Method and apparatus for extracting and removing rare earth metal ions from plating solution

Patent metadata

Field	Value
Publication number	US-9399828-B2
Application number	US-201514679206-A
Country	US
Kind code	B2
Filing date	Apr 6, 2015
Priority date	Apr 7, 2014
Publication date	Jul 26, 2016
Grant date	Jul 26, 2016

Abstract

In an extraction tank, a plating solution containing rare earth metal ions is treated with an extracting solution of an extractant in a water-insoluble organic solvent. Extraction treatment is carried out by atomizing the extracting solution through a lower nozzle into the plating solution in the tank lower zone, and atomizing the plating solution through an upper nozzle into the extracting solution in the tank upper zone, for thereby bringing the plating solution in contact with the extracting solution to extract rare earth metal ions from the plating solution into the extractant for removal.

First claim

The invention claimed is:

1. A method for extracting and removing rare earth metal ions from a plating solution in an extraction tank using an extracting solution, the extraction tank including a lower zone filled with the plating solution and an upper zone filled with the extracting solution, the plating solution containing rare earth metal ions as impurities, the extracting solution containing an extractant in a water-insoluble organic solvent and having a lower specific gravity than the plating solution, said method comprising the steps of:
atomizing the extracting solution from a lower position in the extraction tank, into the plating solution in the tank lower zone, and
atomizing the plating solution from an upper position in the extraction tank, into the extracting solution in the tank upper zone,
for thereby bringing the plating solution in contact with the extracting solution to extract rare earth metal ions from the plating solution into the extractant for removal.

2. The method of claim 1 wherein the step of atomizing the solution in an atomized fashion includes atomizing the solution through a spray nozzle or full-cone nozzle.

3. The method of claim 1 wherein the plating solution is a nickel plating solution.

4. The method of claim 1 , wherein a vertical partition is disposed in the extraction tank to divide into two compartments, extraction compartment and stationary compartment,
a lower portion of the partition being provided with a passage for communication of the plating solution between the compartments,
an upper portion of the partition being provided with another passage for communication of the extracting solution between the compartments.

5. The method of claim 1 wherein the extraction tank is provided with an outlet for discharging the plating solution from which rare earth metal ions have been extracted and another outlet for discharging the extracting solution having rare earth metal ions extracted therein.

6. An apparatus for extracting and removing rare earth metal ions from a plating solution containing rare earth metal ions as impurities, using an extracting solution of an extractant in a water-insoluble organic solvent having a lower specific gravity than water, said apparatus comprising
an extraction tank,
a plating solution feed line fitted at a distal end with a spray or full-cone nozzle, the spray or full-cone nozzle at the distal end of the plating solution feed line being positioned in an upper zone of the extraction tank, and
an extracting solution feed line fitted at a distal end with a spray or full-cone nozzle, the spray or full-cone nozzle at the distal end of the extracting solution feed line being positioned in a lower zone of the extraction tank,
wherein the extracting solution is atomized from the spray or full-cone nozzle at the distal end of the extracting solution feed line into the tank lower zone so as to flow upward, and the plating solution is atomized from the spray or full-cone nozzle at the distal end of the plating solution feed line into the tank upper zone so as to flow downward, for thereby bringing the plating solution in contact with the extracting solution.

7. The apparatus of claim 6 , further comprising
a vertical partition disposed in the extraction tank to divide into two compartments, extraction compartment and stationary compartment,
a passage provided in a lower portion of the partition for communication of the plating solution between the compartments, and
another passage provided in an upper portion of the partition for communication of the extracting solution between the compartments.

8. The apparatus of claim 6 , further comprising
an outlet provided in the extraction tank for discharging the plating solution from which rare earth metal ions have been extracted, and
another outlet provided in the extraction tank for discharging the extracting solution having rare earth metal ions extracted therein.

Assignees

• Shinetsu Chemical Co

Inventors

• Sugahara Hiroto
• Minowa Takehisa

Classifications

• C25D21/18 Primary

  of electrolytes (C25D21/22 takes precedence) · CPC title

• B01D11/04

  of solutions which are liquid · CPC title

• C22B59/00

  Obtaining rare earth metals · CPC title

• C25D3/12

  of nickel or cobalt · CPC title