Graphene nanoribbons derived from poly(phenylene ethynylene) polymer, methods of making same, and uses thereof
US-9556085-B2 · Jan 31, 2017 · US
US9481618B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9481618-B2 |
| Application number | US-201214003512-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 9, 2012 |
| Priority date | Mar 9, 2011 |
| Publication date | Nov 1, 2016 |
| Grant date | Nov 1, 2016 |
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A cyclopolyarylene compound represented by Formula (1): wherein k is the same or different, and each represents 0, 1 or 2; m is the same or different, and each represents 1, 2 or 3; and n represents 3, 4, 5 or 6.
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The invention claimed is: 1. A cyclopolyarylene compound corresponding to Formula (1): wherein k is the same or different, and each corresponds to 0, 1 or 2; m is the same or different, and each corresponds to 1, 2 or 3; and n is 3, 4, 5 or 6. 2. The cyclopolyarylene compound according to claim 1 , wherein all k are the same; and all m are the same in Formula (1). 3. The cyclopolyarylene compound according to claim 1 , wherein all k are 0 or 1; all m are 1 or 2; and n is 3 or 4 in Formula (1). 4. A method for producing a cyclopolyarylene compound according to claim 1 , the method comprising the step of aromatizing a compound corresponding to Formula (2): wherein R is the same or different, and each corresponds to hydrogen atom, alkyl group or protecting group for hydroxy group; and k, m and n are as defined above. 5. The method according to claim 4 , comprising the step of reacting a compound corresponding to Formula (3): wherein X is the same or different, and each corresponds to halogen atom; and R, k and m are as defined above, in the presence of a transition metal compound, thereby obtaining the compound corresponding to Formula (2).
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