Mixed collector compositions

Patent metadata

Field	Value
Publication number	US-9457357-B2
Application number	US-201314088585-A
Country	US
Kind code	B2
Filing date	Nov 25, 2013
Priority date	Nov 28, 2012
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

Collector compositions and methods for making and using same are provided. The collector can include one or more etheramines and one or more amidoamines. A liquid suspension or slurry comprising one or more particulates can be contacted with the collector to produce a treated mixture. A product can be recovered from the treated mixture that includes a purified liquid having a reduced concentration of the particulates relative to the treated mixture, a purified particulate product having a reduced concentration of liquid relative to the treated mixture, or both.

First claim

What is claimed is:

1. A process for beneficiation of an iron-containing ore, comprising:
contacting an aqueous suspension or slurry comprising an ore with a collector to produce a treated mixture, wherein:
the ore comprises iron and silica,
the collector comprises a mixture of an amidoamine and an etheramine,
the amidoamine comprises a reaction product of a tall oil fatty acid and a polyamine,
the polyamine comprises diethylenetriamine, 1,3-diaminopentane, or a mixture thereof, and
the mixture of the amidoamine and the etheramine has a weight ratio of the amidoamine to the etheramine of about 35:65 to about 65:35; and

recovering a purified iron product from the treated mixture, wherein the purified iron product has a reduced concentration of the silica relative to the treated mixture.

2. The process of claim 1 , wherein the iron comprises iron oxide.

3. The process of claim 1 , wherein the treated mixture has a pH of about 8 to about 11.

4. The process of claim 1 , wherein the weight ratio of the amidoamine to the etheramine is about 35:65.

5. The process of claim 1 , wherein the polyamine comprises diethylenetriamine.

6. The process of claim 1 , wherein the polyamine comprises 1,3-diaminopentane.

7. The process of claim 1 , the treated mixture comprises about 1 gram of the collector per tonne of ore to about 120 grams of the collector per tonne of ore.

8. The process of claim 1 , the treated mixture comprises about 1 gram of the collector per tonne of ore to about 100 grams of the collector per tonne of ore, and wherein the purified iron product comprises less than 2 wt % of the silica, based on a solids weight of the purified iron product.

9. The process of claim 1 , further comprising passing air through the treated mixture.

10. The process of claim 1 , further comprising contacting the aqueous suspension or slurry with a depressant to produce the treated mixture, wherein the depressant comprises a modified starch, carboxymethyl cellulose, gum arabic, or any mixture thereof.

11. The process of claim 1 , further comprising contacting the aqueous suspension or slurry with a frothing agent to produce the treated mixture, wherein the frothing agent comprises methyl isobutyl carbinol, a polypropylene glycol alkyl ether, a polypropylene glycol phenyl ether, or any mixture thereof.

12. A process for beneficiation of an iron-containing ore, comprising:
adding a collector to an aqueous suspension or slurry comprising an ore to produce a treated mixture, wherein:
the ore comprises iron and silica,
the collector comprises about 60 wt % to about 70 wt % of an etheramine and about 30 wt % to about 40 wt % of an amidoamine, based on a combined weight of the etheramine and the amidoamine,
the amidoamine comprises a reaction product of a tall oil fatty acid and a polyamine,
the polyamine comprises diethylenetriamine, 1,3-diaminopentane, or a mixture thereof,
the treated mixture has a pH of about 8 to about 11, and
the treated mixture comprises about 30 grams of the collector per tonne of ore to about 120 grams of the collector per tonne of ore;

subjecting the treated mixture to froth flotation; and
recovering a purified iron product from the treated mixture, wherein the purified iron product has a reduced concentration of the silica relative to the treated mixture.

13. The process of claim 12 , wherein the polyamine comprises diethylenetriamine.

14. The process of claim 12 , wherein the polyamine comprises 1,3-diaminopentane.

15. The process of claim 12 , wherein the iron comprises iron oxide.

16. The process of claim 12 , wherein the purified iron product comprises less than 2 wt % of the silica, based on a solids weight of the purified iron product.

17. The process of claim 12 , the treated mixture comprises about 50 grams of the collector per tonne of ore to about 90 grams of the collector per tonne of ore.

18. The process of claim 12 , further comprising adding a depressant to the aqueous suspension or slurry to produce the treated mixture, wherein the depressant comprises a modified starch, carboxymethyl cellulose, gum arabic, or any mixture thereof.

19. The process of claim 12 , further comprising adding a frothing agent to the aqueous suspension or slurry to produce the treated mixture, wherein the frothing agent comprises methyl isobutyl carbinol, a polypropylene glycol alkyl ether, a polypropylene glycol phenyl ether, or any mixture thereof.

20. A process for beneficiation of an iron-containing ore, comprising:
adding a collector and at least one of a depressant and a frothing agent to an aqueous suspension or slurry comprising an ore to produce a treated mixture, wherein:
the ore comprises iron and silica,
the collector comprises about 60 wt % to about 70 wt % of an etheramine and about 30 wt % to about 40 wt % of an amidoamine, based on a combined weight of the etheramine and the amidoamine,
the amidoamine comprises a reaction product of a tall oil fatty acid and a polyamine,
the polyamine comprises diethylenetriamine, 1,3-diaminopentane, or a mixture thereof,
the depressant comprises a modified starch, carboxymethyl cellulose, gum arabic, or any mixture thereof,
the frothing agent comprises methyl isobutyl carbinol, a polypropylene glycol alkyl ether, a polypropylene glycol phenyl ether, or any mixture thereof,
the treated mixture has a pH of about 8 to about 11, and
the treated mixture comprises about 60 grams of the collector per tonne of ore to about 90 grams of the collector per tonne of ore;

subjecting the treated mixture to froth flotation; and
recovering a purified iron product from the treated mixture, wherein the purified iron product has a reduced concentration of the silica relative to the treated mixture, and wherein the purified iron product comprises less than 2 wt % of the silica, based on a solids weight of the purified iron product.

Assignees

• Georgia Pacific Chemicals Llc

Inventors

• Martins Luiz Henrique

Classifications

• B03D2203/02

  Ores · CPC title

• B03D1/01 Primary

  containing nitrogen · CPC title

• B03D2201/02

  Collectors · CPC title

• B03D1/02

  Froth-flotation processes · CPC title