Magnetic powder for magnetic recording, magnetic recording medium, and method of manufacturing magnetic powder for magnetic recording

Patent metadata

Field	Value
Publication number	US-9454983-B2
Application number	US-201414584557-A
Country	US
Kind code	B2
Filing date	Dec 29, 2014
Priority date	Dec 27, 2013
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

An aspect of the present invention relates to a method of manufacturing hexagonal ferrite powder, which comprises preparing a hexagonal ferrite precursor-containing water-based solution by stirring and mixing a reaction solution which comprises an iron salt, an alkaline earth metal salt, and a base in a reaction tank, and removing the hexagonal ferrite precursor-containing water-based solution that has been prepared from the reaction tank and continuously feeding the hexagonal ferrite precursor-containing water-based solution into a reaction flow passage while conducting heating and pressurizing to converting the hexagonal ferrite precursor to hexagonal ferrite, wherein the preparation of the hexagonal ferrite precursor-containing water-based solution comprises a continual feed period during which feeding of the iron salt, the alkaline earth metal salt, and the base into a reaction tank which comprises a prereaction solution in which an iron salt and a base are not both present is continuously or intermittently continued, during the continual feed period, at least a base is fed over a feed passage separate from feeding of the iron salt and the alkaline earth metal salt, and an amount of at least one from among the iron salt, the alkaline earth metal salt, and the base that is fed per unit time during the continual feed period is controlled and/or acid is added to the reaction solution in the reaction tank so that a pH of the reaction solution within the reaction tank during the continual feed period falls within a range relative to a pH before , a pH of the prereaction solution, of

pH before −2≦pH≦pH before +2.

First claim

What is claimed is:

1. A method of manufacturing hexagonal ferrite powder, which comprises:
preparing a hexagonal ferrite precursor-containing water-based solution by stirring and mixing a reaction solution which comprises an iron salt, an alkaline earth metal salt, and a base in a reaction tank; and
removing the hexagonal ferrite precursor-containing water-based solution that has been prepared from the reaction tank and continuously feeding the hexagonal ferrite precursor-containing water-based solution into a reaction flow passage while conducting heating and pressurizing to converting the hexagonal ferrite precursor to hexagonal ferrite; wherein
the preparation of the hexagonal ferrite precursor-containing water-based solution comprises a continual feed period during which feeding of the iron salt, the alkaline earth metal salt, and the base into a reaction tank which comprises a prereaction solution in which an iron salt and a base are not both present is continuously or intermittently continued;
during the continual feed period, at least a base is fed over a feed passage separate from feeding of the iron salt and the alkaline earth metal salt; and
an amount of at least one from among the iron salt, the alkaline earth metal salt, and the base that is fed per unit time during the continual feed period is controlled and/or acid is added to the reaction solution in the reaction tank so that a pH of the reaction solution within the reaction tank during the continual feed period falls within a range relative to a pH before , a pH of the prereaction solution, of
pH before −2≦pH≦pH before +2.

2. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the feeding of the iron salt, the alkaline earth metal salt, and the base is conducted over separate feed passages in the preparation of the hexagonal ferrite precursor-containing water-based solution.

3. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the iron salt and the alkaline earth metal salt are mixed and then fed to the reaction tank over the same feed passage in the preparation of the hexagonal ferrite precursor-containing water-based solution.

4. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein at least an amount of the base being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased during the continual feed period.

5. The method of manufacturing hexagonal ferrite powder according to claim 4 , wherein during the continual feed period, during a period within which an amount of the iron salt and the alkaline earth metal salt being fed per unit time is not varied, an amount of the base that is being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased.

6. The method of manufacturing hexagonal ferrite powder according to claim 2 , wherein at least an amount of the base being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased during the continual feed period.

7. The method of manufacturing hexagonal ferrite powder according to claim 6 , wherein during the continual feed period, during a period within which an amount of the iron salt and the alkaline earth metal salt being fed per unit time is not varied, an amount of the base that is being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased.

8. The method of manufacturing hexagonal ferrite powder according to claim 3 , wherein at least an amount of the base being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased during the continual feed period.

9. The method of manufacturing hexagonal ferrite powder according to claim 8 , wherein during the continual feed period, during a period within which an amount of the iron salt and the alkaline earth metal salt being fed per unit time is not varied, an amount of the base that is being fed per unit time is increased, decreased, increased and then decreased, or decreased and then increased.

10. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the iron salt, the alkaline earth metal salt, and the base are fed as solutions.

11. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the removal of the hexagonal ferrite precursor-containing solution that has been prepared from the reaction tank is conducted in parallel with feeding the iron salt, the alkaline earth metal salt, and the base.

12. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the preparation of the precursor-containing water-based solution is conducted in a batch reaction tank.

13. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the hexagonal ferrite precursor-containing water-based solution that is removed from the reaction tank is mixed with an organic compound and then continuously flowed in a reaction flow passage while being heated and pressurized.

14. The method of manufacturing hexagonal ferrite powder according to claim 1 , which further comprises feeding an organic compound to the reaction tank in the preparation of the hexagonal ferrite precursor-containing water-based solution.

15. The method of manufacturing hexagonal ferrite powder according to claim 1 , wherein the heating and the pressurizing are conducted by heating the hexagonal ferrite precursor-containing water-based solution flowing through the reaction flow passage to equal to or higher than 300° C. and pressurizing to equal to or higher than 20 MPa.

Assignees

• Fujifilm Corp

Inventors

• Hosoya Yoichi

Classifications

• C01P2004/10

  extending in one dimension, e.g. needle-like · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2006/42

  Magnetic properties · CPC title

• C01P2004/54

  Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension · CPC title

• Y10T428/2982

  Particulate matter [e.g., sphere, flake, etc.] · CPC title