Glass article provided with photocatalyst film

Patent metadata

Field	Value
Publication number	US-9486779-B2
Application number	US-201314375638-A
Country	US
Kind code	B2
Filing date	Feb 1, 2013
Priority date	Feb 3, 2012
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

The present invention provides a glass article including a photocatalyst film 1 containing silicon oxide particles 6 and titanium oxide particles 5 , and a glass sheet 2 . Assuming that the photocatalyst film 1 has a film thickness T, 80% or more of the titanium oxide particles are localized in a region between a surface of the glass sheet 2 and a position spaced from the surface by 0.6 T toward a surface of the photocatalyst film 1 in a thickness direction of the photocatalyst film 1 . The glass article has an increased transmittance provided by enhancing the reflection-reducing function of the photocatalyst film 1 while maintaining the film strength and photocatalytic function of the photocatalyst film 1 .

First claim

The invention claimed is:

1. A glass article comprising a glass sheet and a photocatalyst film formed on a surface of the glass sheet, wherein
the photocatalyst film contains silicon oxide particles, titanium oxide particles, and a binder material whose main component is silicon oxide,
the silicon oxide particles are contained in an amount of 72 to 79 mass %, the titanium oxide particles are contained in an amount of 13 to 18 mass %, and the binder material is contained in an amount of 8 to 12 mass %, with respect to a total amount of the silicon oxide particles, the titanium oxide particles, and the binder material,
the silicon oxide particles have an average particle diameter of 50 nm to 150 nm, the titanium oxide particles have an average particle diameter of 5 nm to 20 nm, and the average particle diameter of the silicon oxide particles is five times or more of the average particle diameter of the titanium oxide particles,
assuming that the photocatalyst film has a film thickness T, 80% or more of the titanium oxide particles are present between the surface of the glass sheet and a position spaced from the surface of the glass sheet by 0.6 T toward a surface of the photocatalyst film in a thickness direction of the photocatalyst film, and
an amount of transmittance increase ΔT is 2.13% to 2.39%, the amount of transmittance increase ΔT being obtained by subtracting an average transmittance in a range of 400 to 1200 nm of the glass sheet having no photocatalyst film formed thereon from an average transmittance in a range of 400 to 1200 nm of the glass article.

2. The glass article according to claim 1 , wherein the silicon oxide particles are contained in an amount of 73 to 78 mass %, the titanium oxide particles are contained in an amount of 14 to 18 mass %, with respect to the total amount of the silicon oxide particles, the titanium oxide particles, and the binder material.

3. The glass article according to claim 1 , wherein the film thickness T of the photocatalyst film is in a range of 70 nm to 280 nm.

4. The glass article according to claim 1 , wherein the photocatalyst film is formed by a method comprising (i) applying a coating liquid to the glass sheet to form a coating film on the glass sheet, (ii) drying the glass sheet to which the coating liquid is applied, and (iii) sintering the coating film,
the coating liquid contains the silicon oxide particles, the titanium oxide particles, and a binder source as a source of the binder material,
the binder source is silicon alkoxide,
the coating liquid includes a high-boiling-point aqueous-organic solvent that is an organic solvent having a boiling point of 190° C. or higher and being miscible with water, and
a concentration of the high-boiling-point aqueous-organic solvent in the coating liquid is 5 to 15% in terms of mass.

5. The glass article according to claim 4 , wherein the coating liquid includes a surfactant.

6. The glass article according to claim 1 , wherein the photocatalyst film has the film thickness T, 95% or more of the titanium oxide particles are present between the surface of the glass sheet and a position spaced from the surface by 0.5 T toward the surface of the photocatalyst film in the thickness direction of the photocatalyst film.

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Yabuta Takeshi
• Kondo Fumiyoshi
• Kawazu Mitsuhiro

Classifications

• C03C17/23 Primary

  Oxides (C03C17/02 takes precedence) · CPC title

• C03C2217/45

  Inorganic continuous phases · CPC title

• G02B27/0006

  with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation (G02B1/18 takes precedence; cleaning in general B08B) · CPC title

• Y10T428/256

  Heavy metal or aluminum or compound thereof · CPC title

• C03C17/007

  containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase · CPC title