Process of preparing a chemically pre-formed (CPF) iron negative electrode with oxidizing compounds
US-9478793-B2 · Oct 25, 2016 · US
US9478806B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9478806-B2 |
| Application number | US-201414170043-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 31, 2014 |
| Priority date | Feb 1, 2013 |
| Publication date | Oct 25, 2016 |
| Grant date | Oct 25, 2016 |
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The present invention provides one with an iron electrode employing a binder comprised of polyvinyl alcohol (PVA) binder. In one embodiment, the invention comprises an iron based electrode comprising a single layer of a conductive substrate coated on at least one side with a coating comprising an iron active material and a binder, wherein the binder is PVA. This iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.
Opening claim text (preview).
What is claimed is: 1. An iron electrode comprising an active iron material, sulfur and a polyvinyl alcohol binder in an amount of from 2 to 5 wt %. 2. The iron electrode of claim 1 , wherein the sulfur comprises elemental sulfur. 3. The iron electrode of claim 1 , wherein the iron electrode further comprises a nickel additive. 4. The iron electrode of claim 1 , wherein the active iron material comprises iron metal, an iron oxide material, or a mixture thereof. 5. The iron electrode of claim 4 , wherein the iron oxide material comprises Fe 3 O 4 . 6. The iron electrode of claim 1 , wherein the polyvinyl alcohol binder comprises polyvinyl alcohol that is hydrolyzed between 98.5 and 100%. 7. The iron electrode of claim 1 , wherein the polyvinyl alcohol binder comprises polyvinyl alcohol that is hydrolyzed between 99 and 100%. 8. The iron electrode of claim 1 , wherein the polyvinyl alcohol binder comprises from 2.5 to 4 wt % of the iron electrode. 9. A paste formulation for an iron electrode which comprises an active iron material, sulfur and from 2 to 5 wt % of a polyvinyl alcohol binder. 10. The paste formulation of claim 9 , wherein the formulation comprises from 2.5 to 4 wt % polyvinyl alcohol binder. 11. The paste formulation of claim 9 , wherein the sulfur comprises elemental sulfur. 12. The paste formulation of claim 9 , further comprising 1 nickel additive. 13. The paste formulation of claim 9 , wherein the active iron material comprises iron metal, an iron oxide material, or a mixture thereof. 14. The paste formulation of claim 13 , wherein the iron oxide material comprises Fe 3 O 4 .
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