Granulation of fine powder

Patent metadata

Field	Value
Publication number	US-9409825-B2
Application number	US-201313971157-A
Country	US
Kind code	B2
Filing date	Aug 20, 2013
Priority date	Aug 20, 2013
Publication date	Aug 9, 2016
Grant date	Aug 9, 2016

Abstract

A mixture of fine powder including thorium oxide was converted to granulated powder by forming a first-green-body and heat treating the first-green-body at a high temperature to strengthen the first-green-body followed by granulation by crushing or milling the heat-treated first-green-body. The granulated powder was achieved by screening through a combination of sieves to achieve the desired granule size distribution. The granulated powder relies on the thermal bonding to maintain its shape and structure. The granulated powder contains no organic binder and can be stored in a radioactive or other extreme environment. The granulated powder was pressed and sintered to form a dense compact with a higher density and more uniform pore size distribution.

First claim

What is claimed is:

1. A process for granulating fine powder, the process comprising:
mixing a fine powder having a particle size in a range from 10 nm to 1 mm by dry mixing or wet mixing, the fine powder including cerium oxide and at least one radioactive compound;
forming a first-green-body from the mixed powder;
heat treating the first-green-body to a temperature in a range from 100 to 2000 degrees C. to strengthen the structure of the first-green-body;
forming granulated powder by crushing or milling the heat-treated first-green-body; and
filtering the granulated powder.

2. The process of claim 1 , wherein the step of forming the first-green-body further includes applying heat in a vacuum or a gaseous environment, the gaseous environment including at least one gas selected from nitrogen, air, argon, and helium.

3. The process of claim 1 , wherein the radioactive compound includes a radioactive compound of Th, Pa, U, Np, Pu, Am, Cm, or Bk.

4. The process of claim 3 , wherein the radioactive compound includes an oxide, a nitride, a fluoride, a chloride, a bromide, an iodide, a sulfide, or combinations thereof.

5. The process of claim 1 , wherein forming the first-green-body includes applying a pressing pressure in a range from 1 psi to 40,000 psi.

6. The process of claim 1 , wherein the step of forming the first-green-body includes dry pressing, cold isostatic pressing, roll compaction, or dry bag isostatic pressing.

7. The process of claim 1 , wherein the granulated powder contains no organic binder.

8. The process of claim 1 , wherein the granulated powder includes a total surface area reduced by 0.00001 to 80% compared to a total surface area of the fine powder.

9. A process for forming a compact, the process comprising:
mixing a fine powder having a particle size in a range from 10 nm to 1mm by dry mixing or wet mixing, the fine powder including cerium oxide and at least one radioactive compound;
forming a first-green-body from the mixed powder;
heat treating the first-green-body to a temperature in a range from 100 to 2000 degrees C. to strengthen the structure of the first-green-body;
forming granulated powder from the first-green-body;
filtering the granulated powder;
forming a second-green-body from the granulated powder; and
sintering the second-green body under conditions effective for forming a dense radioactive compact.

10. The process of claim 9 , wherein the step of forming the first-green-body further includes applying heat in a vacuum or a gaseous environment, the gaseous environment including at least one gas selected from nitrogen, air, argon, and helium.

11. The process of claim 9 , wherein the radioactive compound includes at least one of radioactive compound of Th, Pa, U, Np, Pu, Am, Cm, or Bk.

12. The process of claim 11 , wherein the radioactive compound includes an oxide, a nitride, a fluoride, a chloride, a bromide, an iodide, a sulfide, or combinations thereof.

13. The process of claim 9 , wherein forming the first-green-body includes applying a pressing pressure in a range from 1 psi to 40,000 psi.

14. The process of claim 9 , wherein the step of forming the first-green-body includes dry pressing, cold isostatic pressing, roll compaction, or dry bag isostatic pressing.

15. The process of claim 9 , wherein the granulated powder contains no organic binder.

16. The process of claim 9 , wherein the step of forming the second-green-body includes pressing the granulated powder in a die using a pressure in a range from 1 psi to 100,000 psi.

17. The process of claim 9 , wherein the step of sintering the second-green-body includes heating the second-green-body at a temperature within a range from 400 degrees C. to 2500 degrees C.

18. The process of claim 9 , wherein the granulated powder includes a total surface area reduced by 0.00001 to 80% compared to a total surface area of the fine powder.

Assignees

• Los Alamos Nat Security Llc

Inventors

• Chen Ching-Fong

Classifications

• C01F15/00

  Compounds of thorium · CPC title

• C04B35/51 Primary

  based on compounds of actinides ({non-oxide actinide compounds C04B35/5158;} nuclear fuel materials G21C3/62) · CPC title

• C04B2235/604

  Pressing at temperatures other than sintering temperatures · CPC title

• C01P2004/50

  Agglomerated particles · CPC title

• C01P2006/10

  Solid density · CPC title