wherein:
R 7 is hydrogen, a (C 1 -C 18 )alkyl, a halogen-(C 1 -C 18 )alkyl, a phenyl, a (C 1 -C 6 )alkenyl, a heterocyclyl, an unsubstituted aryl, or an aryl substituted by one or more substituents selected from a halogen, a (C 1 -C 18 )alkyl, and a halogen-(C 1 -C 18 )alkyl; and
R 8 is selected from a (C 1 -C 6 )alkylene, a halogen-(C 1 -C 6 )alkylene, a phenylene, a (C 1 -C 6 )alkenylene, a heterocyclylene, an unsubstituted arylene, or an arylene substituted by one or more substituents selected from a halogen, a (C 1 -C 6 )alkyl, and a halogen-(C 1 -C 6 )alkyl;

wherein the weight ratio of the amidoamine to the amine is about 98:1 to about 1:98; and
wherein a weight ratio of the amidoamine to the etheramine is about 98:1 to about 1:98.

6. The composition of claim 1 , wherein the collector composition further comprises:
one or more ether diamines having a formula:
R 9 —O—R 10 —NH—R 11 —NH 2 ,

wherein:
R 9 is hydrogen, a (C 1 -C 18 )alkyl, a halogen-(C 1 -C 18 )alkyl, a phenyl, a (C 1 -C 18 )alkenyl, a heterocyclyl, an unsubstituted aryl, or an aryl substituted by one or more substituents selected from a halogen, a (C 1 -C 18 )alkyl, and a halogen-(C 1 -C 18 )alkyls; and
R 10 and R 11 are independently selected from a (C 1 -C 6 )alkylene, a halogen-(C 1 -C 6 )alkylene, a phenylene, a (C 1 -C 6 )alkenylene, a heterocyclylene, an unsubstituted arylene, or an arylene substituted by one or more substituents selected from a halogen, a (C 1 -C 6 )alkyl, and a halogen-(C 1 -C 6 )alkyl;

wherein a weight ratio of the amidoamine to the amine is about 98:1 to about 1:98; and
wherein a weight ratio of the amidoamine to the etheramine is about 98:1 to about 1:98.

7. A collector composition, comprising an amidoamine and an amine, wherein:
a weight ratio of the amidoamine to the amine is about 99:1 to about 1:99,
the amidoamine is produced by reacting coconut oil and a polyamine comprising 1,3-diaminopentane, and
the amine has a formula:
R 6 —NH 2 ,

wherein R 6 is a (C 1 -C 24 )alkyl, a phenyl, a benzyl, a (C 1 -C 24 )alkenyl, a heterocyclyl, an unsubstituted aryl, or an aryl substituted by one or more (C 1 -C 8 )alkyl substituents.

8. The composition of claim 7 , wherein the polyamine further comprises diethylenetriamine; N-(hydroxyethyl)ethylenediamine; 3-(dimethylamino)-1-propylamine; aminoguanidine bicarbonate; 1,5-diamino-2-methylpentane; 1,2-diaminopropane; 2,4-diaminotoluene; 2,4-diaminobenzene sulfonic acid; N,N-dimethylaminopropyl-N-proplyenediamine; 3-(N,N-diethylamino)propylamine, 2-amino-4-methylpyridine; 2-(N,N-diethylamino)ethylamine; 2-amino-6-methylpyridine; 2-aminothiazole; aminoguanidine carbonate; aminoethylpiperazine; 1-methylpiperazine; 2-aminopyrimidine; aminoethylaminopropyltrimethoxysilane; 2-aminopyridine; 5-aminotetrazole; 2-amino-3-methylpyridine; 2-aminobenzothiazole; 3-aminomethylpyridine; 3-picolylamine; 3-morpholinopropylamine; 1-ethylpiperazine; N-methylpropylenediamine, histidine; aminoethylaminoethylaminopropyltrimethoxysilane; 3-aminopyridine; N-ethylethylenediamine; aminopropylimidazole; 2-methylpiperazine; 2-amino-5-diethylaminopentane; 3-amino-1,2,4-triazole; 2-(N,N-dimethylamino)ethylamine; L-ornithine-monohydrochloride; N-(aminoethyl)morpholine; 6-aminopurine; histamine; 1-[2-[[2-[(2-aminoethyl)amino]ethyl]amino]ethyl]-piperazine); N-[(2-aminoethyl)2-aminoethyl]piperazine)]; 5,6-diamino-2-thiouracil; adenosine; adenosine 3′,5′-cyclic monophosphate; S-adenosylmethionine, S-adenosyl homocysteine; 5-hydroxylysine; carnosine; serotonin; 5-hydroxytryptophan; N-methyltryptamine; norbaeocystin; 5, 6-dibromotryptamine; 6-bromotryptamine; anserine; beta-methylamino-L-alanine, diphthamide; ibotenic acid; saccharopine; 4-aminopiperidine; 3-aminopiperidine; 2,4-diaminobenzoic acid; 1,2-diaminoanthraquinone; 2,3-diaminophenol; 2,4-diaminophenol; 2,3-diaminopropionic acid; 1-amino-4-methylpiperidine; 4-(aminomethyl)piperidine; 4-amino-2,2,6,6-tetramethylpiperidine; 3-aminopyrrolidine; 4-aminobenzylamine; 2-aminobenzylamine; or any mixture thereof.

9. The composition of claim 7 , wherein the polyamine further comprises diethylenetriamine.

10. The composition of claim 7 , wherein the collector composition further comprises:
one or more etheramines having a formula:
R 7 —O—R 8 —NH 2 ,

wherein:
R 7 is hydrogen, a (C 1 -C 18 )alkyl, a halogen-(C 1 -C 18 )alkyl, a phenyl, a (C 1 -C 6 )alkenyl, a heterocyclyl, an unsubstituted aryl, or an aryl substituted by one or more substituents selected from a halogen, a (C 1 -C 18 )alkyl, and a halogen-(C 1 -C 18 )alkyl; and
R 8 is selected from a (C 1 -C 6 )alkylene, a halogen-(C 1 -C 6 )alkylene, a phenylene, a (C 1 -C 6 )alkenylene, a heterocyclylene, an unsubstituted arylene, or an arylene substituted by one or more substituents selected from a halogen, a (C 1 -C 6 )alkyl, and a halogen-(C 1 -C 6 )alkyl;

wherein the weight ratio of the amidoamine to the amine is about 98:1 to about 1:98; and
wherein a weight ratio of the amido

Assignees

• Georgia Pacific Chemicals Llc

Inventors

• Hines John B
• Swift Brian L

Classifications

• B03D2203/02

  Ores · CPC title

• B03D2203/006

  Oil well fluids, oil sands, bitumen · CPC title

• B03D1/021

  for treatment of phosphate ores · CPC title

• B03D2201/04

  Frothers · CPC title

• B03D1/01 Primary

  containing nitrogen · CPC title