Laser ablation methods for producing feedstock powder suitable for laser-based additive manufacturing

Patent metadata

Field	Value
Publication number	US-12202046-B2
Application number	US-202017757937-A
Country	US
Kind code	B2
Filing date	Dec 22, 2020
Priority date	Dec 24, 2019
Publication date	Jan 21, 2025
Grant date	Jan 21, 2025

Abstract

Methods and systems for producing feedstock powders, suitable for use in laser-based additive manufacturing, use laser ablation to vaporize a source material, which may be in bulk solid or solid coarse grain form. The source material is vaporized by a laser (or other focused energy source) in a vaporization chamber that is temperature controlled to provide a vertical thermal gradient. The vertical thermal gradient may be controlled to, in turn, control the nucleation, coagulation, and agglomeration of the vaporized molecules, enabling formation of microparticles that may then be used as feedstock powders in laser-based additive manufacturing. The produced feedstock powder particles may be of uniform composition, of uniform shape (e.g., substantially spherical), and of uniform phase or homogeneously mixed phases.

First claim

What is claimed is:

1. A method for producing feedstock powder suitable for use in laser-based additive manufacturing, the method comprising:
directing a focused energy source toward a solid source material to vaporize compounds of the solid source material; and
passing the compounds through a temperature-controlled vaporization chamber to cool the compounds and form solid microparticles comprising the compounds.

2. The method of claim 1 , further comprising passing the solid microparticles through an oil bubbler filtration unit.

3. The method of claim 1 , further comprising depositing, by atomic layer deposition, additional material onto an outer surface of each of the solid microparticles.

4. The method of claim 1 , further comprising providing the solid source material in a form of a solid bulk material.

5. The method of claim 1 , further comprising providing the solid source material in a form of solid coarse grains.

6. The method of claim 1 , further comprising introducing a carrier gas into the temperature-controlled vaporization chamber.

7. The method of claim 6 , further comprising passing the carrier gas through a HEPA filter.

8. The method of claim 1 , wherein passing the compounds through the temperature-controlled vaporization chamber comprises providing a vertical thermal gradient in the temperature-controlled vaporization chamber.

9. The method of claim 1 , wherein directing the focused energy source toward the solid source material comprises directing a laser toward the solid source material.

10. The method of claim 9 , wherein directing the laser toward the solid source material comprises directing a carbon dioxide laser toward the solid source material.

11. The method of claim 9 , wherein directing the laser toward the solid source material comprises directing the laser toward a solid source material comprising uranium and/or plutonium.

12. The method of claim 1 , further comprising providing the solid source material, the solid source material comprising at least one of uranium oxide and plutonium oxide.

13. The method of claim 1 , further comprising collecting the solid microparticles, the solid microparticles each having a greatest dimension in a range of 1 μm to 1000 μm and being substantially spherical.

14. A method for producing feedstock powder suitable for use in laser-based additive manufacturing, the method comprising:
directing a focused energy source toward a solid source material to vaporize compounds of the solid source material, comprising passing a laser beam through a conduit opening into a temperature-controlled vaporization chamber;
passing a carrier gas and the compounds through the temperature-controlled vaporization chamber comprising cooling elements to cool the compounds and form solid microparticles comprising the compounds; and
passing the carrier gas through at least one filter after the temperature-controlled vaporization chamber.

15. The method of claim 14 , wherein passing the carrier gas through the at least one filter comprises passing the carrier gas through an oil bubbler filtration unit.

16. The method of claim 14 , wherein passing the carrier gas through the at least one filter comprises passing the carrier gas through a HEPA filter.

17. The method of claim 14 , further comprising, before directing the focused energy source toward the solid source material, providing the solid source material on a support at a base of the temperature-controlled vaporization chamber.

18. The method of claim 1 , further comprising, with at least one filter, collecting the solid microparticles in a receptacle, the solid microparticles being of substantially uniform material phase or homogeneously mixed material phases.

19. The method of claim 1 , further comprising, with at least one filter, collecting the solid microparticles in a receptacle, the solid microparticles being substantially spherical and of substantially uniform composition.

20. The method of claim 1 , wherein passing the compounds through the temperature-controlled vaporization chamber comprises controlling the temperature-controlled vaporization chamber temperature with a temperature controller within the temperature-controlled vaporization chamber.

21. The method of claim 1 , wherein passing the compounds through the temperature-controlled vaporization chamber comprises controlling the temperature-controlled vaporization chamber temperature with a temperature controller within the temperature-controlled vaporization chamber, the temperature controller comprising heating elements along a first portion of the vaporization chamber and cooling elements along a second portion of the vaporization chamber.

Assignees

• Battelle Energy Alliance Llc

Inventors

• O'Brien Robert C
• Abe Owen O

Classifications

• B23K26/36

  Removing material (B23K26/55, B23K26/57 take precedence) · CPC title

• B23K26/127

  in an enclosure · CPC title

• B22F2302/25

  Oxide · CPC title

• B22F2301/00

  Metallic composition of the powder or its coating · CPC title

• B33Y40/10

  Pre-treatment · CPC title