Molded article of polyolefin-based resin expanded beads

Patent metadata

Field	Value
Publication number	US-9449735-B2
Application number	US-201314047584-A
Country	US
Kind code	B2
Filing date	Oct 7, 2013
Priority date	Oct 10, 2012
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

An electrostatic dissipating molded article having a surface resistivity of 1×10 5 to 1×10 10 Ω and obtained by in-mold molding of multi-layered polyolefin-based resin expanded beads each having an polyolefin-based resin expanded core layer and a polyolefin-based resin cover layer which covers the polyolefin-based resin expanded core layer and which is formed from a polyolefin-based resin (A), a polymeric antistatic agent (B) of a block copolymer of a polyether block and a polyolefin block, and an electrically conductive carbon black (C), the components (A) to (C) being present in a specific proportion.

First claim

What is claimed is:

1. A polyolefin-based resin expanded beads molded article obtained by in-mold molding of multi-layered polyolefin-based resin expanded beads each having an polyolefin-based resin expanded core layer and a polyolefin-based resin cover layer covering the polyolefin-based resin expanded core layer,
wherein the polyolefin-based resin cover layer comprises a mixture of a polyolefin-based resin (A), a polymeric antistatic agent (B) which is a block copolymer of a polyether block and a polyolefin block, and an electrically conductive carbon black (C),
wherein a weight ratio (A:B) of the polyolefin-based resin (A) to the polymeric antistatic agent (B) is 99.5:0.5 to 55:45, and the electrically conductive carbon black (C) is present in an amount of 5 to 30 parts by weight per 100 parts by weight of the total of the polyolefin-based resin (A) and the polymeric antistatic agent (B),
wherein the cover layer has a structure in which the polyolefin-based resin (A) forms a continuous phase and the polymeric antistatic agent (B) forms dispersed phases that are dispersed in the continuous phase with the electrically conductive carbon black (C) being unevenly distributed to the dispersed phases, and
wherein the polyolefin-based resin expanded beads molded article has a surface resistivity of 1×10 5 to 1×10 10 Ω.

2. The polyolefin-based resin expanded beads molded article according to claim 1 , wherein both of the polyolefin-based resin of the polyolefin-based resin expanded core layer and the polyolefin-based resin of the polyolefin-based resin cover layer are a polypropylene-based resin.

3. The polyolefin-based resin expanded beads molded article according to claim 1 , wherein the electrically conductive carbon black (C) is Ketjen black and present in an amount of 5 to 15 parts by weight per 100 parts by weight of the total of the polyolefin-based resin (A) and the polymeric antistatic agent (B).

4. The polyolefin-based resin expanded beads molded article according to claim 1 , wherein a weight ratio of the polyolefin-based resin expanded core layer to the polyolefin-based resin cover layer is 99.5:0.5 to 65:35.

5. The polyolefin-based resin expanded beads molded article according to claim 1 , wherein the polyolefin-based resin expanded beads molded article has an apparent density of 10 to 90 kg/m 3 .

6. The polyolefin-based resin expanded beads molded article according to claim 1 , wherein the polyolefin-based resin expanded beads molded article has a 50% compressive stress of Cs [kPa] and an apparent density of Ad [kg/m 3 ] and, wherein a ratio Cs/Ad is 6 or higher.

Assignees

• Jsp Corp

Inventors

• Chiba Takuya
• Oikawa Masaharu
• Shinohara Mitsuru

Classifications

• C08J9/18

  by impregnating polymer particles with the blowing agent · CPC title

• C08J2203/06

  CO2, N2 or noble gases · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title

• C08J9/008

  Nanoparticles · CPC title

• C08J2453/00

  Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title