Method for making patterned carbon nanotube array and carbon nanotube device

Patent metadata

Field	Value
Publication number	US-9481125-B2
Application number	US-201414524800-A
Country	US
Kind code	B2
Filing date	Oct 27, 2014
Priority date	Jun 19, 2014
Publication date	Nov 1, 2016
Grant date	Nov 1, 2016

Abstract

A method for patterning a carbon nanotube array is disclosed. A carbon nanotube array is transferred onto a surface of a substitute substrate. The carbon nanotube array has a second surface adjacent to the substitute substrate and a first surface away from the substitute substrate. The carbon nanotube array is laser etched from the first surface to divide the carbon nanotube array into two areas which are a preserving area and a removing area. A carbon nanotube structure is drawn from the removing area.

First claim

What is claimed is:

1. A method for patterning a carbon nanotube array, the method comprising:
providing a carbon nanotube array transferred onto a surface of a substitute substrate, the carbon nanotube array having a second surface adjacent to the substitute substrate and a first surface away from the substitute substrate, the carbon nanotube array having an ability to have a carbon nanotube structure drawn therefrom, and the carbon nanotube structure comprising a plurality of carbon nanotubes joined end to end;
laser etching the first surface of the carbon nanotube array to divide the carbon nanotube array into a preserving area and a removing area; and
drawing the carbon nanotube structure from the removing area and leaving carbon nanotubes in the preserving area.

2. The method of claim 1 , wherein the providing the carbon nanotube array comprising:
providing a growing substrate having the carbon nanotube array grown thereon, the carbon nanotube array having the first surface adjacent to the growing substrate and the second surface away from the growing substrate, and the carbon nanotube array having the ability to have a carbon nanotube structure drawn therefrom;
contacting the surface of the substitute substrate to the second surface of the carbon nanotube array; and
separating the substitute substrate from the growing substrate, thereby separating the first surface of the carbon nanotube array from the growing substrate to transfer the carbon nanotube array from the growing substrate to the substitute substrate, and the carbon nanotube array still having the ability to have a carbon nanotube structure drawn therefrom.

3. The method of claim 2 , wherein the surface of the substitute substrate and the second surface of the carbon nanotube array are combined only by van der Waals attractive forces.

4. The method of claim 2 , wherein the surface of the substitute substrate has a plurality of microstructures located thereon.

5. The method of claim 2 , wherein the substitute substrate is spaced from the growing substrate by a spacing element, and the spacing element has at least a portion located between the substitute substrate and the growing substrate, and the portion of the spacing element has a height less than or equal to the height of the carbon nanotube array.

6. The method of claim 1 , wherein the carbon nanotube array is transferred to the substitute substrate by:
providing a growing substrate having the carbon nanotube array grown thereon, the carbon nanotube array having the first surface adjacent to the growing substrate and the second surface away from the growing substrate, the carbon nanotube array having the ability to have a carbon nanotube structure drawn therefrom;
placing the substitute substrate on the second surface of the carbon nanotube array and sandwiching liquid medium between the substitute substrate and the carbon nanotube array;
solidifying the liquid medium between the substitute substrate and the carbon nanotube array into solid medium;
separating the substitute substrate from the growing substrate, thereby separating the first surface of the carbon nanotube array from the growing substrate; and
removing the solid medium between the substitute substrate and the carbon nanotube array, wherein the carbon nanotube array still having the ability to have a carbon nanotube structure drawn therefrom.

7. The method of claim 6 , wherein the sandwiching the liquid medium between the substitute substrate and the carbon nanotube array comprises:
forming the liquid medium on the second surface of the carbon nanotube array; and
contacting the surface of the substitute substrate and the liquid medium on the second surface with each other.

8. The method of claim 7 , wherein the solidifying the liquid medium between the substitute substrate and the carbon nanotube array comprises contacting the substitute substrate having a temperature below a freezing point with the liquid medium on the second surface of the carbon nanotube array.

9. The method of claim 6 , wherein the sandwiching the liquid medium between the substitute substrate and the carbon nanotube array comprises:
forming the liquid medium on the surface of the substitute substrate; and
contacting the second surface of the carbon nanotube array and the liquid medium on the surface of the substitute substrate with each other.

10. The method of claim 6 , wherein the solidifying the liquid medium between the substitute substrate and the carbon nanotube array comprises placing a lamination of the growing substrate, the carbon nanotube array, the liquid medium, and the substitute substrate into a freezer, the freezer having an internal temperature below a freezing point of the liquid medium.

11. The method of claim 6 , wherein the liquid medium is water, the solid medium is ice.

12. The method of claim 1 , wherein the laser etching the carbon nanotube array forms an etching groove on the first surface.

13. The method of claim 12 , wherein a depth of the etching groove is smaller than or equal to a height of the carbon nanotube array.

14. A carbon nanotube device comprising a device body and a patterned carbon nanotube array located on the device body, the patterned carbon nanotube array having an ability to have a carbon nanotube structure drawn therefrom, the carbon nanotube structure comprising a plurality of carbon nanotubes joined end to end, the patterned carbon nanotube array is patterned from an original carbon nanotube array grown on a growing substrate, and the device body is not the growing substrate.

15. A method for patterning a carbon nanotube array, the method comprising:
providing a carbon nanotube array transferred onto a second substrate from a first substrate, the carbon nanotube array having a second surface adjacent to the second substrate and a first surface away from the substitute substrate, the carbon nanotube array having an ability to have a carbon nanotube structure drawn therefrom, and the carbon nanotube structure comprising a plurality of carbon nanotubes joined end to end;
laser etching the first surface of the carbon nanotube array to divide the carbon nanotube array into a preserving area and a removing area; and
drawing the carbon nanotube structure from the removing area and leaving carbon nanotubes in the preserving area.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wei Yang
• Wei Hao-Ming
• Fan Shou-Shan

Classifications

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title

• B29C2059/028

  Incorporating particles by impact in the surface, e.g. using fluid jets or explosive forces to implant particles · CPC title

• B29C59/005 Primary

  characterised by the choice of material · CPC title

• B29C2059/023

  Microembossing · CPC title

• B29C59/022

  characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor · CPC title