Process and apparatus for improving light olefin yield from a fluid catalytic cracking process

Patent metadata

Field	Value
Publication number	US-9468897-B2
Application number	US-201414578181-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 19, 2014
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

The present invention discloses a process optimizing the yield of ethylene and propylene from a fluid catalytic cracking unit. The method combines a first catalytic reactor, a fractionation zone, a separation unit and a second catalytic reactor. The separation unit produces a first separate stream comprising C 4 olefins and a second separate stream comprising C 5 olefins. The separate streams may be combined and are passed to a second catalytic reactor for additional conversion to ethylene and propylene.

First claim

The invention claimed is:

1. An apparatus for catalytic cracking, comprising:
a first catalytic reactor for catalytically cracking a first hydrocarbon feed stream;
a fractionation zone in downstream communication with the first catalytic reactor, said fractionation zone comprising a debutanizer column;
a separation unit including a first distillation column in downstream communication with said debutanizer column for producing a first separated stream comprising C 4 olefins and a second distillation column in downstream communication with said fractionation section for producing a second separated stream comprising C 5 olefins and a recovery column in said separation unit for separating extractant from extract, said recovery column being in downstream communication with said first distillation column and said second distillation column; and
a second catalytic reactor in downstream communication with an overhead line of said first distillation column and an overhead line of said second distillation column of the separation unit for cracking a second hydrocarbon feed stream comprising said first separated stream and said second separated stream.

2. The apparatus of claim 1 wherein said first distillation column and said second distillation column are in downstream communication with a bottoms line of said recovery column.

3. The apparatus of claim 2 further comprising an overhead line on said recovery column for carrying an extract comprising C 4 olefins and C 5 olefins, said second catalytic reactor being in downstream communication with said overhead line.

4. The apparatus of claim 1 wherein said recovery column is in downstream communication with a bottoms line of said first distillation column and said second distillation column.

5. The apparatus of claim 1 wherein said separation unit is in downstream communication with an overhead line and a bottoms line of said debutanizer column.

6. The apparatus of claim 1 further comprising a LPG splitter column in downstream communication with said debutanizer column, and said separation unit is in downstream communication with said LPG splitter.

7. The apparatus of claim 1 further comprising a depentanizer column in downstream communication with said debutanizer column and said separation unit is in downstream communication with an overhead line of said depentanizer column.

8. The apparatus of claim 7 wherein said first distillation column is in downstream communication with said debutanizer column and said second distillation column is in downstream communication with said depentanizer column.

9. An apparatus for catalytic cracking, comprising:
a first catalytic reactor for catalytically cracking a first hydrocarbon feed stream;
a fractionation zone in downstream communication with the first catalytic reactor, said fractionation zone comprising a debutanizer column;
an extraction unit including a first extractive distillation column in downstream communication with said debutanizer column for producing a first extract stream comprising C 4 olefins, a second extractive distillation column for producing a second extract stream comprising C 5 olefins and a recovery column in connection with a bottoms line of said first distillation column and a bottoms line of said second distillation column; and
a second catalytic reactor in downstream communication with the extraction unit for cracking a second hydrocarbon feed stream.

10. The apparatus of claim 9 wherein said second extractive distillation column is in downstream communication with said debutanizer column.

11. The apparatus of claim 9 wherein said fractionation zone further comprises a depentanizer column and said second extractive distillation column is in downstream communication with said depentanizer column.

12. The apparatus of claim 11 wherein said depentanizer column is in downstream communication with said debutanizer column.

13. An apparatus for catalytic cracking, comprising:
a first catalytic reactor for catalytically cracking a first hydrocarbon feed stream;
a fractionation zone in downstream communication with the first catalytic reactor, said fractionation zone comprising a debutanizer column, a LPG splitter column in downstream communication with said debutanizer column and a depentanizer column in downstream communication with said debutanizer column;
an extraction unit including a first extractive distillation column in downstream communication with said debutanizer column for producing a first extract stream comprising C 4 olefins and a second extractive distillation column in downstream communication with said fractionation zone for producing a second extract stream comprising C 5 olefins, said extraction unit in downstream communication with said LPG splitter column and said depentanizer column; and
a second catalytic reactor in downstream communication with an overhead line of said first extractive distillation column and an overhead line of said second extractive distillation column of the extraction unit for cracking a second hydrocarbon feed stream comprising said first extract stream and said second extract stream.

14. The apparatus of claim 13 wherein said extraction unit further comprises a recovery column for separating extractant from extract, said recovery column being in downstream communication with said first extractive distillation column and said second extractive distillation column and producing a combined stream of said first extract and said second extract and said second catalytic reactor in downstream communication with said recovery column.

15. The apparatus of claim 14 wherein said first extractive distillation column and said second extractive distillation column are in downstream communication with a bottoms line of said recovery column.

Assignees

• Uop Llc

Inventors

• Liu Kirk
• Fei Zhihao
• Luebke Charles P

Classifications

• C10G51/026 Primary

  only catalytic cracking steps · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title

• B01J2208/00893

  Feeding means for the reactants · CPC title

• C07C2529/06

  Crystalline aluminosilicate zeolites; Isomorphous compounds thereof · CPC title

• B01J8/26 Primary

  with two or more fluidised beds, e.g. reactor and regeneration installations · CPC title