Control of electrolyte hydrodynamics for efficient mass transfer during electroplating
US-9394620-B2 · Jul 19, 2016 · US
US9449808B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9449808-B2 |
| Application number | US-201313904283-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 29, 2013 |
| Priority date | May 29, 2013 |
| Publication date | Sep 20, 2016 |
| Grant date | Sep 20, 2016 |
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The embodiments disclosed herein pertain to novel methods and apparatus for removing material from a substrate. In certain embodiments, the method and apparatus are used to remove negative photoresist, though the disclosed techniques may be implemented to remove a variety of materials. In practicing the disclosed embodiments, a stripping solution may be introduced from an inlet to an internal manifold, sometimes referred to as a cross flow manifold. The solution flows laterally through a relatively narrow cavity between the substrate and the base plate. Fluid exits the narrow cavity at an outlet, which is positioned on the other side of the substrate, opposite the inlet and internal manifold. The substrate spins while in contact with the stripping solution to achieve a more uniform flow over the face of the substrate. In some embodiments, the base plate includes protuberances which operate to increase the flow rate (and thereby increase the local Re) near the face of the substrate.
Opening claim text (preview).
What is claimed is: 1. An apparatus for removing material from a substrate, comprising: a removal cell comprising: (a) a substrate holder configured to hold and rotate a disc-shaped substrate in a substrate plane, (b) a base plate positioned substantially parallel to the substrate plane such that a gap is formed between the base plate and the substrate when the substrate is present in the substrate holder, the base plate comprising a plurality of protuberances that extend into the gap, wherein the distance between the base plate and the substrate in the substrate holder is between about 2-10 mm, and (c) a flow distributor positioned proximate a periphery of the gap and at least partially positioned between the baseplate and substrate holder, comprising: (i) an inlet side comprising an internal manifold spanning between about 90-180° of the flow distributor, wherein the internal manifold is a cavity in the flow distributor through which fluid may flow, (ii) one or more inlets for delivering fluid from a fluid supply line to the internal manifold, and (iii) an outlet side comprising an outlet manifold spanning between about 90-180° of the flow distributor, wherein the inlet side and outlet side of the flow distributor are positioned on azimuthally opposed perimeter locations of the flow distributor, and wherein during operation fluid flows from the internal manifold at the inlet side of the flow distributor to the outlet manifold on the outlet side of the flow distributor. 2. The apparatus of claim 1 , further comprising a plurality of fins positioned in the gap that operate to direct fluid to flow in a substantially linear flow pattern from the internal manifold to the outlet manifold. 3. The apparatus of claim 1 , wherein the substrate has a diameter of about 300 or 450 mm. 4. The apparatus of claim 1 , wherein a gap between the flow distributor and the substrate holder, when engaged, is between about 0.25-8 mm. 5. The apparatus of claim 1 , wherein the internal manifold comprises a plurality of angularly distinct sections. 6. The apparatus of claim 5 , wherein the flow to at least one angularly distinct section of the internal manifold may be controlled independently of at least one other angularly distinct section of the internal manifold. 7. The apparatus of claim 1 , wherein the protuberances are oriented perpendicular to a direction between the inlet side and outlet side of the flow distributor, and wherein the protuberances have a height that is between about 30-85% of the distance between the base plate and the substrate in the substrate holder. 8. The apparatus of claim 1 , wherein the protuberances are continuous in a length-wise direction across the base plate, the length-wise direction being perpendicular to a direction between the inlet side and outlet side of the flow distributor. 9. The apparatus of claim 1 , wherein a width of the protuberances, as measured in a direction between the inlet side and outlet side of the flow distributor, is between about 0.5-3 mm, and wherein a distance between adjacent protuberances, as measured in the direction between the inlet side and outlet side of the flow distributor, is between about 2-10 mm. 10. The apparatus of claim 1 , wherein the internal manifold comprises a plurality of showerhead outlet holes designed or configured to deliver fluid to the gap. 11. The apparatus of claim 10 , wherein the showerhead outlet holes are positioned between the substrate holder and the base plate, and radially outside of the peripheral edge of the substrate. 12. The apparatus of claim 1 , wherein the protuberances are discontinuous in a length-wise direction across the base plate, the length-wise direction being perpendicular to a direction between the inlet side and outlet side of the flow distributor. 13. The apparatus of claim 12 , wherein discontinuities in the protuberances form channels between protuberances, and wherein the protuberances are arranged in a set-off manner such that the channels between the protuberances do not line up with one another in a direction between the inlet side and outlet side of the flow distributor. 14. The apparatus of claim 1 , further comprising a rinsing element designed or configured to deliver rinsing fluid to the surface of the substrate. 15. The apparatus of claim 14 , wherein the rinsing element is designed or configured to be used in the removal cell. 16. The apparatus of claim 14 , wherein the rinsing element is positioned in a spin rinse drying module that is separate from the removal cell. 17. An apparatus for removing material from a substrate, comprising: a removal cell comprising: (a) a substrate holder configured to hold and rotate a disc-shaped substrate in a substrate plane, (b) a base plate positioned substantially parallel to the substrate plane such that a gap is formed between the base plate and the substrate when the substrate is present in the substrate holder, wherein the distance between the base plate and the substrate in the substrate holder is between about 2-10 mm, and (c) a flow distributor positioned proximate a periphery of the gap and at least partially positioned between the baseplate and substrate holder, comprising: (i) an inlet side comprising an internal manifold spanning between about 90-180° of the flow distributor, wherein the internal manifold is divided into angularly distinct segments in the flow distributor through which fluid may flow, (ii) inlets for independently delivering fluid from a fluid supply line to each of the angularly distinct segments of the internal manifold of the flow distributor, (iii) flow control structures for independently controlling the flow rate of fluid delivered to the angularly distinct segments of the internal manifold of the flow distributor, and (iv) an outlet side comprising an outlet manifold spanning between about 90-180° of the flow distributor, wherein the inlet side and outlet side of the flow distributor are positioned on azimuthally opposed perimeter locations of the flow distributor, and wherein during operation fluid flows from the internal manifold at the inlet side of the flow distributor to the outlet manifold on the outlet side of the flow distributor. 18. The apparatus of claim 17 , further comprising a plurality of fins positioned in the gap that operate to direct fluid to flow in a substantially linear flow pattern from the internal manifold to the outlet manifold. 19. The apparatus of claim 17 , further comprising a rinsing element designed or configured to deliver rinsing fluid to the surface of the substrate. 20. The apparatus of claim 17 , wherein the internal manifold comprises a plurality of showerhead outlet holes designed or configured to deliver fluid to the gap. 21. The apparatus of claim 20 , wherein the showerhead outlet holes are positioned between the substrate holder and the base plate, and radially outside of the peripheral edge of the substrate. 22. The apparatus of claim 17 , wherein a gap between the flow distributor and the substrate holder, when engaged, is between about 0.25-8 mm. 23. An apparatus for removing material from a substrate, comprising: a removal cell comprising: (a) a substrate holder configured to hold and rotate a disc-shaped substrate in a substrate plane, (b) a base plate positioned substantially parallel to the substrate plane such that a gap is formed between the base plate and the substrate when the substrate is present in the substr
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