Fiber-reinforced thermoplactic-resin molded article, fiber-reinforced thermoplastic-resin molding material, and method of manufacturing fiber-reinforced thermoplastic-resin molding material

Patent metadata

Field	Value
Publication number	US-9505928-B2
Application number	US-201314646116-A
Country	US
Kind code	B2
Filing date	Dec 18, 2013
Priority date	Dec 21, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A fiber reinforced thermoplastic resin molded article includes 5 to 40 parts by weight of carbon fibers (A), 1 to 40 parts by weight of organic fibers (B), and 20 to 94 parts by weight of a thermoplastic resin (C) based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C), wherein the carbon fibers (A) have an average fiber length (L A ) of 0.3 to 1.5 mm, and an average straight-line distance between two edges of a single fiber (D A ), and the organic fibers (B) have an average fiber length (L B ) of 1.5 to 4 mm.

First claim

The invention claimed is:

1. A fiber reinforced thermoplastic resin molded article, comprising:
5 to 45 parts by weight of carbon fibers (A);
1 to 45 parts by weight of organic fibers (B); and
20 to 94 parts by weight of a thermoplastic resin (C) based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C),
wherein the carbon fibers (A) in the fiber reinforced thermoplastic resin molded article have an average fiber length (L A ) of 0.3 to 1.5 mm, and an average straight-line distance between two edges of a single fiber (D A ), which is a distance from a starting point to an end point of the carbon fibers (A), and the average fiber length (L A ) satisfy relationship [1], and
the organic fibers (B) in the fiber reinforced thermoplastic resin molded article have an average fiber length (L B ) of 1.5 to 4 mm, and an average straight-line distance between two edges of a single fiber (D B ), which is a distance from a starting point to an end point of the organic fibers (B), and the average fiber length (L B ) satisfy relationship [2]:
0.9× L A ≦D A ≦L A   [1]

0.1× L B ≦D B ≦0.9× L B   [2].

2. The fiber reinforced thermoplastic resin molded article according to claim 1 , wherein a falling weight impact strength at 23° C. (I 23° C. ) and a falling weight impact strength at −20° C. (L −20° C. ) satisfy relationship [3]:
I 23° C. ×0.8≦ I −20° C.   [3].

3. The fiber reinforced thermoplastic resin molded article according to claim 1 , wherein an end face of the organic fibers (B) at break has an inclination with respect to a perpendicular plane to the fiber axis.

4. The fiber reinforced thermoplastic resin molded article according to claim 1 , wherein the organic fibers (B) have a tensile break elongation of 10 to 50%.

5. The fiber reinforced thermoplastic resin molded article according to claim 1 , wherein the organic fibers (B) are at least one selected from the group consisting of polyamide fibers, polyester fibers, polyarylene sulfide fibers, and fluororesin fibers.

6. The fiber reinforced thermoplastic resin molded article according to claim 1 , wherein the carbon fibers (A) have a surface oxygen concentration ratio [O/C] of 0.05 to 0.5, and the carbon fibers (A) have an epoxy resin on their surfaces.

Assignees

• Toray Industries

Inventors

• Hirata Shin
• Mitsutsuji Yuki
• Nishimura Toru

Classifications

• C08J5/047 Primary

  with mixed fibrous material · CPC title

• C08L23/12

  Polypropene · CPC title

• C08J2423/26

  modified by chemical after-treatment · CPC title

• C08J2323/12

  Polypropene · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title