System for dense loading of catalyst into bayonet tubes for a steam reforming exchanger-reactor using flexible and removable slowing elements

Patent metadata

Field	Value
Publication number	US-9492802-B2
Application number	US-201314436153-A
Country	US
Kind code	B2
Filing date	Sep 24, 2013
Priority date	Oct 17, 2012
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

The present invention describes a device and a method for dense and homogeneous loading of catalyst into the annular space of bayonet tubes employed in a steam reforming reactor, said device employing removable slowing elements.

First claim

The invention claimed is:

1. A device for densely filling catalyst specially adapted to a steam reforming exchanger-reactor comprising a plurality of bayonet tubes enclosed in a shell, the catalyst being constituted by solid particles occupying at least part of an annular space ( 4 ) included between an internal tube ( 5 ) and an external tube ( 6 ), the assembly of these two tubes constituting a bayonet tube, the width of said annular space being in the range 30 mm to 80 mm, and its height being in the range 10 to 20 meters, the catalyst particles being in the form of cylinders with an approximate height of 10 mm to 20 mm and an approximate diameter of 10 mm to 20 mm, the device comprising:
a series of slowing elements ( 7 ) which are annular in shape, the internal diameter of the slowing elements being substantially equal to that of the internal tube ( 5 ) and the external diameter of the slowing elements being substantially equal to that of the internal diameter of the external tube ( 6 ), said series of slowing elements ( 7 ), when deployed, being distributed vertically in a regular manner along the annular space ( 4 ) and each occupying the whole section of the annular zone ( 4 ), connected together via vertical flexible connections and separated by a vertical distance in the range of 50 cm to 150 cm, each slowing element being constituted by a rigid annular structure onto which a plurality of substantially radial flexible rods are attached and occupying the whole section of the annular space ( 4 ),
said slowing elements ( 7 ) being connected together via one or more vertical flexible connections ( 8 ) which are capable of being wound around a spooler ( 10 ) located outside the annular space ( 4 ) to be filled so that the slowing elements can be deployed in and removed from the annular space ( 4 ), and

the particles of catalyst being contained in:
a central feed hopper ( 1 ) which is capable of delivering the particles onto a conveyor belt or shaker conveyor ( 2 ) supplying the annular space ( 4 ) via:
a funnel ( 3 ) via which the particles flow into the interior of the annular space ( 4 ).

2. The filling device according to claim 1 , in which each slowing element ( 7 ) is additionally provided with rigid fins ( 9 ) disposed in a radial manner and extending over the whole width of the annular space ( 4 ).

3. The filling device according to claim 1 , in which each slowing element ( 7 ) has a rigid structure with a helical shape around the internal tube ( 5 ) to which the plurality of substantially radial flexible rods occupying the whole section of the annular space ( 4 ) are attached.

4. The filling device according to claim 1 , wherein the radial dimension of the annular space ( 4 ) varies because portions of the external tube ( 6 ) have an increasing internal diameter from bottom to top, and the slowing elements ( 7 ) have a rigid peripheral structure and have increasing diameters from bottom to top so as to occupy the whole horizontal section of the portion of the annular space ( 4 ) in which they are located when deployed in the annular space ( 4 ).

5. The filling device according to claim 1 which, in order to facilitate the descent of the device into the annular space ( 4 ) when being deployed, has a first slowing element ( 7 ), which first enters the annular space when being deployed, equipped with a weight which can overcome the friction of the flexible rods on the wall of the external tube ( 6 ) in the case of a rigid central structure, or on the wall of the internal tube ( 5 ) in the case of a rigid peripheral structure.

6. A method for loading solid particles of catalyst using the device according to claim 1 , comprising:
initially, having the loading system being wound onto the spooler ( 10 ), and the feed hopper ( 1 ) being filled with the solid particles;
next, introducing the device into the annular space ( 4 ) via its upper portion until the first slowing element ( 7 ) reaches a distance with respect to the bottom of the annular space ( 4 ) in the range 50 cm to 100 cm;
starting the conveyor belt or the shaker conveyor ( 2 ) so as to provide a flow rate of solid particles in the range 250 kg/h to 500 kg/h, the solid particles being introduced into the annular space ( 4 ) via the funnel ( 3 );
when the annular space ( 4 ) is filled, raising the device from the annular space ( 4 ) with the aid of the spooler ( 10 ) so as to keep a constant distance between the first slowing element and the surface of the bed of solid particles which is gradually being constituted, said distance being in the range of 50 cm to 100 cm;
the device being raised up and wound onto the spooler at a speed equivalent to the speed of loading of the annular space ( 4 ), in the range 0.2 meter/min to 0.4 meter/min; and
once the annular space ( 4 ) has been loaded and the device has been wound up on the spooler, the device is displaced in order to load another annular space.

7. The filling device according to claim 1 , wherein the rigid annular structure is a central structure having a diameter substantially equal to that of the internal tube ( 5 ) onto which a plurality of substantially radially outward flexible rods are attached.

8. The filling device according to claim 1 , wherein the rigid annular structure is a peripheral structure having a diameter substantially equal to that of the internal diameter of the external tube ( 6 ) onto which a plurality of substantially radially inward flexible rods are attached.

9. The filling device according to claim 1 , wherein the vertical flexible connections ( 8 ) are chains.

Assignees

• Ifp Energies Now

Inventors

• Sanz Elena
• Beaumont Robert
• Svezia Daniel
• Boyer Christophe

Classifications

• B01J2208/00778

  Kinetic energy reducing devices in the flow channel · CPC title

• B01J8/06

  in tube reactors; the solid particles being arranged in tubes · CPC title

• B01J2208/00752

  Feeding · CPC title

• B01J8/002 Primary

  with a moving instrument · CPC title

• B01J8/003 Primary

  in a downward flow · CPC title