Ternary compositions for low-capacity refrigeration

Patent metadata

Field	Value
Publication number	US-9505968-B2
Application number	US-201514873891-A
Country	US
Kind code	B2
Filing date	Oct 2, 2015
Priority date	Sep 11, 2009
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

Compositions containing 2,3,3,3-tetrafluoropropene and to the uses thereof as heat transfer fluid, expansion agents, solvents and aerosol. Compositions essentially containing between 10 and 90 wt. % of 2,3,3,3-tetrafluoropropene, between 5 and 80 wt. % of HFC-134a and between 5 and 10 wt. % of HFC-32. Compositions essentially containing from 10 to 45% by weight of 2,3,3,3-tetrafluoropropene, from 50 to 80% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

First claim

The invention claimed is:

1. A method of heat transfer comprising operating a compression refrigeration system to transfer heat, wherein the compression refrigeration system includes exchangers operating in countercurrent mode or in crossed-current mode with countercurrent tendency, and wherein the compression refrigeration system includes a heat-transfer fluid comprising a refrigerant consisting essentially of from 50 to 90% by weight of 2,3,3,3-tetrafluoropropene, from 5 to 40% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

2. The method as claimed in claim 1 , wherein the heat-transfer fluid further comprises a stabilizer.

3. The method as claimed in claim 2 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

4. The method as claimed in claim 2 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

5. The method as claimed in claim 1 , wherein the heat-transfer fluid further comprises a lubricant.

6. The method as claimed in claim 5 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

7. The method as claimed in claim 1 , wherein the refrigerant consists of from 50 to 90% by weight of 2,3,3,3-tetrafluoropropene, from 5 to 40% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

8. A method of heat transfer comprising operating a heat transfer system, wherein the heat transfer system comprises a heat-transfer fluid including a refrigerant consisting essentially of from 50 to 90% by weight of 2,3,3,3-tetrafluoropropene, from 5 to 40% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

9. The method as claimed in claim 8 , wherein the heat-transfer fluid further comprises a stabilizer.

10. The method as claimed in claim 9 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

11. The method as claimed in claim 9 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

12. The method as claimed in claim 8 , wherein the heat-transfer fluid further comprises a lubricant.

13. The method as claimed in claim 12 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

14. The method as claimed in claim 8 , wherein the refrigerant consists of from 50 to 90% by weight of 2,3,3,3-tetrafluoropropene, from 5 to 40% by weight of HFC-134a and from 5 to 10% by weight of HFC-32.

Assignees

• Arkema France

Inventors

• Rached Wissam

Classifications

• C09K2205/40

  Replacement mixtures · CPC title

• C09K3/00

  Materials not provided for elsewhere · CPC title

• C09K5/045 Primary

  containing only fluorine as halogen · CPC title

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• C09K2205/22

  All components of a mixture being fluoro compounds · CPC title