Use of ternary compositions

Patent metadata

Field	Value
Publication number	US-9127191-B2
Application number	US-201414329556-A
Country	US
Kind code	B2
Filing date	Jul 11, 2014
Priority date	Sep 11, 2009
Publication date	Sep 8, 2015
Grant date	Sep 8, 2015

Abstract

The use of a ternary composition of 2,3,3,3-tetrafluoropropene, 1,1,1,2-tetrafluoroethane and difluoromethane, as a heat-transfer fluid, in compression refrigeration systems with exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency. A heat-transfer process in which a ternary composition of 2,3,3,3-tetrafluoropropene, 1,1,1,2-tetrafluoroethane and difluoromethane is used as a refrigerant in compression systems with exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency.

First claim

The invention claimed is:

1. A heat-transfer fluid consisting essentially of from 5 to 25% by weight of 2,3,3,3-tetrafluoropropene, from 60 to 80% by weight of 1,1,1,2-tetrafluoroethane, and from 15 to 25% by weight of difluoromethane, the heat-transfer fluid configured for use as a heat-transfer fluid in compression refrigeration systems with exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency.

2. A heat-transfer fluid consisting essentially of:
from 45 to 80% by weight of 2,3,3,3-tetrafluoropropene;
from 5 to 25% by weight of 1,1,1,2-tetrafluoroethane; and
from 15 to 30% by weight of difluoromethane;
wherein the heat-transfer fluid is configured for use as a heat-transfer fluid in compression refrigeration systems with exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency.

3. A heat-transfer fluid consisting essentially of:
from 65 to 80% by weight of 2,3,3,3-tetrafluoropropene;
from 5 to 10% by weight of 1,1,1,2-tetrafluoroethane; and
from 15 to 30% by weight of difluoromethane;
wherein the heat-transfer fluid is configured for use as a heat-transfer fluid in compression refrigeration systems with exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency.

4. A refrigerant comprising the heat-transfer fluid as claimed in claim 1 , the refrigerant further comprising a stabilizer.

5. The refrigerant as claimed in claim 4 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

6. The refrigerant as claimed in claim 4 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

7. A method comprising:
transferring heat, in a compression system with heat exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency, with a refrigerant comprising the heat transfer fluid according to claim 1 .

8. The method of claim 7 , wherein the transferring is carried out in the presence of lubricant.

9. The method as claimed in claim 8 , wherein the lubricant is selected from the group consisting of mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.

10. The method as claimed in claim 7 , wherein the refrigerant further comprises a stabilizer.

11. The method as claimed in claim 10 , wherein the stabilizer is selected from the group consisting of nitromethane, ascorbic acid, terephthalic acid, azoles, phenolic compounds, epoxides, phosphites, phosphates, phosphonates, thiols and lactones.

12. The method as claimed in claim 10 , wherein stabilizer represents at most 5% by weight relative to the refrigerant.

13. A method comprising:
transferring heat, in a compression system with heat exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency, with a refrigerant comprising the heat transfer fluid according to claim 2 .

14. A method comprising:
transferring heat, in a compression system with heat exchangers operating in counterflow mode or in cross-flow mode with counterflow tendency, with a refrigerant comprising the heat transfer fluid according to claim 3 .

15. The heat-transfer fluid according to claim 1 , wherein the heat-transfer fluid consists of from 5 to 25% by weight of 2,3,3,3-tetrafluoropropene, from 60 to 80% by weight of 1,1,1,2-tetrafluoroethane, and from 15 to 25% by weight of difluoromethane.

16. The heat-transfer fluid according to claim 2 , wherein the heat transfer fluid consists of from 45 to 80% by weight of 2,3,3,3-tetrafluoropropene; from 5 to 25% by weight of 1,1,1,2-tetrafluoroethane; and from 15 to 30% by weight of difluoromethane.

17. The heat-transfer fluid according to claim 3 , wherein the heat-transfer fluid consists of from 65 to 80% by weight of 2,3,3,3-tetrafluoropropene; from 5 to 10% by weight of 1,1,1,2-tetrafluoroethane; and from 15 to 30% by weight of difluoromethane.

Assignees

• Arkema France

Inventors

• Rached Wissam

Classifications

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title

• F25B9/006

  the refrigerant containing more than one component (F25B9/004 takes precedence) · CPC title

• C09K5/045 Primary

  containing only fluorine as halogen · CPC title

• C09K2205/22

  All components of a mixture being fluoro compounds · CPC title

• C09K2205/122

  Halogenated hydrocarbons · CPC title